钠氨基磺酸 | 13845-18-6

• 物质功能分类: 有机原料 - 氨基化合物 - 磺酸类氨基化合物
• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 碱金属有机物
• 中文名称: 钠氨基磺酸
• 英文名称: sodium sulfamate
• 英文别名: sulfamic acid sodium salt；sodium;sulfamate
• CAS: 13845-18-6；26288-34-6
• 化学式: H₂NO₃S*Na
• 分子量: 119.077
• InChiKey: QDWYPRSFEZRKDK-UHFFFAOYSA-M

物化性质

• 沸点：
  272℃[at 101 325 Pa]
• 密度：
  2.08[at 20℃]
• LogP：
  -3.84 at 22℃
• 物理描述：
  Liquid

计算性质

• 辛醇/水分配系数(LogP)：
  -4.59
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  91.6
• 氢给体数：
  1
• 氢受体数：
  4

安全信息

• 安全说明：
  S26,S36/37/39
• 危险类别码：
  R36/37/38
• 危险性防范说明：
  P261,P301+P312,P302+P352,P304+P340,P305+P351+P338
• 危险性描述：
  H302,H315,H319,H335

制备方法与用途

化学性质：白色晶体，易溶于水，其水溶液呈弱碱性。

用途：氨基磺酸钠是生产甜味剂的主要原料。

反应信息

• 作为反应物：
  描述：

  钠氨基磺酸 以 neat (no solvent) 为溶剂， 生成 sodium imidosulfonate
  参考文献：
  名称：

  Parent, Yves, Bulletin de la Societe Chimique de France, 1984, vol. I, p. 60 - 64

  摘要：

  DOI：
• 作为产物：
  描述：

  氨基磺酸 在 sodium hydroxide 作用下， 以 sodium hydroxide 为溶剂， 生成 钠氨基磺酸
  参考文献：
  名称：

  Lusty, James R.; Peeling, James, Inorganic Chemistry, 1985, vol. 24, # 8, p. 1179 - 1182

  摘要：

  DOI：
• 作为试剂：
  描述：

  环戊二烯 在 sodium hypochlorite 、 钠氨基磺酸 作用下， 生成 六氯环戊二烯
  参考文献：
  名称：

  Chlorination of cyclopentadiene

  摘要：

  公开号：

  US02658085A1

文献信息

• Processes for preparing concentrated aqueous liquid biocidal compositions
  申请人：Albemarle Corporation

  公开号：US06348219B1

  公开（公告）日：2002-02-19

  The process involves (a) continuously forming bromine chloride from separate feed streams of bromine and chlorine by maintaining said streams under automatic feed rate control whereby the streams are continuously proportioned to come together to form bromine chloride; (b) continuously forming an aqueous product having an active bromine content of at least 100,000 ppm (wt/wt), a pH of at least 7, and an atom ratio of nitrogen to active bromine greater than 0.93:1 by continuously or intermittently feeding into mixing apparatus separate feed streams of (1) bromine chloride formed in (a), and (2) an aqueous solution of alkali metal salt of sulfamic acid, under automatic feed rate control.

  该过程涉及：(a) 通过保持溴和氯的独立进料流，在自动进料速率控制下连续形成溴氯化物，从而使这些流连续地按比例混合形成溴氯化物；(b) 通过连续或间歇地在混合设备中分别进料流(1) 在(a)中形成的溴氯化物，和(2) 磺酸铵盐碱金属的水溶液，在自动进料速率控制下，连续形成至少含有活性溴含量为100,000 ppm（重量/重量）、pH至少为7，并且氮原子与活性溴的比例大于0.93:1的水性产品。
• Continuous processes for preparing concentrated aqueous liquid biocidal composition
  申请人：Albemarle Corporation

  公开号：US06352725B1

  公开（公告）日：2002-03-05

  The process involves (a) continuously forming bromine chloride from separate feed streams of bromine and chlorine by maintaining said streams under automatic feed rate control whereby the streams are continuously proportioned to come together in equimolar amounts to form bromine chloride; (b) continuously forming an aqueous product having an active bromine content of at least 100,000 ppm (wt/wt), a pH of at least 7, and an atom ratio of nitrogen to active bromine greater than 0.93:1 by continuously feeding into mixing apparatus separate feed streams of (1) bromine chloride formed in (a), and (2) an aqueous solution of alkali metal salt of sulfamic acid, under automatic feed rate control whereby the feed streams are continuously proportioned to come together in amounts that produce an aqueous product having an active bromine content of at least 100,000 ppm (wt/wt), a pH of at least 7, and an atom ratio of nitrogen to active bromine from (1) and (2) greater than 0.93:1; and, (c) withdrawing said aqueous product from said mixing apparatus at a rate sufficient to enable the continuous feeding in (a) and (b) to be maintained.

