1-[4-(1-羟基-1-苯基丙-2-炔基)苯基]-1-苯基丙-2-炔-1-醇 | 15880-27-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-[4-(1-羟基-1-苯基丙-2-炔基)苯基]-1-苯基丙-2-炔-1-醇
• 英文名称: 1-[4-(1-hydroxy-1-phenylprop-2-ynyl)phenyl]-1-phenylprop-2-yn-1-ol
• 英文别名: 1,4-bis(1-hydroxy-1-phenylprop-2-yn-1-yl)benzene；1,4-di(1-hydroxy-1-phenyl-prop-2-ynyl)benzene；HCC(OH)C(Ph)-p-C6H4(Ph)C(OH)CCH；1,4-C6H4(C(Ph)(OH)CCH)2；1,4-Bis-<1-phenyl-1-hydroxy-propin-(2)-yl>-benzol；1,4-Bis-(1-phenyl-1-hydroxy-prop-2-inyl)-benzol
• CAS: 15880-27-0
• 化学式: C₂₄H₁₈O₂
• 分子量: 338.406
• InChiKey: UICIKNPXDNBQFZ-UHFFFAOYSA-N

物化性质

• 沸点：
  501.7±45.0 °C(Predicted)
• 密度：
  1.214±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-[4-(1-羟基-1-苯基丙-2-炔基)苯基]-1-苯基丙-2-炔-1-醇 在 4-甲基苯磺酸吡啶 、 原甲酸三甲酯 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 4.0h， 生成 13-oxo-3-phenyl-3-[p-(2-phenyl-2H-naphtho[1,2-b]pyran-2-yl)]phenylindeno[2,1-f]naphtho[1,2-b]pyran
  参考文献：
  名称：

  Spectrokinetic studies on new bi-photochromic molecules containing two naphthopyran entities

  摘要：

  A range of new bi-photochromic molecules containing two identical (3a-d) or two distinct naphthopyran units (6a-d), linked through the phenyl substituents located on the sp(3) hybridised pyran ring carbon atom, using conjugated and non-conjugated spacers, have been synthesised from bis-propynols and (substituted) naphthols. Study of the spectrokinetic properties of these compounds under near UV-vis continuous irradiation conditions revealed that the two naphthopyran units are stimulated independently leading to open forms with higher colourabilities but without affecting the individual bleaching kinetics. Compared to the individual photochromic components and to model mono-photochromes it was observed that the nature of the bridge has a small effect on the photochromic properties of each system. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2005.09.035
• 作为产物：
  描述：

  1,4-联苯酰基苯 、 乙炔钠 在 乙炔 作用下， 以 四氢呋喃 、 二甲基亚砜 为溶剂， 以72.6%的产率得到1-[4-(1-羟基-1-苯基丙-2-炔基)苯基]-1-苯基丙-2-炔-1-醇
  参考文献：
  名称：

  新型亚苯基连接的光致变色双吡喃的合成和光致变色。

  摘要：

  [反应：见正文]通过双炔丙基醇与萘酚的一锅反应以高收率合成了苯连接的双萘并吡喃。1,4-亚苯基连接的双吡喃中随温度变化的光致变色现象导致在室温和-20摄氏度下形成的有色物质之间出现高达60 nm的红移。在1,4-亚苯基中观察到更好的抗疲劳性和更高的可着色性与1，3-亚苯基连接的双-[2H]-萘并[1,2-b]吡喃相比，双-[2H]-萘并[1,2-b]吡喃。

  DOI：

  10.1021/ol052587y

文献信息

• Carbon‐Rich Ruthenium Complexes Containing Bis(allenylidene) and Mixed Alkynyl−Allenylidene Bridges
  作者：Stéphane Rigaut、Johann Perruchon、Salaheddine Guesmi、Claire Fave、Daniel Touchard、Pierre H. Dixneuf

  DOI：10.1002/ejic.200400457

  日期：2005.2

  Complexes cis-[RuCl(dppe)2][X] (2a X = PF6, 2b X = CF3SO3) react with a variety of bis(propargylic) alcohols to selectively lead to mono-trans-[Cl(dppe)2Ru=C=C=C(R)−T−C(R)(OH)(C≡C−H)][X] (4) [R = H, Ph; T = m,p-(C6H4), 2,5-(thiophene), 5,5′-(2,2′-bithiophene), 5,5′′-(2,2′:5′2′′-terthiophene), −C≡C−] or bis(allenylidene) trans-[Cl(dppe)2Ru=C=C=C(R)−T−(R)C=C=C=RuCl(dppe)2][X]2 (5) complexes. New dimetallic

  配合物顺式-[RuCl(dppe)2][X] (2a X = PF6, 2b X = CF3SO3) 与多种双（炔）醇反应选择性地生成单反式-[Cl(dppe)2Ru=C =C=C(R)−T−C(R)(OH)(C≡C−H)][X] (4) [R = H, Ph; T = m,p-(C6H4), 2,5-(噻吩), 5,5'-(2,2'-联噻吩), 5,5''-(2,2':5'2''- terthiophene), -C≡C-] 或双（亚丙叉基）反式-[Cl(dppe)2Ru=C=C=C(R)-T-(R)C=C=C=RuCl(dppe)2][ X]2 (5) 络合物。新的双金属和三金属配合物含有混合炔基-亚丙叉基桥，反式-[Cl(dppe)2Ru-C≡C-p-(C6H4)-(Ph)C=C=C=RuCl(dppe)2][CF3SO3] ( 12) 和反式-[Cl(dppe)2Ru-C≡C-p
• Synthesis, Characterization, and Electrochemical Behavior of Mono- and Bimetallic Ruthenium and Rhenium Allenylidenes Bearing Multiconjugated Organic Spacers
  作者：Nicoletta Mantovani、Michele Brugnati、Luca Gonsalvi、Emanuela Grigiotti、Franco Laschi、Lorenza Marvelli、Maurizio Peruzzini、Gianna Reginato、Roberto Rossi、Piero Zanello

