1,4-双(1,1,2,2-四氟苄氯)苯 | 3832-65-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 1,4-双(1,1,2,2-四氟苄氯)苯
• 中文别名: 1,4-二(1,1,2,2-四氟乙氧基)苯
• 英文名称: Hydrochinon-bis-(1,1,2,2-tetrafluor-aethylaether
• 英文别名: 1,4-Bis(1,1,2,2-tetrafluoroethoxy)benzene
• CAS: 3832-65-3
• 化学式: C₁₀H₆F₈O₂
• 分子量: 310.144
• InChiKey: SYMFAUQESLPCRO-UHFFFAOYSA-N

物化性质

• 沸点：
  81-83℃ (10 Torr)
• 密度：
  1.443±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  10

安全信息

• 海关编码：
  2909309090

反应信息

• 作为产物：
  描述：

  四氟乙烯 、 对苯二酚 在 sodium 作用下， 以 1,4-二氧六环 、 N,N-二甲基甲酰胺 、 xylene 为溶剂， 生成 1,4-双(1,1,2,2-四氟苄氯)苯
  参考文献：
  名称：

  Nucleophilic Reactions of Fluoroölefins

  摘要：

  DOI：

  10.1021/ja01504a026

文献信息

• Lithium sulfur battery
  申请人：Olschimke Jens

  公开号：US20120214043A1

  公开（公告）日：2012-08-23

  A lithium sulfur battery comprising an electrolyte solvent which comprises at least one fluorosubstituted compound is described. Preferred fluorosubstituted compounds which are predominantly solvents are notably selected from the group consisting of fluorosubstituted carboxylic acid esters, fluorosubstituted carboxylic acid amides, fluorosubstituted fluorinated ethers, fluorosubstituted carbamates, fluorosubstituted cyclic carbonates, fluorosubstituted acyclic carbonates, fluorosubstituted ethers, perfluoroalkyl phosphoranes, fluorosubstituted phosphites, fluorosubstituted phosphates, fluorosubstituted phosphonates, and fluorosubstituted heterocycles. Monofluoroethylene carbonate, cis-difluoroethylene carbonate, trans-difluoroethylene carbonate, 4,4-difluoroethylene carbonate, trifluoroethylene carbonate, tetrafluoroethylene carbonate, 4-fluoro-4-methyl-1,3-dioxolane-2-one, 4-fluoro-4-ethyl-1,3-dioxolane-2-one, 2,2,2-trifluoroethyl-methyl carbonate, 2,2,2-trifluoroethyl-fluoromethyl carbonate are preferred. The solvent may further comprise a non-fluorinated solvent, e.g., ethylene carbonate, a dialkyl carbonate, or propylene carbonate. Use of such fluorinated compound as additive for such batteries and specific electrolyte solutions.

  本文描述了一种包括至少一种含氟取代化合物的电解质溶剂的锂硫电池。优选的主要作为溶剂的氟取代化合物主要选自包括氟取代羧酸酯、氟取代羧酸酰胺、氟取代氟化醚、氟取代碳酸酯、氟取代环状碳酸酯、氟取代非环状碳酸酯、氟取代醚、全氟烷基磷烷、氟取代亚磷酸酯、氟取代磷酸酯、氟取代膦酸酯和氟取代杂环化合物的群组的化合物。优选的化合物包括单氟乙烯碳酸酯、顺-二氟乙烯碳酸酯、反-二氟乙烯碳酸酯、4,4-二氟乙烯碳酸酯、三氟乙烯碳酸酯、四氟乙烯碳酸酯、4-氟-4-甲基-1,3-二氧六环-2-酮、4-氟-4-乙基-1,3-二氧六环-2-酮、2,2,2-三氟乙基甲基碳酸酯、2,2,2-三氟乙基-氟甲基碳酸酯。该溶剂还可以包括非氟化溶剂，例如乙烯碳酸酯、二烷基碳酸酯或丙烯碳酸酯。使用这种含氟化合物作为电池和特定电解质溶液的添加剂。
• FLUORINATED CARBONYL COMPOUNDS COMPRISING A TRIPLE BOND, METHODS FOR THEIR MANUFACTURE AND USES THEREOF
  申请人：SOLVAY SA

  公开号：US20150191423A1

  公开（公告）日：2015-07-09

  Fluorinated carbonyl compounds comprising a triple bond were prepared and their use as solvent additives or solvents in lithium ion batteries, lithium air batteries, lithium sulphur batteries and supercapacitors is described. Preferred compounds contain at least one nitrile or at least one alkynyl group.

  含有三键的氟化羰基化合物已经制备好，并描述了它们作为溶剂添加剂或溶剂在锂离子电池、锂空气电池、锂硫电池和超级电容器中的用途。首选化合物至少含有一个腈基或至少一个炔基。
• Process for the manufacture of 1, 1'-difluorosubstituted dialkyl carbonates, isomers thereof and electrolyte compositions containing them
  申请人：SOLVAY SA

  公开号：EP2602241A1

  公开（公告）日：2013-06-12

  Fluoroalkyl alkyl carbonates which are suitable as additives or solvents in lithium ion batteries are prepared from fluoroalkyl fluoroformates and an aldehyde, preferably formaldehyde and acetaldehyde. 1,1'-difluoromethyl carbonate and 1,1'-difluorodiethylcarbonate are the preferred compounds prepared by the process of the present invention.

  本发明的工艺从氟烷酸酯和醛，特别是甲醛和乙醛制备适用于锂离子电池中的添加剂或溶剂的氟烷基烷基碳酸酯。1,1'-二氟甲基碳酸酯和1,1'-二氟二乙基碳酸酯是所制备的首选化合物。
• Fluorinated carbonyl compounds comprising a triple bond, methods for their manufacture and uses thereof
  申请人：SOLVAY SA

  公开号：US10106492B2

  公开（公告）日：2018-10-23

  Fluorinated carbonyl compounds comprising a triple bond were prepared and their use as solvent additives or solvents in lithium ion batteries, lithium air batteries, lithium sulphur batteries and supercapacitors is described. Preferred compounds contain at least one nitrile or at least one alkynyl group.

  制备了包含三键的氟化羰基化合物，并介绍了它们在锂离子电池、锂空气电池、锂硫电池和超级电容器中作为溶剂添加剂或溶剂的用途。优选化合物含有至少一个腈基或至少一个炔基。
• Method for the application of active materials onto active surfaces and devices made with such methods
  申请人：Petrov A. Viacheslav

  公开号：US20050062021A1

  公开（公告）日：2005-03-24

  The invention provides methods for the application of active materials onto active surfaces useful in organic electronic devices. The methods of the invention include selecting a liquid composition including an active material and a suitable liquid medium whereby when the liquid composition is deposited on the desired active surface it has no greater than about a 40° contact angle; treating the active surface to raise its surface tension before the deposition of a liquid composition containing the desired active material is deposited thereon; and combination thereof. The invention also provides organic electronic devices having at least two active layers, wherein at least one active layer comprises an active material that was deposited using at least one practice of the method of the invention.

  本发明提供了将活性材料应用于有机电子设备中的活性表面的方法。本发明的方法包括选择一种包括活性材料和适当液体介质的液体组合物，当该液体组合物沉积在所需的活性表面上时，其接触角不大于约 40°；在沉积含有所需活性材料的液体组合物之前，处理活性表面以提高其表面张力；及其组合。本发明还提供了具有至少两个活性层的有机电子器件，其中至少一个活性层包括使用本发明方法的至少一种做法沉积的活性材料。