(1-甲基丁基)-环氧乙烷 | 53229-39-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 中文名称: (1-甲基丁基)-环氧乙烷
• 中文别名: 2-(戊烷-2-基)噁丙环
• 英文名称: 2-(pentan-2-yl)oxirane
• 英文别名: 1,2-Epoxy-3-methyl-hexan；(1-methyl-butyl)-oxirane；(1-Methylbutyl)oxirane；2-pentan-2-yloxirane
• CAS: 53229-39-3
• 化学式: C₇H₁₄O
• 分子量: 114.188
• InChiKey: YJNBGESTCBYXQO-UHFFFAOYSA-N

物化性质

• 沸点：
  125.0±8.0 °C(Predicted)
• 密度：
  0.882±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-甲基-1-己烯 在 tris-(2,2'-bipyridine)ruthenium(II) chloride 、 hexaamminecobalt (III) chloride 、 C₂₆H₂₈N₄*2CF₃O₃S^(1-)*Mn⁽²⁺⁾ 、 水 、 溶剂黄146 作用下， 以 乙腈 为溶剂， 反应 4.0h， 以52%的产率得到(1-甲基丁基)-环氧乙烷
  参考文献：
  名称：

  在单核非血红素手性锰配合物存在下以水为氧源光催化不对称环氧化末端烯烃

  摘要：

  使用单核非血红素手性锰催化剂 [(R,R-BQCN)MnII]2+ 和水作为氧源对末端烯烃进行光催化对映选择性环氧化，产生具有相对较高对映选择性（例如，对映体过量达 60%）的环氧化物）。合成的单核非血红素手性 Mn(IV)-氧配合物 [(R,R-BQCN)MnIV(O)]2+ 在化学计量反应条件下端烯烃的环氧化中提供了类似的对映选择性。在激光闪光光解和其他光谱方法的组合结果的基础上，讨论了光诱导催化每个单独步骤的机制细节，包括 Mn(IV)-氧代中间体的形成。

  DOI：

  10.1021/jacs.6b10836

文献信息

• Process for producing 1,3-dialkyl-2-imidazolidinone compound
  申请人：——

  公开号：US20030009035A1

  公开（公告）日：2003-01-09

  There is provided a process for preparing a 1,3-dialkyl-2-imidazolidinone by using an alkylene oxide as a first component, using at least one of (A) carbon dioxide and a monoalkylamine; (B) a carbon dioxide compound of the monoalkylamine; and (C) an 1,3-dialkylurea, reacting the first and second components by heating at 50 ° C. or higher to give 1,3-dialkyl-2-imidazolidinone, characterized in that the total molar amount of a molar feed amount of the monoalkylamine included in the component (A), a molar feed amount of the monoalkylamine part of the carbon dioxide compound of monoalkylamine, component (B), and the double of a molar feed amount of the 1,3-dialkylurea, component (C), is at least three folds of a molar feed amount of the alkylene oxide. The preparation process of this invention uses an industrially readily available alkylene oxide as a starting material and can be suitably conducted with a higher yield in an industrial scale.

  提供了一种制备1,3-二烷基-2-咪唑烷酮的方法，该方法使用乙烯氧化物作为第一组分，至少使用以下之一：（A）二氧化碳和一种单烷基胺；（B）单烷基胺的二氧化碳化合物；和（C）1,3-二烷基脲，通过加热至50°C或更高温度来使第一和第二组分反应，得到1,3-二烷基-2-咪唑烷酮，其特点是：单烷基胺的摩尔进料量包括在组分（A）中的单烷基胺的摩尔进料量，单烷基胺的二氧化碳化合物中的单烷基胺部分的摩尔进料量，组分（B），以及1,3-二烷基脲的摩尔进料量的两倍，组分（C），至少是乙烯氧化物的摩尔进料量的三倍。这种发明的制备过程使用工业上易得的乙烯氧化物作为起始物质，并且可以在工业规模上以更高的产率进行适当的操作。
• Modified ethylene-vinyl alcohol copolymer and method for the production thereof
  申请人：——

  公开号：US20040096683A1

  公开（公告）日：2004-05-20

  Provided is a modified ethylene-vinyl alcohol copolymer (C) having an ethylen content of 5 to 55 mol %, which contains a specific structural unit (I) in an amount of 0.3 to 40 mol % and may be obtained by reacting an ethylene-vinyl alcohol copolymer (A) with a monofunctional epoxy compound (B) having a molecular weight of not more than 500. This can be produced by a method for producing the modified ethylene-vinyl alcohol copolymer (C) which comprises melting and kneading an ethylene-vinyl alcohol copolymer (A) with a monofunctional epoxy compound (B) in an extruder. The modified ethylene-vinyl alcohol copolymer (C) is superior to a unmodified ethylene-vinyl alcohol copolymer (A) in transparency, stretchability, flexibility and flexing resistance due to the specific structural unit (I) incorporated therein, and thus, can be used as a barrier material in various applications requiring the above performance capabilities.

