1,3-双[(4-甲基苯氧基)甲基]苯 | 143522-20-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 1,3-双[(4-甲基苯氧基)甲基]苯
• 英文名称: 1,1'-[1,3-Phenylenebis(methyleneoxy)]bis(4-methylbenzene)
• 英文别名: 1,3-bis[(4-methylphenoxy)methyl]benzene
• CAS: 143522-20-7
• 化学式: C₂₂H₂₂O₂
• 分子量: 318.415
• InChiKey: UHKIBCJGDYEUQN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  24
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,6-bis(p-methylphenoxymethyl)bromobenzene 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 、 甲苯 为溶剂， 反应 6.5h， 生成 2-[2,6-bis[(4-methylphenoxy)methyl]phenyl]-1,3-bis[(4-methylphenoxy)methyl]benzene 、 1,3-双[(4-甲基苯氧基)甲基]苯
  参考文献：
  名称：

  Synthesis and characterization of hexacoordinate cobalt(III) complexes bearing three C,O-bidentate ligands

  摘要：

  Hexacoordinated Co(III) complexes bearing three C,O-bidentate ligands (9a and 9b) were prepared from 1-bromo-2-(P-tolyloxymethyl)benzene (8a) and 1-bromo-2,6-bis(p-tolyloxymethyi)benzene (8b), respectively. Both complexes were stable in air at room temperature. X-ray analyses revealed that the structures of both complexes were essentially the same. According to variable temperature H-1 NMR study, it was found that the two oxygen ligands on the same aromatic ring of 9b interchanged with each other. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.08.100

文献信息

• DIPHENYLSULFONE CROSSLINKED COMPOUND, COLOR DEVELOPMENT SUBSTANCE FOR THERMAL RECORDING AND THERMAL RECORDING MATERIAL
  申请人：NICCA CHEMICAL CO., LTD.

  公开号：EP2314573A1

  公开（公告）日：2011-04-27

  Diphenylsulfone bridged compounds of the general formula: (1) wherein n is an integer of 1. to 10. Further, there is disclosed a thermal recording material comprising a support and, superimposed thereon, a thermosensitive color forming layer containing a color forming substance for thermal recording consisting of any of the diphenylsulfone bridged compounds and a color forming substance consisting of a colorless or light-colored leuco dye. This thermal recording material excels in the storability, especially wet heat resistance and oil resistance, of image areas and further exhibits excellent characteristics in the storability, especially heat resistance, of undeveloped areas.

  通式如下的二苯砜桥接化合物(1) 其中 n 为 1 至 10 的整数。此外，还公开了一种热敏记录材料，该材料包括一个支架和叠加在支架上的热敏彩色形成层，该热敏彩色形成层含有热敏记录用彩色形成物质，该彩色形成物质由任意一种二苯砜桥接化合物和彩色形成物质组成，该彩色形成物质由无色或浅色的leuco染料组成。这种热敏记录材料在图像区域的储存性，特别是湿热和耐油性方面表现出色，在未显影区域的储存性，特别是耐热性方面也表现出优异的特性。
• DIPHENYLSULFONE BRIDGED COMPOUND, COLOR FORMING SUBSTANCE FOR THERMAL RECORDING AND THERMAL RECORDING MATERIAL
  申请人：Saito Hajime

  公开号：US20110136664A1

  公开（公告）日：2011-06-09

  Diphenylsulfone bridged compounds of the general formula: (1) wherein n is an integer of 1 to 10. Further, there is disclosed a thermal recording material comprising a support and, superimposed thereon, a thermosensitive color forming layer containing a color forming substance for thermal recording consisting of any of the diphenylsulfone bridged compounds and a color forming substance consisting of a colorless or light-colored leuco dye. This thermal recording material excels in the storability, especially wet heat resistance and oil resistance, of image areas and further exhibits excellent characteristics in the storability, especially heat resistance, of undeveloped areas.
• US7811675B2
  申请人：——

  公开号：US7811675B2

  公开（公告）日：2010-10-12
• US8283286B2
  申请人：——

  公开号：US8283286B2

  公开（公告）日：2012-10-09
• US8497227B2
  申请人：——

  公开号：US8497227B2

  公开（公告）日：2013-07-30