  该过程涉及（a）通过保持溴和氯的分开进料流，并通过维持所述流在自动进料速率控制下，连续形成溴氯化物，使得这些流以等摩尔量连续配比在一起形成溴氯化物；（b）通过不断向混合设备进料分开的（1）在（a）中形成的溴氯化物和（2）磺酸氨盐的碱金属盐的水溶液，使得进料流在自动进料速率控制下，不断配比在一起，产生具有至少100,000 ppm（重量/重量）活性溴含量、至少7的pH值和氮原子与活性溴之比大于0.93:1的水溶液产品；以及（c）以足以使得在（a）和（b）中连续进料的速率维持的速率从所述混合设备中撤出所述水溶液产品。
• Methods for the preparation of concentrated aqueous bromine solutions and high activity bromine-containing solids
  申请人：Howarth N. Jonathan

  公开号：US20050249825A1

  公开（公告）日：2005-11-10

  The invention includes convenient methods of preparing: (1) highly concentrated liquid bromine-containing biocidal solutions, (2) highly concentrated mixed halogen liquid bromine and chlorine-containing biocidal solutions, and (3) high-activity bromine-containing biocidal solids, all having excellent physical and chemical stability. One method yields solutions that have concentrations of bromine in excess of 18% as Br 2 (8% as Cl 2 ) in which the mole ratio of hydroxide ion to hydrogen ion source is at least 1.9:1. Another method employs elemental bromine in conjunction with a solid organic or inorganic halogenating agent to yield halogen solutions at concentrations greater than 22.9% as Br 2 (10.2% as Cl 2 ). This method can be performed under conditions that exceed the solubility of the active ingredient such that it crystallizes and is recovered as a hydrated or anhydrous salt in good yield.

  该发明包括方便的制备方法：(1)高浓度液体溴含生物杀菌溶液，(2)高浓度混合卤素液体溴和氯含生物杀菌溶液，以及(3)高活性溴含生物杀菌固体，所有这些溶液具有优异的物理和化学稳定性。一种方法产生的溶液中，溴的浓度超过18%作为Br2（氯的浓度为8%），其中氢氧根离子与氢离子源的摩尔比至少为1.9:1。另一种方法利用元素溴与固体有机或无机卤化剂结合，产生浓度超过22.9%作为Br2（氯的浓度为10.2%）的卤素溶液。这种方法可以在超过活性成分溶解度的条件下进行，使其结晶并以水合盐或无水盐的形式高产得到。
• [EN] PREPARATION OF CONCENTRATED BROMINE SOLUTIONS AND HIGH ACTIVITY BROMINE SOLIDS<br/>[FR] PRÉPARATION DE SOLUTIONS DE BROME CONCENTRÉ ET DE SOLIDES DE BROME À FORTE ACTIVITÉ
  申请人：ENVIRO TECH CHEMICAL SERVICES

  公开号：WO2005112649A1

  公开（公告）日：2005-12-01

  The invention includes convenient methods of preparing: (1) highly concentrated liquid bromine-containing biocidal solutions, (2) highly concentrated mixed halogen liquid bromine and chlorine-containing biocidal solutions, and (3) high-activity bromine containing biocidal solids, all having excellent physical and chemical stability. One method yields solutions that have concentrations of bromine in excess of 18% as Br2 (8% as C12) in which the mole ratio of hydroxide ion to hydrogen ion source is at least 1.9: 1. Another method employs elemental bromine in conjunction with a solid organic or inorganic halogenating agent to yield halogen solutions at concentrations greater than 22.9% as Br2 (10.2% as C12). This method can be performed under conditions that exceed the solubility of the active ingredient such that it crystallizes and is recovered as a hydrated or anhydrous salt in good yield.

  该发明包括方便的制备方法：（1）高浓度液体溴含生物杀菌溶液，（2）高浓度混合卤素液体溴和氯含生物杀菌溶液，以及（3）高活性含溴生物杀菌固体，所有这些溶液均具有优异的物理和化学稳定性。一种方法产生的溶液中溴的浓度超过18%作为Br2（8%作为C12），其中氢氧根离子与氢离子源的摩尔比至少为1.9：1。另一种方法利用元素溴与固体有机或无机卤化剂结合，产生浓度大于22.9%作为Br2（10.2%作为C12）的卤素溶液。该方法可在超过活性成分的溶解度的条件下进行，使其结晶并以良好产率作为水合盐或无水盐回收。
• Biocides and apparatus
  申请人：Barak Ayala

  公开号：US20060154978A1

  公开（公告）日：2006-07-13

  There are provided methods for controlling microbial or bioflim growth, comprising mixing a hypochlorite oxidant and at least one nitrogen-containing compound or salt thereof selected from a particular group of nitrogen-containing compounds and salts to form a biocide, and applying the biocide. Apparatus for practicing the methods are also provided.

  提供了控制微生物或生物膜生长的方法，包括混合次氯酸氧化剂和至少一种从特定的一组氮化合物和盐中选择的含氮化合物或盐，以形成一种生物杀灭剂，并应用该生物杀灭剂。还提供了用于实施该方法的装置。

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