  提供的是一种改性乙烯-醋酸乙烯共聚物(C)，其乙烯含量为5至55摩尔％，其中含有一种特定的结构单元(I)，其含量为0.3至40摩尔％，可通过将乙烯-醋酸乙烯共聚物(A)与分子量不超过500的单官能环氧化合物(B)反应而获得。该改性乙烯-醋酸乙烯共聚物(C)的制备方法包括在挤出机中熔融和揉捏乙烯-醋酸乙烯共聚物(A)与单官能环氧化合物(B)。由于其中包含了特定的结构单元(I)，改性乙烯-醋酸乙烯共聚物(C)在透明度、可伸展性、柔韧性和耐弯曲性方面优于未改性的乙烯-醋酸乙烯共聚物(A)，因此可以用作在需要上述性能能力的各种应用中的障壁材料。
• Resin composition and multi-layer structures
  申请人：Tai Shinji

  公开号：US20050147778A1

  公开（公告）日：2005-07-07

  Provided is a resin composition comprising 1-99% by weight of a modified ethylene-vinyl alcohol copolymer (C) having an ethylene content of 5-55 mol %, which contains a specific structural unit (I) in an amount of 0.3-40 mol % and can be obtained by reacting an ethylene-vinyl alcohol copolymer (A) with a monofunctional epoxy compound (B) having a molecular weight of not more than 500, and 1-99% by weight of a thermoplastic resin (T 1 ) other than (C). Moreover, a multilayer structure in which the resin composition and a thermoplastic resin (T 2 ) are laminated is also provided. Thus, a resin composition superior in barrier properties, transparency, stretchability, flexibility, flexing resistance and interlayer adhesiveness and various kinds of molded articles made thereof are provided.

  本发明提供了一种树脂组合物，包括重量百分比为1-99%的改性乙烯-醇酸共聚物(C)，该共聚物的乙烯含量为5-55摩尔％，其中含有特定的结构单元(I)，其含量为0.3-40摩尔％，可以通过将乙烯-醇酸共聚物(A)与分子量不超过500的单官能环氧化合物(B)反应而获得，以及重量百分比为1-99%的热塑性树脂(T1)，该树脂组合物和热塑性树脂(T2)层压形成多层结构。因此，提供了一种优异的阻隔性、透明性、可拉伸性、柔韧性、耐弯曲性和层间粘附性的树脂组合物及其各种成型制品。
• MODIFIED ETHYLENE-VINYL ALCOHOL COPOLYMER AND METHOD FOR THE PRODUCTION THEREOF
  申请人：IKEDA Kaoru

  公开号：US20100280178A1

  公开（公告）日：2010-11-04

  Provided is a modified ethylene-vinyl alcohol copolymer (C) having an ethylen content of 5 to 55 mol %, which contains a specific structural unit (I) in an amount of 0.3 to 40 mol % and may be obtained by reacting an ethylene-vinyl alcohol copolymer (A) with a monofunctional epoxy compound (B) having a molecular weight of not more than 500. This can be produced by a method for producing the modified ethylene-vinyl alcohol copolymer (C) which comprises melting and kneading an ethylene-vinyl alcohol copolymer (A) with a monofunctional epoxy compound (B) in an extruder. The modified ethylene-vinyl alcohol copolymer (C) is superior to a unmodified ethylene-vinyl alcohol copolymer (A) in transparency, stretchability, flexibility and flexing resistance due to the specific structural unit (I) incorporated therein, and thus, can be used as a barrier material in various applications requiring the above performance capabilities.

  提供的是一种改性乙烯-醇酸共聚物（C），其乙烯含量为5至55摩尔％，其中含有特定的结构单元（I），其量为0.3至40摩尔％，可以通过将乙烯-醇酸共聚物（A）与分子量不超过500的单官能环氧化合物（B）反应而获得。可以通过在挤出机中熔融和揉捏乙烯-醇酸共聚物（A）和单官能环氧化合物（B）来生产改性乙烯-醇酸共聚物（C）。由于其中包含了特定的结构单元（I），改性乙烯-醇酸共聚物（C）在透明度、可伸展性、柔韧性和弯曲抗力方面优于未改性的乙烯-醇酸共聚物（A），因此可以用作需要上述性能能力的各种应用中的障壁材料。
• PROCESS FOR PRODUCING 1,3-DIALKYL-2-IMIDAZOLIDINONE COMPOUND
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1279667A1

  公开（公告）日：2003-01-29

  There is provided a process for preparing a 1,3-dialkyl-2-imidazolidinone by using an alkylene oxide as a first component, using at least one of (A) carbon dioxide and a monoalkylamine; (B) a carbon dioxide compound of the monoalkylamine; and (C) an 1,3-dialkylurea, reacting the first and second components by heating at 50 °C or higher to give 1, 3-dialkyl-2-imidazolidinone, characterized in that the total molar amount of a molar feed amount of the monoalkylamine included in the component (A) , a molar feed amount of the monoalkylamine part of the carbon dioxide compound of monoalkylamine, component (B), and the double of a molar feed amount of the 1, 3-dialkylurea, component (C), is at least three folds of a molar feed amount of the alkylene oxide. The preparation process of this invention uses an industrially readily available alkylene oxide as a starting material and can be suitably conducted with a higher yield in an industrial scale.

  本发明提供了一种制备 1，3-二烷基-2-咪唑烷酮的工艺，该工艺以环氧亚 烷为第一组分，使用 (A) 二氧化碳和单烷基胺；(B) 单烷基胺的二氧化碳化合物；和 (C) 1，3-二烷基脲中的至少一种；和 (C) 1，3-二烷基脲，通过在 50℃或更高温度下加热使第一和第二组分反应，得到 1，3-二烷基-2-咪唑烷酮，其特征在于，组分 (A) 中包含的单烷基胺的摩尔进料总量 、单烷基胺二氧化碳化合物的单烷基胺部分的摩尔进料量，组分(B)，以及 1，3-二烷基脲的摩尔进料量的双倍，组分(C)，至少是环氧亚烷基摩尔进料量的三倍。 本发明的制备工艺使用工业上容易获得的环氧亚烷烃作为起始原料，可以适当地在工业规模上以更高的产率进行。