己酸十二酯 | 6938-60-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 己酸十二酯
• 英文名称: Hexansaeure-dodecylester
• 英文别名: Duodecylcapronat；hexanoic acid dodecyl ester；Dodecyl hexanoate
• CAS: 6938-60-9
• 化学式: C₁₈H₃₆O₂
• 分子量: 284.483
• InChiKey: NZKTXIRCNHDQKO-UHFFFAOYSA-N

物化性质

• 溶解度：
  可溶于氯仿（少许）、甲醇（少许）
• 保留指数：
  1966

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  20
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  己酸十二酯 、 alkaline earth salt of/the/ methylsulfuric acid 225.0 ℃ 、19.61 MPa 条件下， 生成 正己醇
  参考文献：
  名称：

  Folkers; Adkins, Journal of the American Chemical Society, 1932, vol. 54, p. 1146

  摘要：

  DOI：
• 作为产物：
  描述：

  十二烷醇 、 己酸 在 对甲苯磺酸 作用下， 生成 己酸十二酯
  参考文献：
  名称：

  Paquot et al., Ind.chim.belge Sonderband 27.Congr.int.Chim.ind.Bruessel 1954,Bd.3,S.727

  摘要：

  DOI：

文献信息

• Maleated vegetable oils and derivatives, as self-emulsifying lubricants in metalworking
  申请人：Lange Richard M.

  公开号：US20090209441A1

  公开（公告）日：2009-08-20

  A succinated triglyceride oil derived from maleating triglyceride oil from a plant or land animal is described for use as an emulsifying agent for metalworking fluids. The metalworking fluid would comprise water; as an emulsifier this succinated triglyceride, optionally further reacted with water, Group IA and IIA metals, ammonium hydroxide, various amines, alkanolamines, alkoxylated alkanolamines, and polyamines to form a modified emulsifier; and optionally an oil and other additives.

  一种从植物或陆地动物中制得的马来化甘油三酯油，用作金属加工液的乳化剂。该金属加工液包括水；作为乳化剂的这种琥珀酸酯化甘油，可选择进一步与水、IA和IIA族金属、氢氧化铵、各种胺、烷基胺、烷氧基化烷基胺和多胺反应，形成改性乳化剂；并可选择添加油和其他添加剂。
• Compositions containing derivatives of succinic acylating agent or hydroxyaromatic compounds and methods of using the same
  申请人：THE LUBRIZOL CORPORATION

  公开号：EP0561601A2

  公开（公告）日：1993-09-22

  This invention relates to a composition comprising: a mixture of a brine and a liquid oil, and (A) an emulsifying amount of (i) at least one reaction product of a hydrocarbyl-substituted succinic acylating agent, and at least one of (a) ammonia, (b) an alcohol, (c) an amine, (d) or mixtures thereof, or at least one salt of the reaction product; or (ii) at least one reaction product of a hydroxyaromatic compound, an aldehyde, and an amine. The compositions of the present invention have beneficial emulsification properties. These compositions are useful in drilling, workingover and completing well-bore holes. The well-drilling compositions of the present invention have beneficial viscosity, pumping and suspension properties.

  本发明涉及一种组合物，包括：盐水和液态油的混合物，以及(A)以下物质的乳化量：(i) 至少一种烃基取代的琥珀酰化剂与(a)氨、(b)醇、(c)胺、(d)或其混合物中至少一种的反应产物，或反应产物的至少一种盐；或(ii)至少一种羟基芳香族化合物、醛和胺的反应产物。本发明的组合物具有良好的乳化性能。这些组合物可用于钻井、修井和完成井孔作业。本发明的钻井组合物具有良好的粘度、泵送和悬浮特性。
• Compositions containing esters of carboxy-containing interpolymers and methods of using the same
  申请人：THE LUBRIZOL CORPORATION

  公开号：EP0561608A2

  公开（公告）日：1993-09-22

  This invention relates to a composition comprising a mixture of a brine and a liquid oil, and (A) a viscosity increasing amount of at least one ester of a carboxy-containing interpolymer or salt thereof wherein the interpolymer is prepared by polymerizing an olefin selected from the group consisting of alpha-olefins and vinyl aromatic monomers with at least one alpha, beta-unsaturated carboxylic acylating agent, and provided that when the olefin is vinyl toluene, then the alpha, beta-unsaturated carboxylic acylating agent is an alpha, beta-unsaturated dicarboxylic acylating agent. The compositions of the present invention are useful as drilling fluids as well as completion fluids. The esters of the carboxy-containing interpolymer or salts thereof provide beneficial viscosity, formation stabilization, emulsification and rheology properties to the fluids.