  DOI：10.1021/om0492193

  日期：2005.1.1

  and Re and homobimetallic Ru/Ru and heterobimetallic Ru/Re complexes bridged by multiconjugated aromatic organic spacers such as bianthracenylidene and biphenylene were obtained and characterized by conventional spectroscopic techniques and elemental analysis. Electrochemical measurements coupled to spectroelectrochemistry and EPR spectroscopy proved that in the bis(allenylidene) complexes an electronic

  得到了新型的Ru和Re的单亚烯基以及同双金属Ru / Ru和异双金属Ru / Re配合物，它们由多共轭芳族有机间隔基如联蒽和亚联苯桥接，并通过常规光谱技术和元素分析对其进行了表征。电化学测量与光谱电化学和EPR光谱相结合证明，在双（亚烯基）络合物中，两个亚烯基桥或两个金属中心之间存在电子通信，从而诱使分子内电子迁移性增强。
• Synthesis and reactivity of dinuclear rhodium complexes with RhCCHR and RhCCCRR′ units as building blocks
  作者：Berta Callejas-Gaspar、Matthias Laubender、Helmut Werner

  DOI：10.1016/s0022-328x(03)00521-7

  日期：2003.11

  The reaction of [Rhκ2-O2S(O)CF3}(PiPr3)2] (1) with ethynylferrocene in the presence of KF affords the substituted vinylidene complex trans-[RhFCCH(C5H4)Fe(C5H5)}(PiPr3)2] (2) which upon treatment with the butadiyne derivative Ph3SnCCCCSnPh3 produces the chain-like compound trans-[(μ-CCCC)Rh(CCH(C5H4)Fe(C5H5))(PiPr3)2}2] (7). The triflato complex 1 reacts with 1,4-C6H4(CCH)2 to give the

  的的[Rh κ反应2 -O 2 S（O）CF 3 }（P我镨3）2 ]（1），在KF存在ethynylferrocene，得到取代的亚乙烯基复杂的反式[RHF CCH - （C 5 H ^ 4）的Fe（C 5 H ^ 5）}（P我镨3）2 ]（2），其在与所述丁二炔衍生物pH处理3 SnCCCCSnPh 3产生链状化合物反式- [（μ-CCCC）Rh（CCH（C 5 H 4）Fe（C 5 H 5））（P i Pr 3）2 } 2 ]（7）。三氟甲磺酸盐络合物1与1,4-C 6 H 4（CCH）2反应，生成双核化合物反式-[μ-1,4- C6 H 4（CHC）2 } Rh（ η 1 -OS（O）2 CF 3）（P我镨3）2 } 2 ]（3），在存在KF的情况下进行配体交换，得到相应的二氟衍生物4。由4和RC ＝CSnPh 3（R ＝ CH 3，C 6 H 5）得到配合物5和6，其中C
• Synthesis and Photochromism of Novel Phenylene-Linked Photochromic Bispyrans
  作者：Weili Zhao、Erick M. Carreira

  DOI：10.1021/ol052587y

  日期：2006.1.1

  [reaction: see text] Phenylene-linked bisnaphthopyrans were synthesized in good yields via the one-pot reaction of bis-propargyl alcohols with naphthols. Temperature-dependent photochromism in 1,4-phenylene-linked bispyrans leads to up to 60 nm bathochromic shift between the colored species formed at room temperature and at -20 degrees C. Better fatigue resistance and higher colorability was observed

  [反应：见正文]通过双炔丙基醇与萘酚的一锅反应以高收率合成了苯连接的双萘并吡喃。1,4-亚苯基连接的双吡喃中随温度变化的光致变色现象导致在室温和-20摄氏度下形成的有色物质之间出现高达60 nm的红移。在1,4-亚苯基中观察到更好的抗疲劳性和更高的可着色性与1，3-亚苯基连接的双-[2H]-萘并[1,2-b]吡喃相比，双-[2H]-萘并[1,2-b]吡喃。
• Spectrokinetic studies on new bi-photochromic molecules containing two naphthopyran entities
  作者：Paulo J. Coelho、Maria A. Salvador、B.Mark Heron、Luis M. Carvalho

  DOI：10.1016/j.tet.2005.09.035

  日期：2005.12

  A range of new bi-photochromic molecules containing two identical (3a-d) or two distinct naphthopyran units (6a-d), linked through the phenyl substituents located on the sp(3) hybridised pyran ring carbon atom, using conjugated and non-conjugated spacers, have been synthesised from bis-propynols and (substituted) naphthols. Study of the spectrokinetic properties of these compounds under near UV-vis continuous irradiation conditions revealed that the two naphthopyran units are stimulated independently leading to open forms with higher colourabilities but without affecting the individual bleaching kinetics. Compared to the individual photochromic components and to model mono-photochromes it was observed that the nature of the bridge has a small effect on the photochromic properties of each system. (c) 2005 Elsevier Ltd. All rights reserved.