N,N'-bis(2,6-diisopropylphenyl)-1,6,7,12-tetra-[4-(2-hydroxyethyl)phenoxy]perylene-3,4,9,10-tetracarboxylic acid diimide

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N'-bis(2,6-diisopropylphenyl)-1,6,7,12-tetra-[4-(2-hydroxyethyl)phenoxy]perylene-3,4,9,10-tetracarboxylic acid diimide
• 英文别名: 7,18-Bis[2,6-di(propan-2-yl)phenyl]-11,14,22,26-tetrakis[4-(2-hydroxyethyl)phenoxy]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2(26),3,5(25),9,11,13,15,20,23-decaene-6,8,17,19-tetrone
• 化学式: C₈₀H₇₄N₂O₁₂
• 分子量: 1255.47
• InChiKey: GNYOAULMSKFWIW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.7
• 重原子数：
  94
• 可旋转键数：
  22
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  193
• 氢给体数：
  4
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  N,N'-bis(2,6-diisopropylphenyl)-1,6,7,12-tetra-[4-(2-hydroxyethyl)phenoxy]perylene-3,4,9,10-tetracarboxylic acid diimide 、 2,2,5-trimethyl-1,3-dioxane-5-carboxylic anhydride 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 以90%的产率得到
  参考文献：
  名称：

  Design and synthesis of a fluorescent amino poly(glycidyl methacrylate) for efficient gene delivery

  摘要：

  通过原子转移自由基聚合（ATRP）和后聚合合成了一种荧光氨基聚（甲基丙烯酸缩水甘油酯）（PGOHMA）。PGOHMA 细胞毒性低，DNA 传输效率高。

  DOI：

  10.1039/c8tb02968g
• 作为产物：
  描述：

  对羟基苯乙醇 、 染料红620 在 potassium carbonate 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 12.0h， 以75%的产率得到N,N'-bis(2,6-diisopropylphenyl)-1,6,7,12-tetra-[4-(2-hydroxyethyl)phenoxy]perylene-3,4,9,10-tetracarboxylic acid diimide
  参考文献：
  名称：

  Functionalized perylene tetracarboxylic acid diimides

  摘要：

  本发明涉及将官能化的苝-3,4,9,10-四羧酸二亚胺作为引发剂和/或共反应剂用于聚合反应，涉及使用苝-3,4,9,10-四羧酸二亚胺化合物制备的聚合物，涉及使用这些有色和/或荧光聚合物，以及新型的官能化苝四羧酸二亚胺。

  公开号：

  US06916928B2

文献信息

• Synthesis and properties of fluorescent dyes conjugated to hyperbranched polyglycerols
  作者：Andrew T. Zill、Kai Licha、Rainer Haag、Steven C. Zimmerman

  DOI：10.1039/c1nj20476a

  日期：——

  polyglycerol hyperbranched polymers containing fluorescent labels (fluorescein or perylene diimide (PDI)) at their core are presented. The hyperbranched polyglycerol (HPG) precursors were synthesized using a one step polymerization reaction wherein the initiator leaves a single reactive group for dye functionalization. For further site isolation, allylated HPG was synthesized allowing cross-linking via ring

  聚合合成含荧光标记的聚甘油超支化聚合物（荧光素或以per二酰亚胺（PDI）为核心。使用一步聚合反应合成超支化聚甘油（HPG）前体，其中引发剂留下单个反应基团用于染料官能化。为了进一步分离位点，合成了烯丙基化的HPG，允许通过闭环复分解和随后的二羟基化进行交联，以生成水溶性的荧光纳米粒子。产生的染料显示出光稳定性的改善，水溶解度或量子产率，取决于所使用的染料和交联。这些荧光纳米粒子的性能优于掺入线性聚乙二醇（PEG）聚合物的类似染料。
• 자외선을 흡수하는 반응형 형광 염료 및 이를 포함하는 형광 아크릴 시트
  申请人：ICB CO., LTD (주)아이씨비(120040338195) Corp. No ▼ 180111-0479807BRN ▼605-81-65321