  本发明涉及一种组合物，该组合物包含盐水和液态油的混合物，以及(A) 至少一种增粘剂量的含羧基互聚物的酯或其盐，其中互聚物的制备方法是从α-烯烃和乙烯基芳香族单体组成的组中选出的烯烃与至少一种α、当烯烃为乙烯基甲苯时，α，β-不饱和羧酸酰化剂为α，β-不饱和二羧酸酰化剂。本发明的组合物可用作钻井液和完井液。含羧基互聚物的酯类或其盐类可为钻井液提供有益的粘度、地层稳定、乳化和流变特性。
• Compositions containing combinations of surfactants and derivatives of succinic acylating agent or hydroxyaromatic compounds and methods of using the same
  申请人：THE LUBRIZOL CORPORATION

  公开号：EP0561607A2

  公开（公告）日：1993-09-22

  This invention relates to a composition comprising a mixture of a brine and a liquid oil, and (A) an emulsifying amount of (i) at least one reaction product of a hydrocarbyl-substituted succinic acylating agent, and at least one of (a) ammonia, (b) an alcohol, or (c) an amine, or at least one salt of the reaction product; or (ii) at least one reaction product of a hydroxyaromatic compound, an aldehyde, and an amine, and (B) at least one surfactant selected from the group consisting of a polyoxyalkylene amine, a polyoxyalkylene amide, a polyoxyalkylene alcohol, a polyoxyalkylene phenol, a polyoxyalkylene ester, a fatty acid salt, an amine or an alkaline earth or transition metal sulfonate, or a reaction product or a hydroxyamine or a polyalkylenepolyamine with an acylating agent selected from the group consisting of a fatty monocarboxylic acylating agents, a dicarboxylic acylating agent other than a succinic acylating agent, and a tricarboxylic acylating agent. The compositions of the present invention have beneficial emulsion and viscosity properties. These compositions are useful in drilling, working and completing well bore holes. The compositions of the present invention have beneficial viscosity, pumping and suspension properties. These compositions are stable. The surfactants of the compositions act as wetting agents for barites and organophilic clays. The surfactants may also act as an emulsifier as well as a wetting agent.

  本发明涉及一种组合物，该组合物包括盐水和液体油的混合物，以及(A)以下物质的乳化量：(i) 至少一种烃基取代的琥珀酰化剂与(a)氨、(b)醇或(c)胺中至少一种的反应产物，或该反应产物的至少一种盐；或 (ii) 至少一种羟基芳香族化合物、醛和胺的反应产物，以及 (B) 至少一种表面活性剂，该表面活性剂选自由聚氧亚烷基胺、聚氧亚烷基酰胺、聚氧亚烷基醇、聚氧亚烷基酚、聚氧亚烷基酯、脂肪酸盐组成的组、胺或碱土金属或过渡金属磺酸盐，或羟胺或聚亚烷基多胺与酰化剂的反应产物，酰化剂选自脂肪一羧酸酰化剂、二羧酸酰化剂（琥珀酸酰化剂除外）和三羧酸酰化剂组成的组。本发明的组合物具有良好的乳化和粘度特性。这些组合物可用于钻井、修井和完井。本发明的组合物具有良好的粘度、泵送和悬浮特性。这些组合物具有稳定性。组合物中的表面活性剂可作为重晶石和亲有机粘土的润湿剂。表面活性剂还可用作乳化剂和润湿剂。
• Sulfonate containing copolymers as mist suppressants in water-based metal working fluids
  申请人：The Lubrizol Corporation

  公开号：EP0811677A2

  公开（公告）日：1997-12-10

  Aqueous metal working fluids containing a mist suppressing copolymer are disclosed. The copolymer includes hydrophobic and hydrophilic monomers. Optionally, the metal working fluid may be an oil-in-water emulsion.

  本发明公开了含有抑雾共聚物的含水金属加工液。共聚物包括疏水性单体和亲水性单体。可选地，金属加工液可以是水包油型乳液。

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