1,3-二苯基丙烷-2,2-二硫醇 | 42937-97-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 中文名称: 1,3-二苯基丙烷-2,2-二硫醇
• 英文名称: 1,3-diphenyl-2,2-dimercaptopropane
• 英文别名: 1,3-diphenylpropane-2,2-dithiol；1,3-diphenyl-propane-2,2-dithiol；Bn2C(CH2)2；1,3-Diphenyl-propan-2,2-dithiol；1,3-Diphenyl-2,2-propanedithiol
• CAS: 42937-97-3
• 化学式: C₁₅H₁₆S₂
• 分子量: 260.424
• InChiKey: KADZDOLYFZTSSM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,3-二苯基丙烷-2,2-二硫醇 在 盐酸 、 碘 作用下， 以 水 、 苯 为溶剂， 反应 49.5h， 生成 1,2-bis(1,3-diphenylpropan-2-yl)disulfane
  参考文献：
  名称：

  Synthesis of 3,3,5,5-tetrabenzyl-1,2,4-trithiol and 1,2-dis(1,3-arylpropan-2-yl)disulfane

  摘要：

  Novel sulfur-containing compounds (3a-3c, 4a-4c) were obtained in ethanol with 1,3-diphenyl-2-propanone as the starting material. The advantages of this procedure were mild reaction conditions, simple protocol, and high yields. The structures of the products were characterized by IR, H-1 NMR, MS and elementary analysis. The crystal of the new compound 4a belongs to monoclinic, space group C2 with a = 18.727(3), b = 6.5179(9), c = 13.7576(18) angstrom, beta = 131.0610(10)degrees, V = 1266.2(3)angstrom(3), Z = 2, Dc = 2.136 g/cm(3), mu = 1.078 mm(-1), F(0 0 0) = 843, R = 0.0490 and wR = 0.1247 for 3211 observed reflection with I > 2 sigma(I). X-ray analysis reveals that the molecule is not symmetrical, the molecular structure is stabilized by weak pi-pi stacking interactions, and no classical hydrogen bonds can be observed. (C) 2013 Wei-Bing Hu. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

  DOI：

  10.1016/j.cclet.2013.05.041
• 作为产物：
  描述：

  二苄基甲酮 在 盐酸 、 乙醇 、 硫化氢 作用下， 生成 1,3-二苯基丙烷-2,2-二硫醇
  参考文献：
  名称：

  EXCHANGE RATES OF ACETYLENIC HYDROGENS IN AQUEOUS SOLUTIONS¹

  摘要：

  DOI：

  10.1021/ja01521a060

文献信息

• POLYMERIZABLE COMPOSITION AND NOVEL ALKYNE COMPOUND
  申请人：MITSUI CHEMICALS, INC.

  公开号：US20180066082A1

  公开（公告）日：2018-03-08

  Provided is a polymerizable composition including an alkyne compound represented by the following general formula (1): wherein, in general formula (1), X 1 and X 2 represent a sulfur atom, an oxygen atom, or an NH group and may be the same or different from each other, Q represents an alkylene group having 1 or 2 carbon atoms, a carbonyl group, or a thiophenylene group in which one of carbon atoms is substituted by an antimony atom, R 1 and R 2 represent an alkylene group having 1 or 2 carbon atoms and may be the same or different from each other, and m and n each represent 0 or 1.

  提供的是一种可聚合组合物，其中包括以下一般式（1）所表示的炔基化合物：在一般式（1）中，X1和X2代表硫原子、氧原子或NH基团，可以相同也可以不同，Q代表具有1或2个碳原子的烷基基团、酰基基团或一种硫代苯基团，其中一个碳原子被锑原子取代，R1和R2代表具有1或2个碳原子的烷基基团，可以相同也可以不同，m和n分别表示0或1。
• Synthesis, Structural Characterization, and Ligand Replacement Reactions of <i>gem</i>-Dithiolato-Bridged Rhodium and Iridium Complexes
  作者：Angel B. Rivas、José M. Gascón、Fernando J. Lahoz、Ana I. Balana、Alvaro J. Pardey、Luis A. Oro、Jesús J. Pérez-Torrente

  DOI：10.1021/ic800464p

  日期：2008.7.7

  (cyclohexyl)) ( 10- 13) and [Rh 2(mu-S 2CBn 2)(CO) 2P(OR') 3} 2] (R' = Me, Ph) ( 14- 15). The substitution process in [Rh 2(mu-S 2CBn 2)(CO) 4] ( 7) by P(OMe) 3 has been studied by spectroscopic means and the full series of substituted complexes [Rh 2(mu-S 2CBn 2)(CO) 4- n P(OR) 3} n ] ( n = 1, 4) has been identified in solution. The cis complex [Rh 2(mu-S 2CBn 2)(CO) 2(mu-dppb)] ( 16) was obtained by reaction

