3-iminophthalide | 484-90-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异香豆素
• 英文名称: 3-iminophthalide
• 英文别名: 3-Imino-2-benzofuran-1-one
• CAS: 484-90-2
• 化学式: C₈H₅NO₂
• 分子量: 147.133
• InChiKey: SGMXPKAFOKYPKA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  50.2
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3-azido-phthalide 以 xylene 为溶剂， 以73%的产率得到3-iminophthalide
  参考文献：
  名称：

  Takeuchi, Hisato; Eguchi, Shoji, Journal of the Chemical Society. Perkin transactions I, 1988, p. 2149 - 2154

  摘要：

  DOI：

文献信息

• N-Heterocyclylphthaldiamides as Insecticides
  申请人：Fischer Rudiger

  公开号：US20090023752A1

  公开（公告）日：2009-01-22

  New N-heterocyclylphthaldiamides of structure (I) in which n, A, Q 1 , Q 2 , R 1 and X have the meanings given in the description, several methods for the preparation of these substances and their use for the control of pests, as well as new intermediates and methods for their preparation.

  新的N-杂环基酞酰二胺化合物（I）的结构中，其中n，A，Q1，Q2，R1和X具有描述中给出的含义，提供了几种制备这些物质的方法以及它们用于控制害虫的用途，还提供了新的中间体和制备它们的方法。
• METHOD OF PRODUCING A METAL PHTHALOCYANINE COMPOUND, AND METHOD OF PRODUCING A PHTHALOCYANINE COMPOUND AND AN ANALOGUE THEREOF
  申请人：Tateishi Keiichi

  公开号：US20090247742A1

  公开（公告）日：2009-10-01

  A method of producing a metal phthalocyanine compound, which contains: conducting a reaction between at least two compounds selected from among Compounds A to F of formula (I), and a metal compound, in a buffer solution of an organic base or an inorganic base and an acid, in the presence of a dehydrating agent: wherein R is a hydrogen atom or a substituent; l is an integer of 0 to 4; a plurality of Rs may be the same or different from each other when l is 2 to 4; and G is a group of atoms necessary for forming at least one of a 5- or 6-membered aromatic ring and a 5- or 6-membered hetero ring.

  生产金属酞菁化合物的方法，包括：在有机碱或无机碱和酸的缓冲溶液中，在脱水剂的存在下，将公式（I）中的至少两种化合物A至F和金属化合物反应，其中R是氢原子或取代基；l是0到4的整数；当l为2到4时，多个R可以相同或不同；G是必要的原子团，用于形成5或6元芳香环和5或6元杂环中的至少一个。
• TONER, DEVELOPER, IMAGE FORMING APPARATUS, AND PROCESS CARTRIDGE
  申请人：SUGIMOTO Tsuyoshi

  公开号：US20160259257A1

  公开（公告）日：2016-09-08

  A toner includes a polyester resin including a polyester resin component A (A) insoluble in tetrahydrofuran; and a polyester resin component B (B) soluble in tetrahydrofuran. The toner has a first glass transition temperature (Tg1st) of from 20° C. to 50° C., measured at a first temperature rising in differential scanning calorimetry (DSC), and satisfies the following formulae (1) and (2): T =1/ a /( TgA +273)+ b /( TgB +273)}−273  (1) T−TgAB >30× a (2) wherein a and b represent weight ratios of (A) and (B) to a total weight of (A) and (B), and satisfy the equation a+b=1; and TgA, TgB and TgAB represent second glass transition temperatures (Tg2nd), measured at a second temperature rising in differential scanning calorimetry, of (A), (B), and a mixture of (A) and (B), respectively.

