夾可酸 | 470-53-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羟基酸及其衍生物
• 中文名称: 夾可酸
• 英文名称: Jaconecinsaeure
• 英文别名: (2R)-5t-((S)-1-hydroxy-ethyl)-2,3t-dimethyl-tetrahydro-furan-2r,5c-dicarboxylic acid；(2R)-5t-((S)-1-Hydroxy-aethyl)-2,3t-dimethyl-tetrahydro-furan-2r,5c-dicarbonsaeure；[2R-(2α,3β,5α,5(S*))]-tetrahydro-5-(1-hydroxyethyl)-2,3-dimethyl-2,5-furandicarboxylic acid；(2R,3R,5R)-5-[(1S)-1-hydroxyethyl]-2,3-dimethyloxolane-2,5-dicarboxylic acid
• CAS: 470-53-1
• 化学式: C₁₀H₁₆O₆
• 分子量: 232.233
• InChiKey: PGCOHQZPXWBFSZ-MLTZYSBQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  104
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  夾可酸 在 乙酸酐 作用下， 生成 (2R)-5t-((S)-1-acetoxy-ethyl)-2,3t-dimethyl-tetrahydro-furan-2r,5c-dicarboxylic acid-anhydride
  参考文献：
  名称：

  The Alkaloids of Senecio jacobaea L. IV. The Structures of Jacobine, Jaconine, Jacoline and their Constituent Acids

  摘要：

  DOI：

  10.1021/ja01528a045
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 barium dihydroxide 、 水 作用下， 生成 夾可酸
  参考文献：
  名称：

  Prototype Demonstration of a Stern Embarkation Platform for the AOE 6 Class: A Navy/Industry Partnership

  摘要：

  ABSTRACTThe US Navy is striving to reduce total ownership costs of the Fleet The operational and safety issues associated with several cases of loss or damage to AOE 6 class accommodation ladders, provided the opportunity to demonstrate the effectiveness of a Government‐Industry partnership and the application of proven commercial technology in reducing manpower requirements and life cycle cost, while maintaining mission capabilities of an existing U.S. Navy replenishment ship.

  DOI：

  10.1111/j.1559-3584.2000.tb03333.x

文献信息

• Bradbury; Willis, Australian Journal of Chemistry, 1956, vol. 9, p. 258,272
  作者：Bradbury、Willis

  DOI：——

  日期：——
• The Alkaloids of Senecio jacobaea L. IV. The Structures of Jacobine, Jaconine, Jacoline and their Constituent Acids
  作者：R. B. Bradbury、Satoru Masamune

  DOI：10.1021/ja01528a045

  日期：1959.10
• Prototype Demonstration of a Stern Embarkation Platform for the AOE 6 Class: A Navy/Industry Partnership
  作者：S. Grasso、D. Knowles、T. Schiller

  DOI：10.1111/j.1559-3584.2000.tb03333.x

  日期：2000.7

  ABSTRACTThe US Navy is striving to reduce total ownership costs of the Fleet The operational and safety issues associated with several cases of loss or damage to AOE 6 class accommodation ladders, provided the opportunity to demonstrate the effectiveness of a Government‐Industry partnership and the application of proven commercial technology in reducing manpower requirements and life cycle cost, while maintaining mission capabilities of an existing U.S. Navy replenishment ship.