(4-甲基环己基)丙-2-烯酸酯 | 16491-65-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: (4-甲基环己基)丙-2-烯酸酯
• 英文名称: acrylic acid-(4-methyl-cyclohexyl ester)
• 英文别名: Acrylsaeure-(4-methyl-cyclohexylester)；4-Acryloyloxy-1-methyl-cyclohexan；(4-Methyl-cyclohexyl)-acrylat；4-Methylcyclohexyl prop-2-enoate；(4-methylcyclohexyl) prop-2-enoate
• CAS: 16491-65-9
• 化学式: C₁₀H₁₆O₂
• 分子量: 168.236
• InChiKey: RXOMMEFYXLIGTD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-甲基环己醇 、 丙烯酸甲酯（MA） 在 diamylhydroquinone 、 硫酸 作用下， 生成 (4-甲基环己基)丙-2-烯酸酯
  参考文献：
  名称：

  Acrylic esters of secondary alcohols

  摘要：

  公开号：

  US02445925A1

文献信息

• ALPHA-SUBSTITUTED ACRYLATE ESTERS, COMPOSITION CONTAINING THEREOF, AND METHOD FOR PRODUCING THOSE
  申请人：Kawamoto Takahiro

  公开号：US20130072712A1

  公开（公告）日：2013-03-21

  A method for producing α-substituted acrylate esters is provided which can be suitably used as an industrial method for producing α-substituted acrylate esters because the method does not have problems of apparatus corrosion or does not require waste detoxification and allows reaction in a short time with high yield. The method for producing an α-substituted acrylate ester includes a step of carrying out a reaction of a compound having a specific structure and an active hydrogen-containing compound under a condition where a tertiary amine and an acid and/or a salt thereof coexist.

  提供了一种生产α-取代丙烯酸酯的方法，该方法可适当用作工业生产α-取代丙烯酸酯的方法，因为该方法不存在设备腐蚀问题或不需要废物解毒，并允许在短时间内高产率反应。生产α-取代丙烯酸酯的方法包括在三级胺和酸和/或其盐共存的条件下，进行具有特定结构和含有活性氢的化合物的反应的步骤。
• Polarizing plate and liquid crystal display apparatus using the same
  申请人：Takebe Takashi

  公开号：US20070048459A1

  公开（公告）日：2007-03-01

  A polarizing plate includes two transparent supports A and B; and a polarizer sandwiched between the two transparent supports A and B; wherein (i) the transparent support A is a stretched cellulose ester film (a) which contains a non-phosphoric acid ester plasticizer and substantially does not contain a phosphoric acid ester plasticizer, and wherein (ii) the transparent support B is a stretched cellulose ester film (b) which has a retardation value R 0 of from 0 nm to 10 nm and a retardation value R t of from −30 nm to 20 nm, and the retardation value R 0 and the retardation value R t are defined by the following formulas (I) and (II): Ro =( nx−ny )× d Formula (I): Rt =( nx+ny )/2− nz}×d. Formula (II):

  一个偏振板包括两个透明支撑体A和B；以及夹在两个透明支撑体A和B之间的偏振器；其中(i)透明支撑体A是一种拉伸纤维素酯薄膜(a)，它包含一种非磷酸酯增塑剂，且基本不含磷酸酯增塑剂；而(ii)透明支撑体B是一种拉伸纤维素酯薄膜(b)，其具有从0纳米到10纳米的延迟值R0和从-30纳米到20纳米的延迟值Rt，其中延迟值R0和延迟值Rt由以下公式(I)和(II)定义：Ro=(nx-ny)×d公式(I)：Rt=(nx+ny)/2-nz}×d。公式(II)：
• Cellulose Ester Film, Light Diffusing Film, Polarizing Plate, and Liquid Crystal Display
  申请人：Suzuki Shinichiro

  公开号：US20100233389A1

  公开（公告）日：2010-09-16

  Disclosed is a cellulose ester film which, when used in a polarizing plate, can impart excellent dimensional stability, curling properties and surface properties to the polarizing plate. Also disclosed is a light-scattering-film, a polarizing plate or a liquid crystal display element which is produced by using the cellulose ester film, and therefore has more excellent optical anisotropy, higher surface properties and a smoother surface, causes less curling, and has good surface quality. The cellulose ester film comprises 1 to 50% by mass (inclusive) of microparticles having an average particle diameter of 1 to 400 nm (inclusive) and a compound showing negative birefringence in the direction of drawing, and has a retardation value (R 0 ) defined by the equation (I) of 0 to 5 nm (inclusive) and a retardation value (R t ) defined by the equation (II) of −10 to 20 nm (inclusive), both measured at 23° C. and 55% RH: Equation (I): R 0 =(nx−ny)×d; and Equation (II): R t =[(nx+ny)/2×nz]×d.