  一种调色剂包括聚酯树脂，其中包括聚酯树脂组分A（A）不溶于四氢呋喃；和聚酯树脂组分B（B）可溶于四氢呋喃。该调色剂具有第一玻璃转移温度（Tg1st），在差示扫描量热法（DSC）中在第一升温时测得，从20℃到50℃不等，并满足以下公式（1）和（2）：T=1/a/（TgA+273）+b/（TgB+273）}−273  （1）T−TgAB>30×a（2）其中，a和b表示（A）和（B）的重量比，分别占（A）和（B）的总重量，并满足方程式a+b=1；TgA，TgB和TgAB分别表示（A），（B）和（A）和（B）混合物的第二玻璃转移温度（Tg2nd），在差示扫描量热法中在第二升温时测得。
• Oil-based solid cosmetic composition containing a fluoroalkyl (meth)acrylate copolymer and use thereof
  申请人：KAO CORPORATION

  公开号：EP0815836A2

  公开（公告）日：1998-01-07

  Disclosed herein is an oil-based solid cosmetic composition comprising the following components (A) and (B): (A) 0.1-10 wt.% of a fluoroalkyl (meth)acrylate copolymer represented by the following general formula (1): wherein R1 and R2 are independently a hydrogen atom or a methyl group, R3 is a hydrocarbon group having 1-32 carbon atoms, Rf is a group obtained by substituting part or the whole of hydrogen atoms of a hydrocarbon group having 1-32 carbon atoms with the corresponding number of fluorine atoms, and n and m are independently a number of 2-2,000 on the average; and (B) 2.9-50 wt.% of a solid oily substance having a melting point of 60-120°C. The cosmetic composition is good in shape retention and a feeling upon use, has excellent gloss upon its application and can retain the good gloss and color after the application over a long period of time. It may be used as a lipstick or eyebrow composition.

  本文公开了一种油基固体化妆品组合物，由以下成分（A）和（B）组成： (A) 0.1-10重量％的氟烷基（甲基）丙烯酸酯共聚物，由以下通式（1）表示： 其中 R1 和 R2 独立地为氢原子或甲基，R3 为具有 1-32 个碳原子的烃基，Rf 为用相应数目的氟原子取代具有 1-32 个碳原子的烃基中的部分或全部氢原子而得到的基团，n 和 m 独立地为平均 2-2,000 的数目；以及 (B) 2.9-50 重量百分比的固体油性物质，熔点为 60-120°C。 该化妆品组合物在使用时具有良好的保形性和手感，涂抹后具有极佳的光泽度，涂抹后可长时间保持良好的光泽度和色泽。它可用作口红或眉毛组合物。
• Composition for peelable coating
  申请人：Rinrei Wax Co., Ltd.

  公开号：EP1087000A1

  公开（公告）日：2001-03-28

  A composition for peelable coating, which composition exhibits excellent properties such as film-formability and water resistance and can be dried at ambient temperature without any particular heating, to thereby provide excellent coating performance. The composition contains a core/shell copolymer including an acrylic copolymer portion A having a high glass transition temperature of 30°C-70°C and an acrylic copolymer portion B having a low glass transition temperature of 5°C to -30°C and being formed through multi-step polymerization. The core/shell copolymer is made up of 5-40 wt.% of the acrylic copolymer portion A and 60-95 wt.% of the acrylic copolymer portion B, on the basis of the total amount of the portion A and the portion B. The acrylic copolymer portion A and the acrylic copolymer portion B contain the same hard-polymer-providing monomer unit and soft-polymer-providing monomer unit. Each copolymer portion contains a hard-polymer-providing monomer unit and a soft-polymer-providing monomer unit in a total amount of 70 wt.% or more.

  一种用于可剥离涂料的组合物，该组合物具有优异的成膜性和耐水性等性能，无需特别加热即可在环境温度下干燥，从而提供优异的涂料性能。该组合物包含一种芯/壳共聚物，其中丙烯酸共聚物 A 部分具有 30°C 至 70°C 的高玻璃化转变温度，丙烯酸共聚物 B 部分具有 5°C 至 -30°C 的低玻璃化转变温度，是通过多步聚合形成的。按 A 部分和 B 部分的总量计算，芯/壳共聚物由 5-40 重量百分比的丙烯酸共聚物 A 部分和 60-95 重量百分比的丙烯酸共聚物 B 部分组成。丙烯酸共聚物 A 部分和丙烯酸共聚物 B 部分含有相同的硬聚合物单体单元和软聚合物单体单元。每种共聚物部分都含有提供硬聚合物的单体单元和提供软聚合物的单体单元，总含量为 70 wt.%或以上。