(E)-1,2-dibromo-1-nonene

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: (E)-1,2-dibromo-1-nonene
• 化学式: C₉H₁₆Br₂
• 分子量: 284.034
• InChiKey: QEJQEMOEZIHRSA-CMDGGOBGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.98
• 重原子数：
  11.0
• 可旋转键数：
  6.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  1-壬炔 在 potassium permanganate 、 氢溴酸 作用下， 以 乙腈 为溶剂， 以85%的产率得到(E)-1,2-dibromo-1-nonene
  参考文献：
  名称：

  Reaction of Aromatic and Unsaturated Compounds with the Potassium Permanganate/HCl (HBr) Acetonitrile Reagent

  摘要：

  AbstractAddition of hydrochloric or hydrobromic acid to a solution of potassium permanganate in acetonitrile produced a homogeneous mixture, which is suitable for laboratory chlorination or bromination, respectively. Aromatic compounds more reactive than alkylbenzenes can be chlorinated or brominated without additional catalyst. Alkenes and alkynes give the corresponding vicinal dihaloalkanes and vinyl halides. All reactions complete within two hours under mild condition (25‐60 °C) with excellent to moderate yields.

  DOI：

  10.1002/jccs.199600010

文献信息

• Reaction of Aromatic and Unsaturated Compounds with the Potassium Permanganate/HCl (HBr) Acetonitrile Reagent
  作者：Lilian Kao Liu、Ching-Shan Lin

  DOI：10.1002/jccs.199600010

  日期：1996.2

  AbstractAddition of hydrochloric or hydrobromic acid to a solution of potassium permanganate in acetonitrile produced a homogeneous mixture, which is suitable for laboratory chlorination or bromination, respectively. Aromatic compounds more reactive than alkylbenzenes can be chlorinated or brominated without additional catalyst. Alkenes and alkynes give the corresponding vicinal dihaloalkanes and vinyl halides. All reactions complete within two hours under mild condition (25‐60 °C) with excellent to moderate yields.