  宝石二硫醇化合物R 2C（SH）2（R = Bn（苄基），（i）Pr; R 2 =-（CH 2）4-）与含有碱性配体如[M]的双核铑或铱络合物的反应（mu-OH）（cod）] 2和[M（mu-OMe）（cod）] 2或单核[M（acac）（cod）]（M = Rh，Ir，cod = 1,5-环辛二烯）在外部碱的存在下，得到双核络合物[M 2（mu-S 2CR 2）（cod）2]（1-4）。1,1-二巯基环戊烷的单去质子化反应得到单核络合物[Rh（HS 2Cptn）（cod）]（5）（是双核化合物[Rh 2（mu-S 2Cptn）（cod）2]的前体）（6） 。二烯烃化合物的羰基化得到配合物[Rh 2（mu-S 2CR 2）（CO）4]（7-9），其与P-供体配体反应以立体选择性地产生二取代配合物的反式异构体[Rh 2（ mu-S 2CR 2）（CO）2（PR'3）2]（R'= Ph，Cy（环己基））（10-13）和[Rh
• Metal Thietane Compound, Polymerizable Composition Containing the Compound, Resin and Use of the Resin
  申请人：Murakami Masakazu

  公开号：US20130018169A1

  公开（公告）日：2013-01-17

  Polymerizable compositions containing at least one metal thietane compound represented by general formulas (110), (201) or (120), respectively, wherein said formulas are as follows: and wherein the identified moieties and n, p, q and r are defined.

  含有至少一种由通式（110）、（201）或（120）表示的金属噻吩化合物的聚合物组合物，其中所述的通式如下：其中所识别的基团和n、p、q和r已被定义。
• METAL THIETANE COMPOUND, POLYMERIZABLE COMPOSITION CONTAINING THE COMPOUND, RESIN AND USE OF THE RESIN
  申请人：Murakami Masakazu

  公开号：US20100240862A1

  公开（公告）日：2010-09-23

  Disclosed is a metal thietane compound represented by the following general formula (120), (wherein, in the above general formula (120), M is a member selected from the group consisting of Bi, Sb, Ti, Zr and Ta; X 1 and X 2 are each independently a sulfur atom or an oxygen atom; R 1 is a divalent organic group; the bond between M and T shown by a dotted line and a solid line represents a single or double bond; m is an integer of 0 or 1 or more; n is the number of valence of M; and p is an integer of equal to or more than 1 and equal to or less than n, provided that when r is 1, q is 0 and Y is a monovalent inorganic or organic group; when r is 1 and n-p-q is 2 or more, a plurality of Ys contained are each independently selected from monovalent inorganic or organic groups; when r is 1 and n-p-q is 2 or more, a plurality of Ys may be bonded to each other to form a ring containing M; when r is 2, n-p-q is 1 or 2 and Y is a divalent group; when r is 2 and n-p-q is 2, two Ys may form a ring together with two Ms; and when r is 2 and q is 2, a plurality of Ts contained are each independently selected from inorganic or organic groups).

  公开了一种金属硫代环烷化合物，其通式如下（120），其中，在上述通式（120）中，M是从Bi、Sb、Ti、Zr和Ta组成的群体中选择的成员；X1和X2分别是硫原子或氧原子；R1是二价有机基团；M和T之间的键由虚线和实线表示，表示单键或双键；m是0或1或更多的整数；n是M的化合价数；p是大于或等于1且小于或等于n的整数，其中当r为1时，q为0且Y为一价无机或有机基团；当r为1且n-p-q为2或更多时，所含的多个Y各自独立地选择自一价无机或有机基团；当r为1且n-p-q为2或更多时，多个Y可以相互连接形成含M的环；当r为2时，n-p-q为1或2且Y为二价基团；当r为2且n-p-q为2时，两个Y可以与两个M一起形成环；当r为2且q为2时，所含的多个T各自独立地选择自无机或有机基团。
• CHROMENE COMPOUND, CURABLE COMPOSITION COMPRISING THE COMPOUND, AND OPTICAL ARTICLE INCLUDING A CURED BODY OF THE CURABLE COMPOSITION
  申请人：TOKUYAMA CORPORATION

  公开号：US20200190106A1

  公开（公告）日：2020-06-18

  A chromene compound having at least one indenonaphthopyran moiety which has a group forming a spiro ring together with the 13-position carbon atom and further an oligomer chain group selected from a polyalkylene oxide oligomer chain group having at least three recurring units and a polyester oligomer chain group having at least three recurring units, represented by the following formula and having reduced matrix dependence: wherein R 1 and R 2 are each a group which may have an oligomer chain group, the ring Z bonded to the 13-position carbon atom of the chromene compound is a Spiro ring group, and R 3 and R 4 are each an aryl group or heteroaryl group which may have an oligomer chain group. Preferably, the chromene compound has at least one oligomer chain group in the molecule.

  具有至少一个印苯并萘吡喃基团的色酮化合物，其中该基团与13位碳原子形成螺环，并且进一步具有从至少三个重复单元中选择的聚烷氧基寡聚物链基团和聚酯寡聚物链基团中的一个寡聚物链基团，由下式表示并具有降低的矩阵依赖性： 其中R1和R2是各自可能具有寡聚物链基团的基团，与色酮化合物的13位碳原子键合的环Z是螺环基团，而R3和R4是各自可能具有寡聚物链基团的芳基或杂环基团。最好，该色酮化合物在分子中至少具有一个寡聚物链基团。