1,4-蒽二甲酸 | 58791-45-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 中文名称: 1,4-蒽二甲酸
• 英文名称: 1,4-anthracenedicarboxylic acid
• 英文别名: 1,4-ADCA；anthracene-1,4-dicarboxylic acid；Anthracen-1,4-dicarbonsaeure
• CAS: 58791-45-0
• 化学式: C₁₆H₁₀O₄
• 分子量: 266.253
• InChiKey: HJGMZNDYNFRASP-UHFFFAOYSA-N

物化性质

• 沸点：
  576.0±33.0 °C(Predicted)
• 密度：
  1.457±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,4-蒽二甲酸 在 lithium aluminium tetrahydride 、 硫酸 、 氢溴酸 、 溶剂黄146 作用下， 生成 1,4-双(溴甲基)蒽
  参考文献：
  名称：

  Gundermann,K.-D.; Roeker,K.-D., Justus Liebigs Annalen der Chemie, 1976, p. 140 - 152

  摘要：

  DOI：
• 作为产物：
  描述：

  9,10-dioxo-9,10-dihydro-1,4-anthracene dicarboxylic acid 在 ammonium hydroxide 、 锌 作用下， 以49%的产率得到1,4-蒽二甲酸
  参考文献：
  名称：

  Synthesis, DNA-damaging and cytotoxic properties of novel topoisomerase II-directed bisantrene analogues

  摘要：

  New bisantrene analogues were synthesized, bearing one or two 4,5-dihydro-1H-imidazol-2-yl hydrazone side chains at positions 1,4 or 9 of the anthracene ring system. A 10-aza-bioisostere was also prepared. The position of substituents in structurally isomeric drugs modulates topoisomerase II poisoning and specificity, along with cytotoxicity. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0960-894x(97)10207-4

文献信息

• Compound having silsesquioxane skeleton and its polymer
  申请人：Inagaki Jyun-ichi

  公开号：US20050009982A1

  公开（公告）日：2005-01-13

  The present invention relates to a compound represented by Formula (1) and a polymer obtained using the compound: wherein R 1 is phenyl which may have substituents, Q 1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, and Q 2 is a group represented by Formula (2) wherein the code < represents a bonding point with silicon, l, m, n and p are independently 0, 1, 2 or 3, A 1 to A 4 are independently a single bond, 1,4-cyclohexylene, 1,4-cyclohexenylene, a condensed ring group having 6 to 10 carbon atoms which is a divalent group, or 1,4-phenylene, Z 0 to Z 3 are independently a single bond, —CH═CR—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms, and Z 4 is a single bond, —CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms. And Y 1 in Formula (1) is the group defined in Claim 1.

  本发明涉及一种由式（1）表示的化合物和使用该化合物获得的聚合物：其中R1是苯基，可能具有取代基；Q1是氢、卤素、具有1至10个碳原子的烷基、环丙基、环丁基、环戊基、环己基、环己烯基或苯基，其中可选的氢原子可被卤素或具有1至5个碳原子的烷基取代；Q2是由式（2）表示的基团，其中代码<表示与硅的连接点，l、m、n和p独立地为0、1、2或3，A1至A4独立地为单键、1,4-环己亚基、1,4-环己烯亚基、具有6至10个碳原子的缩合环基团，为二价基团，或1,4-苯亚基，Z0至Z3独立地为单键、—CH═CR—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基，Z4为单键、—CH═CH—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基。式（1）中的Y1是权利要求1中定义的基团。
• MODIFIER FOR AROMATIC POLYESTER AND AROMATIC POLYESTER RESIN COMPOSITION COMPRISING THE SAME
  申请人：TABATA Masayoshi

  公开号：US20110224343A1

  公开（公告）日：2011-09-15

  The present invention provides a modifier for aromatic polyesters which enhances the melt fluidity of aromatic polyesters without a significant decrease in the heat resistance of the aromatic polyesters, and an aromatic polyester resin composition including the modifier for aromatic polyesters. The present invention relates to a modifier for aromatic polyesters comprising polyhydric phenol residues and residues of aromatic polycarboxylic acid, acid halide or acid anhydride thereof, and the modifier comprises a material having a structure composed of a first residue selected from the group consisting of divalent residues represented by Formula (I): —Ar—W 1 x —Ar— and by Formula (II): —Ar—, the first residues being bonded to two identical or different second residues selected from the group consisting of monovalent residues represented by Formula (III): and monovalent residues represented by Formula (IV): —O—C(O)—R 7 —.