  本发明涉及一种纤维素酯膜，当用于偏光板时，能够赋予偏光板优异的尺寸稳定性、卷曲性和表面性能。本发明还涉及一种光散射膜、偏光板或液晶显示元件，其通过使用所述纤维素酯膜制备而成，因此具有更优异的光学各向异性、更高的表面性能和更平滑的表面，引起的卷曲更少，表面质量良好。所述纤维素酯膜包括质量分数为1%至50%（含）的平均粒径为1至400纳米（含）的微粒子和在拉伸方向上显示负双折射的化合物，并且在23℃和55%相对湿度下测量的延迟值（R0）由公式（I）定义为0至5纳米（含），延迟值（Rt）由公式（II）定义为-10至20纳米（含）：公式（I）：R0 =（nx-ny）×d; 公式（II）：Rt = [(nx + ny) / 2×nz]×d。
• Polyolefin resin composition and oriented film therefrom
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0791625A2

  公开（公告）日：1997-08-27

  A polyolefin resin composition comprising: (a) 100 parts by weight of a polyolefin resin; and (b) 0.05 to 1 part by weight of beads of a crosslinked polymer comprising (1) 5 to 99% by weight of a radically polymerizable monomer unit of formula (A): wherein R1 is hydrogen or a hydrocarbon group having 1 to 5 carbon atoms and R2 is a hydrocarbon group having 5 to 30 carbon atoms, (2) 0 to 94% by weight of a radically polymerizable monomer unit other than the monomer unit of formula (A), and (3) 1 to 20% by weight of a crosslinkable monomer unit, the percentages being measured relative to the total weight of components (1), (2) and (3), said crosslinked polymer beads having a critical surface tension of 40 dyne/cm or less.

  一种聚烯烃树脂组合物，包括：(a)100 重量份的聚烯烃树脂；和(b)0.05 至 1 重量份的交联聚合物微珠，其中包括(1)5 至 99%重量份的式(A)可辐射聚合单体单元： 其中 R1 是氢或具有 1 至 5 个碳原子的烃基，R2 是具有 5 至 30 个碳原子的烃基；(2) 0 至 94%(重量)的式(A)单体单元以外的可辐射聚合单体单元；(3) 1 至 20%(重量)的可交联单体单元，这些百分比是相对于组分(1)、(2)和(3)的总重量而言的，所述交联聚合物珠的临界表面张力为 40 达因/厘米或更小。
• Ink composition for inkjet-recording and method for inkjet-recording
  申请人：FUJIFILM Corporation

  公开号：EP1927477A1

  公开（公告）日：2008-06-04

  An ink composition for inkjet-recording, which shows a high sensitivity to irradiation with actinic radiation and is able to form an image with superior curability, permitting the image formed after curing to have sufficient adhesiveness to a recording medium, as well as to have excellent flexibility in the formed image portion, and an inkjet-recording method using the same is provided: wherein the ink composition for inkjet-recording comprises (A) a compound having a polymerizable unsaturated bond and a cyclic amine structure in the molecule, (B) a compound having a polymerizable unsaturated bond and an alicyclic structure in the molecule, and (C) a radical polymerization initiator.

  本发明提供了一种喷墨记录用墨水组合物，该组合物对阳极辐射照射具有高灵敏度，能够形成具有优异固化性的图像，使固化后形成的图像对记录介质具有足够的粘附性，并使形成的图像部分具有优异的柔韧性，还提供了使用该组合物的喷墨记录方法： 其中用于喷墨记录的墨水组合物包括 (A) 分子中具有可聚合不饱和键和环胺结构的化合物，(B) 分子中具有可聚合不饱和键和脂环结构的化合物，以及 (C) 自由基聚合引发剂。