1,14-二甲基-4,10-二噁四环[5.5.2.0(2,6).0(8,12)]-13-十四烯-3,5,9,11-四酮 | 134932-59-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 1,14-二甲基-4,10-二噁四环[5.5.2.0(2,6).0(8,12)]-13-十四烯-3,5,9,11-四酮
• 英文名称: 1,8-dimethylbicyclo<2.2.2>oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride
• 英文别名: 1,8-dimethylbicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride；1,14-Dimethyl-4,10-dioxatetracyclo[5.5.2.0~2,6~.0~8,12~]tetradec-13-ene-3,5,9,11-tetraone；1,14-dimethyl-4,10-dioxatetracyclo[5.5.2.02,6.08,12]tetradec-13-ene-3,5,9,11-tetrone
• CAS: 134932-59-5；32251-35-7
• 化学式: C₁₄H₁₂O₆
• 分子量: 276.246
• InChiKey: VPEBWHJXHKKKRE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  20
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  86.7
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,14-二甲基-4,10-二噁四环[5.5.2.0(2,6).0(8,12)]-13-十四烯-3,5,9,11-四酮 在 ammonium hydroxide 、 potassium carbonate 作用下， 以 乙酸乙酯 为溶剂， 反应 90.0h， 生成 N,N'-bis-(3-chloropropyl)-1,8-dimethylbicyclo<2.2.2>oct-7-ene-2,3,5,6-tetracarboxydiimide
  参考文献：
  名称：

  Turlo; Zawadowski, Acta poloniae pharmaceutica, 1994, vol. 51, # 4-5, p. 347 - 349

  摘要：

  DOI：
• 作为产物：
  描述：

  马来酸酐 、 4-甲基-3戊烯-2-酮 在 1,2-丙二醇二乙酸酯 、 对甲苯磺酸 作用下， 生成 1,14-二甲基-4,10-二噁四环[5.5.2.0(2,6).0(8,12)]-13-十四烯-3,5,9,11-四酮
  参考文献：
  名称：

  Turlo; Zawadowski, Acta poloniae pharmaceutica, 1994, vol. 51, # 4-5, p. 347 - 349

  摘要：

  DOI：

文献信息

• Polyimide, dianhydride monomers, and polymers, methods of making and uses thereof
  申请人：King Abdullah University of Science and Technology

  公开号：US11001672B2

  公开（公告）日：2021-05-11

  Embodiments of the present disclosure include, a dianhydride monomer, a polyimide, a method of making a dianhydride, a method of making a polyimide, and the like. Embodiments of the present disclosure can be used in membrane-based gas separation applications.

  本公开的实施例包括二酐单体、聚酰亚胺、制造二酐的方法、制造聚酰亚胺的方法等。本公开的实施例可用于基于膜的气体分离应用。
• ZAWADOWSKI T.; POLUDNIKIEWICZ W., ROCZ. CHEM. <ROCH-AC>, 1976, 50, NO 7-8, 1415-1419
  作者：ZAWADOWSKI T.、 POLUDNIKIEWICZ W.

  DOI：——

  日期：——
• A MICROPOROUS CRYSTALLINE MATERIAL, ZEOLITE ITQ-37, PREPARATION METHOD AND USE
  申请人：Consejo Superior de Investigaciones Cientificas (CSIC)

  公开号：EP1997779B1

  公开（公告）日：2017-10-18
• MICROPOROUS CRYSTALLINE MATERIAL, ZEOLITE ITQ-37, PREPARATION METHOD AND USE
  申请人：Moliner Marin Manuel

  公开号：US20090220661A1

  公开（公告）日：2009-09-03

  The present invention relates to a microporous crystalline material characterized in that it has the following chemical composition in the calcined from: x X 2 O 3 :n YO 2 :m GeO 2 in which (n+m) is at least 5, X is one or more trivalent elements, Y corresponds to one or more tetravalent elements other than Ge, “x” may have any value, including zero, and the ratio Y/Ge is greater than 0.1, and it has a characteristic X-ray diffraction pattern. Its also relates to a method for preparing it and to its use in the conversion of organic-compounds supplies.
• POLYIMIDE, DIANHYDRIDE MONOMERS, AND POLYMERS, METHODS OF MAKING AND USES THEREOF
  申请人：King Abdullah University of Science and Technology

  公开号：US20190085132A1

  公开（公告）日：2019-03-21

  Embodiments of the present disclosure include, a dianhydride monomer, a polyimide, a method of making a dianhydride, a method of making a polyimide, and the like. Embodiments of the present disclosure can be used in membrane-based gas separation applications.