1,3-二羟基丙烷-2-基十一碳-10-烯酸酯 | 142564-41-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 中文名称: 1,3-二羟基丙烷-2-基十一碳-10-烯酸酯
• 英文名称: β-glycerol monoundecenoate
• 英文别名: β-GMU；glycerol monoundecylenate；10-Undecenoic acid, 2-hydroxy-1-(hydroxymethyl)ethyl ester；1,3-dihydroxypropan-2-yl undec-10-enoate
• CAS: 142564-41-8
• 化学式: C₁₄H₂₆O₄
• 分子量: 258.358
• InChiKey: SYFKEANHFZHYLD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  66.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  (2-Dec-9-enyl-[1,3]dioxolan-4-yl)-methanol 在 叔丁基过氧化氢 、 重铬酸吡啶 作用下， 以 二氯甲烷 为溶剂， 反应 6.0h， 以75%的产率得到甘油十一碳烯酸酯
  参考文献：
  名称：

  A highly selective methodology for the direct conversion of acetals to esters

  摘要：

  DOI：

  10.1021/jo00044a042

文献信息

• NOVEL EMULSIFYING COMPOSITION WITH CATIONIC NATURE
  申请人：CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE-CNRS

  公开号：US20170087074A1

  公开（公告）日：2017-03-30

  The invention relates to a surfactant composition including at least one compound of formula (I): in which each of the radicals Z is a hydrogen atom or (Z 1 ); at least one compound of formula (IV); one compound of formula (V); and one compound of formula (VI). The invention also relates to a method for preparing said composition and to the use thereof in cosmetics.

  本发明涉及一种表面活性剂组合物，包括至少一种式(I)的化合物，其中Z的各自基团是氢原子或(Z1)；至少一种式(IV)的化合物；一种式(V)的化合物；以及一种式(VI)的化合物。本发明还涉及制备该组合物的方法以及在化妆品中使用它的用途。
• Structural Analysis of Partial and Total Esters of Glycerol Undecenoate and Diglycerol Undecenoate
  作者：Gildas Nyame Mendendy Boussambe、Romain Valentin、Zéphirin Mouloungui

  DOI：10.1007/s11746-015-2725-1

  日期：2015.12

  composition of esters of undecylenic acid formed with glycerol or diglycerol as a function of their reaction conditions, which constitute a highly complex system. We purified undecylenic acid esters from each polyol family to allow the structural identification of each ester of glycerol and each ester of diglycerol with undecylenic acid. We found that the polarity of these non‐ionic amphiphilic esters directly

  甘油和十一碳烯酸之间或二甘油和十一碳烯酸之间的直接酯化反应产生所有可能类型的甘油或二甘油酯。通过硅胶色谱法纯化，从而以纯净形式分离出每种类型的酯。通过质谱，1 H NMR，13表征并鉴定了分离出的化合物的分子结构C NMR和DEPT-135。然后，我们研究了与甘油或二甘油形成的十一碳烯酸酯的组成，并根据它们的反应条件而定，它们构成了一个高度复杂的系统。我们从每个多元醇家族中纯化十一碳烯酸酯，以使每个甘油酯和二甘油与十一碳烯酸酯的结构鉴定成为可能。我们发现这些非离子两亲酯的极性直接影响它们对有机和无机溶剂的亲和力，并且这些酯的行为与阴离子两亲分子（如十一碳烯酸）有很大不同。
• Composition of alkyl polyglucosides and fatty esters of cationic amino acids
  申请人：SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC

  公开号：US10149810B2

  公开（公告）日：2018-12-11

  The invention relates to a composition (C1) including: (a) at least one compound of formula (I) in which each of the radicals Z is a hydrogen atom or a monovalent radical (Z1); (b) at least one compound of formula (IV); (c) a compound of formula (V). The invention also relates to a method for preparing said composition and to the use thereof in cosmetics.

  本发明涉及一种组合物 (C1)，包括：(a) 至少一种式 (I) 化合物，其中每个基 Z 均为氢原子或一价基 (Z1)；(b) 至少一种式 (IV) 化合物；(c) 一种式 (V) 化合物。本发明还涉及制备上述组合物的方法及其在化妆品中的用途。
• OIL-IN-WATER EMULSION HAVING IMPROVED SENSORY PROPERTIES
  申请人：Amalric Chantal

  公开号：US20120114573A1

  公开（公告）日：2012-05-10

  An oil-in-water emulsion includes, for 100 wt % thereof: a) 0.1 to 10 wt % of an emulsifying system including, for 100 wt % thereof: (i) 5 to 95 wt % of the mixture of the reaction products of a reducing sugar and 1,12-octadecanediol essentially consisting of hydroxyl-octadecyl polyglycosides of formula (I): HO—R—O-(G) n -H (I) and of polyglycosyl octadecyl polyglycosides of formula (II): H-(G) m -O—R—O-(G) p -H (II), where, in formulas (I) and (II), G is the remainder of the reducing sugar and R is the divalent radical octadecane-diyl-1,12, and where n, m and p, identical or different, each are, independently of each other, a decimal number between 1 and 5; (ii) 95 to 5 wt % of 1,12-octadecanediol; b) 0.01 to 5 wt % of at least one thickening and/or gelling agent; c) 10 to 50 wt % of an oil phase; and d) 89.89 to 35 wt % of an aqueous phase.
• COMPOSITION OF ALKYL POLYGLUCOSIDES AND FATTY ESTERS OF CATIONIC AMINO ACIDS
  申请人：SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC

  公开号：US20170087077A1

  公开（公告）日：2017-03-30

  The invention relates to a composition (C 1 ) including: (a) at least one compound of formula (I) in which each of the radicals Z is a hydrogen atom or a monovalent radical (Z 1 ); (b) at least one compound of formula (IV); (c) a compound of formula (V). The invention also relates to a method for preparing said composition and to the use thereof in cosmetics.