1,4-双(2-碘乙基)苯 | 130800-03-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,4-双(2-碘乙基)苯
• 英文名称: 2,2'-(1,4-phenylene)diethyl diiodide
• 英文别名: 1,4-Bis(2'-iodoethyl)benzene；1,4-bis-(2-iodo-ethyl)-benzene；1,4-Bis-(2-jod-aethyl)-benzol；Benzene, 1,4-bis(2-iodoethyl)-；1,4-bis(2-iodoethyl)benzene
• CAS: 130800-03-2
• 化学式: C₁₀H₁₂I₂
• 分子量: 386.014
• InChiKey: VIHJZHSVRYXGBW-UHFFFAOYSA-N

物化性质

• 熔点：
  110-111 °C
• 沸点：
  351.8±35.0 °C(Predicted)
• 密度：
  2.002±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,4-双(2-碘乙基)苯 在 邻四氯苯醌 、 甲烷磺酸 、 乙基溴化镁 作用下， 反应 51.0h， 生成 二苯并[a,h]蒽
  参考文献：
  名称：

  A new general synthesis of polycyclic aromatic compounds based on enamine chemistry

  摘要：

  Alkylation of enamines and enamine salts by benzylic and (beta-haloethyl)aryl halides, respectively, followed by acidic cyclodehydration and dehydrogenation provides an efficient synthetic approach to a wide range of polycyclic aromatic compounds of diverse structural types. Specific polycyclic hydrocarbons synthesized by this route include benzo[a]- and benzo[c]fluorene, 7H-dibenzo[c,g]-, 13H-dibenzo[a,i]-, and 13H-dibenzo[a,g]fluorene, 15H-tribenzo[a,c,i]fluorene, dibenzo[b,def]chrysene, benzo[rst]pentaphene, indeno[1,2-b]fluorene, fluoreno[3,4-c]fluorene, octahydrodibenz[a,j]anthracene, dibenz[a,j]anthracene, octahydrodibenz[a,h]anthracene, dibenz[a,h]anthracene, dibenz[a,h]anthracene, picene, benzo[c]picene, 1H-benz[bc]aceanthrylene, and 4H-cyclopenta[def]chrysene. This method with appropriate modifications appears to be potentially broader in scope than established traditional methods of polycyclic hydrocarbon synthesis.

  DOI：

  10.1021/jo00003a050
• 作为产物：
  描述：

  1,4-苯二乙酸 在 lithium aluminium tetrahydride 、 三乙胺 、 sodium iodide 作用下， 以 四氢呋喃 、 丙酮 为溶剂， 生成 1,4-双(2-碘乙基)苯
  参考文献：
  名称：

  A new general synthesis of polycyclic aromatic compounds based on enamine chemistry

  摘要：

  Alkylation of enamines and enamine salts by benzylic and (beta-haloethyl)aryl halides, respectively, followed by acidic cyclodehydration and dehydrogenation provides an efficient synthetic approach to a wide range of polycyclic aromatic compounds of diverse structural types. Specific polycyclic hydrocarbons synthesized by this route include benzo[a]- and benzo[c]fluorene, 7H-dibenzo[c,g]-, 13H-dibenzo[a,i]-, and 13H-dibenzo[a,g]fluorene, 15H-tribenzo[a,c,i]fluorene, dibenzo[b,def]chrysene, benzo[rst]pentaphene, indeno[1,2-b]fluorene, fluoreno[3,4-c]fluorene, octahydrodibenz[a,j]anthracene, dibenz[a,j]anthracene, octahydrodibenz[a,h]anthracene, dibenz[a,h]anthracene, dibenz[a,h]anthracene, picene, benzo[c]picene, 1H-benz[bc]aceanthrylene, and 4H-cyclopenta[def]chrysene. This method with appropriate modifications appears to be potentially broader in scope than established traditional methods of polycyclic hydrocarbon synthesis.