  公开号：KR20170084652A

  公开（公告）日：2017-07-20

  본 발명은 자외선을 흡수함과 동시에 반응기을 가지고 있는 형광 색소의 합성 및 이를 이용해 제작된 형광 아크릴 시트에 관한 것으로 내광성이 크게 향상된 형광 아크릴 시트를 제공한다. 본 발명에 사용된 형광 색소는 410nm 이하의 영역을 완벽히 흡수하는 나프탈이미드 계열 화합물과 공유결합되어 있을 뿐만 아니라 아크릴 모노머와 공중합될 수 있는 반응기를 가지고 있으므로 형광 색소가 아크릴 고분자 사슬에 화학결합된 형태로 존재 가능하여 형광 아크릴 시트의 문제점인 변색 현상이 현저히 개선된 고내구성 형광 아크릴 시트가 제공된다. 일반적으로 UV 흡수제는 형광 염료 대비 10 내지 50배 또는 그 이상 투입해야 하는데 반해, 본 발명에서는 UV 영역을 차단하는 화합물이 형광 색소와 1:1 비율로 공유 결합되어 있으므로 UV 흡수제의 투입량을 최소화해도 우수한 내광 특성을 확보할 수 있을 뿐만 아니라, UV 흡수제가 석출되거나 이동하는 현상을 억제 할 수 있어, 우수한 품질의 형광 아크릴 시트가 제공 가능하다.

  本发明涉及一种具有吸收紫外线并具有反应器的荧光染料的合成以及制造荧光丙烯酸板材的方法，提供了一种内发光性能大幅提高的荧光丙烯酸板材。本发明所使用的荧光染料不仅与完全吸收410nm以下范围的那酰亚胺类化合物结合，而且还具有与丙烯酸单体和可聚合的反应器结合的能力，因此荧光染料可以以化学结合的形式存在于丙烯酸高聚物链中，从而提供了明显改善色彩变化问题的高耐久性荧光丙烯酸板材。通常，UV吸收剂需要比荧光染料高出10到50倍甚至更多的用量，而在本发明中，由于吸收UV区域的化合物与荧光染料以1:1的比例结合，因此即使减少UV吸收剂的用量，也可以确保出色的内发光特性，同时还可以抑制UV吸收剂的析出或迁移现象，从而提供优质的荧光丙烯酸板材。
• HIGHLY EFFICIENT MOLECULES SHOWING RESONANT ENERGY TRANSFER
  申请人：PHILIPS LIGHTING HOLDING B.V.

  公开号：US20170268746A1

  公开（公告）日：2017-09-21

  The invention provides a lighting device comprising a light source configured to provide light source light having a blue light component and a light converter configured to convert at least part of the light source light into converter light, wherein the light converter comprises a polymeric matrix ( 22 ) with a luminescent material, wherein the luminescent material comprises a luminescent molecule ( 300 ) comprising a first group ( 310 ) able to absorb at least part of the blue light component, and a second group ( 320 ) able to emit luminescent molecule light having a red light component, wherein the first group ( 310 ) is configured to transfer at least part of the energy acquired by the absorption of said blue light component to the second group ( 320 ) for generation of said luminescent molecule light having a red light component.
• Functionalized perylene tetracarboxylic acid diimides
  申请人：Becker Stefan

  公开号：US06916928B2

  公开（公告）日：2005-07-12

  The present invention relates to the use of functionalized perylene-3,4,9,10-tetracarboxylic acid diimides as initiator and/or co-reactant for polymerization reactions, to polymers prepared using the perylene-3,4,9,10-tetracarboxylic acid diimide compounds, to the use of these colored and/or fluorescent polymers, and to novel functionalized perylenetetracarboxylic acid diimides.

  本发明涉及将官能化的苝-3,4,9,10-四羧酸二亚胺作为引发剂和/或共反应剂用于聚合反应，涉及使用苝-3,4,9,10-四羧酸二亚胺化合物制备的聚合物，涉及使用这些有色和/或荧光聚合物，以及新型的官能化苝四羧酸二亚胺。
• Design and synthesis of a fluorescent amino poly(glycidyl methacrylate) for efficient gene delivery
  作者：Hongtao Chen、Shusen You、Qing Cai、Yang Zheng、Liqun Zhang、Jie Shen、Meizhen Yin

  DOI：10.1039/c8tb02968g

  日期：——

  A fluorescent amino poly(glycidyl methacrylate) (PGOHMA) was synthesized by atom transfer radical polymerization (ATRP) and post-polymerization. PGOHMA has low cytotoxicity and high DNA delivery efficiency.

  通过原子转移自由基聚合（ATRP）和后聚合合成了一种荧光氨基聚（甲基丙烯酸缩水甘油酯）（PGOHMA）。PGOHMA 细胞毒性低，DNA 传输效率高。