  本发明提供了一种用于芳香族聚酯的改性剂，可以增强芳香族聚酯的熔融流动性，而不明显降低芳香族聚酯的耐热性，以及包括该改性剂的芳香族聚酯树脂组合物。本发明涉及一种用于芳香族聚酯的改性剂，包括多羟基酚残基和芳香族多羧酸、酸卤或其酸酐残基，该改性剂包括具有以下结构的材料：第一残基，选择自由式(I)所代表的二价残基：—Ar—W1x—Ar—和自由式(II)所代表的：—Ar—，第一残基与选择自由式(III)所代表的单价残基：和自由式(IV)所代表的单价残基：—O—C(O)—R7—的两个相同或不同的第二残基结合。
• Process for the manufacture of 1,4-disubstituted bicyclic or tricyclic
  申请人：Ciba-Geigy Corporation

  公开号：US04011261A1

  公开（公告）日：1977-03-08

  The present invention provides a new process for the manufacture of 1,4-disubstituted bicyclic or tricyclic compounds by reacting a 1,2-bis-cyanomethyl-benzene or 2,3-bis-cyanomethyl-naphthalene with glyoxal in the presence of a base and a solvent as well as new 1,4-disubstituted bicyclic compounds.

  本发明提供了一种新的制备1,4-二取代的双环或三环化合物的方法，通过在碱和溶剂的存在下，将1,2-双(氰甲基)苯或2,3-双(氰甲基)萘与丙二醛反应。同时也提供了新的1,4-二取代的双环化合物。
• Method For Producing Bisbenzoxazoles
  申请人：KRULL Mathias

  公开号：US20100076040A1

  公开（公告）日：2010-03-25

  The invention relates to a method for producing bisbenzoxazoles that are interconnected by means of a system of conjugated double bonds, according to which o-aminophenols are reacted with dicarboxylic acids, the carboxyl groups of which are interconnected via a double bond or a system of conjugated double bonds, to form an ammonium salt, said ammonium salt being converted in the presence of dehydrogenating catalysts and solvents with a low dielectric loss into benzoxazol by means of microwave radiation.

  本发明涉及一种生产通过共轭双键系统相互连接的双苯并噁唑的方法，其中o-氨基酚与二羧酸反应，该二羧酸的羧基通过双键或共轭双键系统相互连接，形成一种铵盐，该铵盐在存在脱氢催化剂和低介电损耗溶剂的情况下，通过微波辐射转化为苯并噁唑。
• Reactive polymer-supporting porous film for battery seperator and use thereof
  申请人：Uetani Yoshihiro

  公开号：US20060257727A1

  公开（公告）日：2006-11-16

  The invention provides a reactive polymer-supporting porous film for use as a battery separator which comprises a porous substrate film and a partially crosslinked reactive polymer supported on the porous substrate film, the partially crosslinked reactive polymer being obtained by the reaction of a crosslinkable polymer having at least one reactive group selected from the group consisting of 3-oxetanyl group and epoxy group in the molecule with a polycarboxylic acid. The reactive polymer-supporting porous film for use as a battery separator has a separator and electrodes sufficiently bonded to each other and low inner resistance so that it is suitably used for production of battery excellent in high rate performance. Further, the invention provides a method of producing a battery which comprises placing the electrode/reactive polymer-supporting porous film layered body in a battery container; introducing an electrolytic solution containing a cationic polymerization catalyst into the battery container thereby bonding the porous film and the electrodes together.

  本发明提供一种反应性聚合物支持多孔膜，用于作为电池隔膜，包括多孔基底膜和部分交联的反应性聚合物支持在多孔基底膜上，所述部分交联的反应性聚合物是通过交联性聚合物与多羧酸反应而得到的，所述交联性聚合物在分子中至少具有3-氧杂环基团和环氧基团中的一种反应性基团。作为电池隔膜使用的反应性聚合物支持多孔膜，具有足够紧密结合的隔膜和电极以及低内阻，因此适用于生产高速性能优异的电池。此外，本发明还提供一种电池的制造方法，其中包括将电极/反应性聚合物支持多孔膜层状体放置在电池容器中；向电池容器中引入含有阳离子聚合催化剂的电解液，从而将多孔膜和电极粘合在一起。