  DOI：

  10.1021/jo00003a050

文献信息

• Iodine transfer polymerization method and compositions therefrom
  申请人：Dow Global Technologies LLC

  公开号：US11390703B2

  公开（公告）日：2022-07-19

  Iodine transfer radical polymerization of an ethylenically unsaturated monomer comprising (meth)acrylic acid, salt thereof, or combination thereof, in the presence of a radical polymerization initiator, an organoiodide, and a solvent, is a useful method for making (meth)acrylic acid polymers. The amounts of components utilized can be 2 to 100 equivalents of acrylic acid and 2 to 100 equivalents of sodium acrylate, both dissolved in water to form a 15 to 50 weight percent solution, based on the total weight of the acrylic acid, sodium acrylate, and water; 0.05 to 1 equivalent of an azo polymerization initiator, 1 equivalent of an organoiodide; and 0 to 3 equivalents of an iodide salt. (Meth)acrylic acid polymer solutions are made by these methods. The (meth)acrylic polymers are useful as dispersants.

  乙烯基不饱和单体的碘转移自由基聚合在自由基聚合引发剂、有机碘化物和溶剂存在下，对于制备（甲基）丙烯酸聚合物是一种有用的方法。所述单体包含（甲基）丙烯酸、其盐或其混合物。所用组分的用量可为：2到100当量的丙烯酸、2到100当量的丙烯酸钠，两者均溶解于水中以形成基于丙烯酸、丙烯酸钠和水的总重量计15%到50%重量百分比的溶液；0.05到1当量的偶氮聚合引发剂；1当量的有机碘化物；以及0到3当量的碘化物盐。通过这些方法可以制备（甲基）丙烯酸聚合物溶液。所述（甲基）丙烯酸聚合物可用作分散剂。
• �ber Derivate des p-Phenylen-?, ??-di�thylalkohols, des m-und p-Diacetyl-benzols und der p-Phenylen-diacryls�ure. (49. Mitteilung �ber Stickstoff-Heterocyclen)
  作者：Paul Ruggli、Wilhelm Theilheimer

  DOI：10.1002/hlca.194102401108

  日期：——
• Highly Regioselective Transformation of <i>out</i>/<i>out</i>-<i>e</i><i>quatorial</i> Bis(formylmethano)[60]fullerenes:  Construction of Dissymmetric [60]Fullerene-Centered Triads
  作者：Hiroshi Ito、Yasuhiro Ishida、Kazuhiko Saigo

  DOI：10.1021/jo060110+

  日期：2006.6.1

  [GRAPHICS]Three kinds of out/out-equatorial bis( formylmethano)[ 60] fullerenes ( 1b-d) were obtained by the tether-directed bifunctionalization of [ 60] fullerene with bis( alpha-formylsulfonium ylide) s. The condensation of aromatic amines with 1b-d proceeded with an unexpectedly high regioselectivity to give one of two possible regioisomers of mono-imines as the main products ( the ratio of the regioisomers, up to 97: 3). By the transformation of the remaining formyl group in the mono-imines thus obtained, the corresponding dissymmetric bis-imines were efficiently synthesized.
• Regio- and diastereo-controlled synthesis of bis(formylmethano)[60]fullerenes and their application to the formation of [60]fullerene pearl-necklace polyimines
  作者：Hiroshi Ito、Yasuhiro Ishida、Kazuhiko Saigo

  DOI：10.1016/j.tetlet.2006.02.148

  日期：2006.5

  The tether-directed method was firstly applied to the biscyclopropanation of [60]fullerene via the addition-elimination reaction of bis(sulfonium ylide)s to give bis(formylmethano)[60]fullerenes with satisfactory regio- and stereoselectivity. The equatorialbisadduct thus obtained was used for the polycondensation with an aromatic diamine to afford the corresponding pearl-necklace polyimine with satisfactorily high degree of polymerization. (c) 2006 Elsevier Ltd. All rights reserved.
• HARYEY, RONALD G.;PATAKI, JOHN;CORTEZ, CECILIA;DI, RADDO PASQUALE;YANG, C+, J. ORG. CHEM., 56,(1991) N, C. 1210-1217
  作者：HARYEY, RONALD G.、PATAKI, JOHN、CORTEZ, CECILIA、DI, RADDO PASQUALE、YANG, C+

  DOI：——

  日期：——