申请人:Albemarle Corporation
公开号:EP2107079A2
公开(公告)日:2009-10-07
A flame retardant formulation which is the combination of at least (1) at least one bromine-containing polyol flame retardant formed from the reaction of (a) tetrabromophthalic anhydride, (b) an aliphatic polyol, and (c) an epoxide, and (2) at least one aliphatic diester of an alkane dicarboxylic acid, with the proviso that the formulation has a viscosity at 25°C of about 20,000 cps or less, and a bromine content of at least about 40 wt%. A flame retardant compound formed from A) tetrabromophthalic anhydride; B) diethylene glycol; C) at least one alpha-omega alkane diol, or at least one alpha-omega alkane diol and at least one aliphatic monool; and D) at least one alkylene oxide; with the proviso that the compound has a viscosity at 25°C of about 60,000 cps or less, and a bromine content of at least about 43 wt%. Polymer compositions formed from (a) a polyurethane or a polyisocyanurate and (b) a formulation of the invention. One process to make a formulation involves heating a mixture of (a), (b), and at least one liquid aliphatic diester of a alkane dicarboxylic acid to form an intermediate composition; and then the intermediate is contacted one or more times with (c) thereby producing the formulation. Optionally, excess (c) is removed.
一种阻燃剂配方,它至少是以下物质的组合:(1)至少一种含溴多元醇阻燃剂,由(a)四溴邻苯二甲酸酐、(b)脂肪族多元醇和(c)环氧化物反应生成;(2)至少一种烷烃二羧酸脂肪族二酯,但该配方在 25°C 时的粘度约为 20°C、(2) 烷烃二羧酸的至少一种脂肪族二酯,但该制剂在 25°C 时的粘度不超过约 20,000 cps,溴含量不低于约 40 wt%。由以下物质形成的阻燃化合物:A) 四溴邻苯二甲酸酐;B) 二甘醇;C) 至少一种α-ω-烷二醇,或至少一种α-ω-烷二醇和至少一种脂族一元醇;以及 D) 至少一种环氧亚烷烃;但条件是该化合物在 25°C 时的粘度约为 60,000 cps 或更低,溴含量至少约为 43 wt%。由(a)聚氨酯或聚异氰脲酸酯和(b)本发明配方形成的聚合物组合物。制备配方的一种工艺包括加热(a)、(b)和至少一种烷烃二羧酸的液态脂肪族二酯类的混合物,以形成中间体组合物;然后将中间体与(c)接触一次或多次,从而制得配方。可选择去除多余的 (c)。