tert-butyl peroxyundecanoate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: tert-butyl peroxyundecanoate
• 英文别名: t-Butyl peroxyundecanoate；tert-butyl undecaneperoxoate
• 化学式: C₁₅H₃₀O₃
• 分子量: 258.401
• InChiKey: IQASYAGDXLJOJH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  18
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  tert-butyl peroxyundecanoate 以70%的产率得到
  参考文献：
  名称：

  HOCAH B. H., BECTH. LVOV. POLITEXN. IN-TA, 1981, HO 149, 89-91

  摘要：

  DOI：
• 作为产物：
  描述：

  十一烷酸 在 吡啶 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 1.0h， 生成 tert-butyl peroxyundecanoate
  参考文献：
  名称：

  New synthesis of tert-butyl peroxycarboxylates

  摘要：

  tert-Butyl peroxyacetate, tert-butyl peroxybutyrate, tert-butyl phenylperoxyacetate, and tert-butyl peroxyundecanoate were obtained in nearly quantitative yields by the esterification of the corresponding carboxylic acids with tert-butyl hydroperoxide in the presence of trifluoroacetic anhydride and pyridine in nonaqueous medium at 0-5 degrees C. No terl-butyl peroxytrifluoroacetate was formed as a by-product during the process. A possible reaction mechanism is discussed.

  DOI：

  10.1134/s1070428006040026

文献信息

• Fuel compositions with enhanced combustion characteristics
  申请人：ETHYL PETROLEUM ADDITIVES, INC.

  公开号：EP0467628A1

  公开（公告）日：1992-01-22

  Reduction of the amount of atmospheric pollutants (NOx, CO, and/or hydrocarbons) formed on combustion of middle distillate fuels in engines or burner apparatus can be achieved, without concomitant increases in emissions ofparticulates, by fuels containing less than 500 ppm of sulfur and at least one peroxy ester combustion improver.

  通过含硫量低于 500 ppm 的燃料和至少一种过氧酯燃烧改进剂，可以减少发动机或燃烧器装置燃烧中间馏分燃料时形成的大气污染物（氮氧化物、一氧化碳和/或碳氢化合物）的数量，而不会同时增加微粒的排放量。
• US5405417A
  申请人：——

  公开号：US5405417A

  公开（公告）日：1995-04-11
• New synthesis of tert-butyl peroxycarboxylates
  作者：V. A. Donchak、S. A. Voronov、R. S. Yur’ev

  DOI：10.1134/s1070428006040026

  日期：2006.4

  tert-Butyl peroxyacetate, tert-butyl peroxybutyrate, tert-butyl phenylperoxyacetate, and tert-butyl peroxyundecanoate were obtained in nearly quantitative yields by the esterification of the corresponding carboxylic acids with tert-butyl hydroperoxide in the presence of trifluoroacetic anhydride and pyridine in nonaqueous medium at 0-5 degrees C. No terl-butyl peroxytrifluoroacetate was formed as a by-product during the process. A possible reaction mechanism is discussed.
• HOCAH B. H., BECTH. LVOV. POLITEXN. IN-TA, 1981, HO 149, 89-91
  作者：HOCAH B. H.

  DOI：——

  日期：——