[Zn(N,N-dimethylcarbamate)2]n

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: [Zn(N,N-dimethylcarbamate)2]n
• 英文别名: zinc;N,N-dimethylcarbamate
• 化学式: 2C₃H₆NO₂*Zn
• 分子量: 241.562
• InChiKey: VFKVJOCCEVGAQU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.11
• 重原子数：
  7.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  43.37
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  [Zn(N,N-dimethylcarbamate)2]n 、 水 以 四氢呋喃 、 甲苯 为溶剂， 以51%的产率得到Zn4(μ-O)(N,N-dimethyaminocarbamate)6
  参考文献：
  名称：

  MATERIAL AND METHOD FOR CARBON DIOXIDE FIXATION

  摘要：

  [问题]提供一种在温和条件下高效固定二氧化碳的新方法。 [解决方案] 根据本发明，用于固定二氧化碳的材料包含金属离子供体和作为桥接配体前体的胺。胺可与气态二氧化碳反应，形成至少有一个氨基甲酸酯阴离子分子的桥接配体。桥联配体可与金属离子供体反应形成配位聚合物，其中多个金属离子通过桥联配体连接。

  公开号：

  US20230191366A1
• 作为产物：
  描述：

  [NH2Me2][Zn2(N,N-dimethylcarbamate)5]*2MeCN 以 neat (no solvent, solid phase) 为溶剂， 生成 [Zn(N,N-dimethylcarbamate)2]n
  参考文献：
  名称：

  N,N-dimethylcarbamato complexes of zinc

  摘要：

  By reaction of Zn4O(O2CNMe2)(6) (1) with [NH2Me2][O2CNMe2] in toluene as medium, the homoleptic zinc compound [Zn(O2CNMe2)(2)] (2) was obtained, which reverted back to the tetranuclear mu-oxo derivative by controlled hydrolysis. The reaction of ZnO in MeCN with an excess of [NH2Me2][O2CNMe2] in concentrated solution produced high yields of [Zn(O2CNMe2)(2)] (2) or [NH2Me2][Zn-2(O2CNMe2)(5)] center dot xMeCN, 3 center dot xMeCN, x = 1 or 2, depending on the experimental conditions. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.03.025

文献信息

• MATERIAL AND METHOD FOR CARBON DIOXIDE FIXATION
  申请人：Kyoto University

  公开号：US20230191366A1

  公开（公告）日：2023-06-22

  [Problem] To provide a new way for fixing carbon dioxide under mild conditions and with high efficiency. [Solution] The material for carbon dioxide fixation according to the present invention contains a metal ion donor and an amine as a precursor of a bridging ligand. The amine is configured to react with a gaseous carbon dioxide to form the bridging ligand having at least one carbamate anion moiety. The bridging ligand is configured to react with the metal ion donor to form a coordination polymer in which a plurality of the metal ions is linked by the bridging ligand.

  [问题]提供一种在温和条件下高效固定二氧化碳的新方法。 [解决方案] 根据本发明，用于固定二氧化碳的材料包含金属离子供体和作为桥接配体前体的胺。胺可与气态二氧化碳反应，形成至少有一个氨基甲酸酯阴离子分子的桥接配体。桥联配体可与金属离子供体反应形成配位聚合物，其中多个金属离子通过桥联配体连接。
• One-Pot, Room-Temperature Conversion of CO₂ into Porous Metal–Organic Frameworks
  作者：Kentaro Kadota、You-lee Hong、Yusuke Nishiyama、Easan Sivaniah、Daniel Packwood、Satoshi Horike

  DOI：10.1021/jacs.1c08227

  日期：2021.10.13
• N,N-dimethylcarbamato complexes of zinc
  作者：Daniela Belli Dell’Amico、Fausto Calderazzo、Luca Labella、Fabio Marchetti、Ilaria Mazzoncini

  DOI：10.1016/j.ica.2006.03.025

  日期：2006.7

  By reaction of Zn4O(O2CNMe2)(6) (1) with [NH2Me2][O2CNMe2] in toluene as medium, the homoleptic zinc compound [Zn(O2CNMe2)(2)] (2) was obtained, which reverted back to the tetranuclear mu-oxo derivative by controlled hydrolysis. The reaction of ZnO in MeCN with an excess of [NH2Me2][O2CNMe2] in concentrated solution produced high yields of [Zn(O2CNMe2)(2)] (2) or [NH2Me2][Zn-2(O2CNMe2)(5)] center dot xMeCN, 3 center dot xMeCN, x = 1 or 2, depending on the experimental conditions. (c) 2006 Elsevier B.V. All rights reserved.