1,5,9-三甲基-13-氧杂二环[10.1.0]-十三烷基-4,8-二烯 | 13786-79-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 中文名称: 1,5,9-三甲基-13-氧杂二环[10.1.0]-十三烷基-4,8-二烯
• 英文名称: 13-Oxabicyclo[10.1.0]trideca-4,8-diene, 1,5,9-trimethyl-
• 英文别名: 1,5,9-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-diene
• CAS: 13786-79-3
• 化学式: C₁₅H₂₄O
• 分子量: 220.35
• InChiKey: PAZWFUGWOAQBJJ-UHFFFAOYSA-N

物化性质

• 沸点：
  106-108 °C(Press: 1 Torr)
• 密度：
  0.918±0.06 g/cm3(Predicted)
• LogP：
  4.647 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• [EN] HINDERED KETONES AS PERFUMING INGREDIENTS<br/>[FR] CETONES ENCOMBREES UTILISEES EN TANT QU'INGREDIENTS DE PARFUMERIE
  申请人：FIRMENICH & CIE

  公开号：WO2003099754A1

  公开（公告）日：2003-12-04

  The present invention relates to the perfumery industry. It concerns more particularly a β-Ϝ unsaturated hindered ketone of formula - formula (I) -wherein R represents, simultaneously or independently, a C1 to C4 linear or branched alkyl group, and in the form of any one of its isomers, i.e. optical isomers or diastereoisomers, or of a mixture thereof. Its use as perfuming ingredient, as well as the perfumed articles or perfuming compositions comprising as active ingredient a compound of formula (I) are also an object of the invention.

  本发明涉及香料工业。它更具体地涉及一种β-Ϝ不饱和受阻酮，其化学式为(I)，其中R同时或独立地代表C1到C4的直链或支链烷基基团，以及其任一异构体形式，即光学异构体或二对映异构体，或二者的混合物。其用作香料成分，以及包含化合物(I)作为活性成分的香料制品或香料组合物也是本发明的对象。
• DERIVATIVES OF 1-(4-METHYLCYCLOHEXYL)-ETHANOLS
  申请人：Symrise AG

  公开号：US20170002294A1

  公开（公告）日：2017-01-05

  The invention relates to mixtures having: components (a) having at least one fragrance of the formula (I) where R1=OC-R2, CH 2 OR3, C1-C8 open-chain or branched aliphatic radical, optionally substituted and/or unsaturated, with R2=an open-chain or branched aliphatic radical, optionally substituted and/or unsaturated, having 2-10 C atoms, with R3=an open-chain or branched aliphatic radical, optionally substituted and/or unsaturated, having 1-8 C atoms, and components (b) having at least one fragrance, different from the fragrances of component a, characterized in that the weight ratio of all components (a) to all components (b) is from 1:10 to 1:10000.

  该发明涉及具有以下特征的混合物：组分(a)至少具有一个符合以下式(I)的香料，其中R1=OC-R2，CH2OR3，C1-C8开链或支链脂肪基，可选择地取代和/或不饱和，其中R2=一个开链或支链脂肪基，可选择地取代和/或不饱和，含有2-10个碳原子，其中R3=一个开链或支链脂肪基，可选择地取代和/或不饱和，含有1-8个碳原子，以及组分(b)至少具有一个与组分a的香料不同的香料，其特征在于所有组分(a)与所有组分(b)的重量比为1:10至1:10000。
• Ambergris and/or indole-like compositions of odoriferous substances
  申请人：SYMRISE AG

  公开号：US10920169B2

  公开（公告）日：2021-02-16

  The present invention primarily relates to the use of one or more compound(s) of formula (I) as fragrance, wherein R is methyl or ethyl and R1 is H, methyl or ethyl. The invention further relates to new fragrance compositions comprising one or more compound(s) of formula (I), as described herein, the use of said fragrance compositions, perfumed articles comprising said fragrance compositions, and various methods of perfuming said articles or for imparting, modifying and/or enhancing certain olfactory notes.

  本发明主要涉及将一个或多个式(I)化合物作为香精使用，其中R为甲基或乙基，R1为H、甲基或乙基。该发明还涉及包含一个或多个式(I)化合物的新香精组合物，所述组合物的使用，包含所述香精组合物的香水制品，以及用于给制品添加、改变和/或增强某些嗅觉音符的各种香水方法。
• 2-Methyl-2-alkenyl-substituted 1,3-dioxanes as odoriferous substances
  申请人：Bertram Heinz-Jurgen

  公开号：US20080070825A1

  公开（公告）日：2008-03-20

  The present invention relates to a compound of the formula (I) wherein R 1 denotes hydrogen or methyl, and R 2 and R 3 independently of one another denote methyl or ethyl.

  本发明涉及一种化合物，其化学式为（I），其中R1代表氢或甲基，R2和R3分别独立地代表甲基或乙基。
• 2-ALKOXYMETHYL-3-ISOALKENYL-1-METHYLCYCLOPENTENES, USE THEREOF, IN PARTICULAR AS FRAGRANCE SUBSTANCES, CORRESPONDING ARTICLES AND PRODUCTION METHODS
  申请人：Panten Johannes

  公开号：US20090092725A1

  公开（公告）日：2009-04-09

  Compounds of formula (A) are described wherein, independently of one another, the following applies to groups R and R 1 : R is methyl or ethyl, and R 1 is hydrogen or methyl, wherein the meandering line shows that for R 1 =methyl, the associated double bind is (E)- or (Z)-configured. Furthermore, methods for producing compounds of formula (A) and the use of corresponding compounds as fragrance and/or flavouring substances are described.

  描述了公式(A)的化合物，其中独立地，对于基团R和R1，以下情况适用：R为甲基或乙基，R1为氢或甲基，其中蜿蜒线表示对于R1=甲基，相关的双键为(E)-或(Z)-构型。此外，还描述了制备公式(A)化合物的方法以及相应化合物作为香料和/或调味物质的用途。