柠檬黄素-3-O-芸香糖苷 | 79384-27-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 黄酮类化合物
• 中文名称: 柠檬黄素-3-O-芸香糖苷
• 英文名称: limocitrin 3-O-rutinoside
• 英文别名: Limocitrin-3-O-rutinoside；5,7-dihydroxy-2-(4-hydroxy-3-methoxyphenyl)-8-methoxy-3-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-[[(2R,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxymethyl]oxan-2-yl]oxychromen-4-one
• CAS: 79384-27-3
• 化学式: C₂₉H₃₄O₁₇
• 分子量: 654.579
• InChiKey: SCMBTGLLYCNHPV-GSRPHVBRSA-N

物化性质

• 沸点：
  967.6±65.0 °C(Predicted)
• 密度：
  1.72±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -1
• 重原子数：
  46
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  264
• 氢给体数：
  9
• 氢受体数：
  17

反应信息

• 作为产物：
  描述：

  limocitrin 3-O-rutinoside-7-O-β-glucopyranoside 在 β-glucosidase 作用下， 以 acetate buffer 为溶剂， 反应 1.0h， 生成 柠檬黄素-3-O-芸香糖苷
  参考文献：
  名称：

  Flavonoid and benzophenone glycosides from Coleogyne ramosissima

  摘要：

  A benzophenone glucoside and two flavonol glycosides were isolated together with 27 known polyphenols from the aerial parts of Coleogyne ramosissima, and their structures were elucidated by spectroscopic and chemical methods as iriflophenone 2-O-beta-glucogyranoside, isorhamnetin 3-O-2(G)-rhamnopyranosylrutinoside-7-O-alpha-rhamnopyranoside and limocitrin 3-O-rutinoside-7-O-beta-glucopylanoside, respectively. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0031-9422(00)00192-8

文献信息

• Flavonoid and benzophenone glycosides from Coleogyne ramosissima
  作者：Hideyuki Ito、Eisei Nishitani、Takao Konoshima、Midori Takasaki、Mutsuo Kozuka、Takashi Yoshida

  DOI：10.1016/s0031-9422(00)00192-8

  日期：2000.8

  A benzophenone glucoside and two flavonol glycosides were isolated together with 27 known polyphenols from the aerial parts of Coleogyne ramosissima, and their structures were elucidated by spectroscopic and chemical methods as iriflophenone 2-O-beta-glucogyranoside, isorhamnetin 3-O-2(G)-rhamnopyranosylrutinoside-7-O-alpha-rhamnopyranoside and limocitrin 3-O-rutinoside-7-O-beta-glucopylanoside, respectively. (C) 2000 Elsevier Science Ltd. All rights reserved.