1-丁基-2-甲基环丙烷 | 2511-92-4

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• 中文名称: 1-丁基-2-甲基环丙烷
• 英文名称: 1-Butyl-2-methylcyclopropane
• 英文别名: 1-n-Butyl-2-methyl-cyclopropan；1-Methyl-2-n-butylcyclopropan；2-Butyl-1-methyl-cyclopropan
• CAS: 2511-92-4
• 化学式: C₈H₁₆
• 分子量: 112.215
• InChiKey: IWTBNPKBPXCCIV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  3,3-Dichlor-2-butyl-1-methyl-cyclopropan 、 naphthalen-1-yl-lithium 生成 1-丁基-2-甲基环丙烷
  参考文献：
  名称：

  WATANABE, SHOJI;FUJITA, TSUTOMU;SUGA, KYOICHI;KURAMOCHI, TADAO;SUGAHARA, +, YUKAGAKU, 1982, 31, N 7, 452-455

  摘要：

  DOI：

文献信息

• Pyrolysis of Alkyl Acetates. A Radical Pathway for the Formation of Minor Products
  作者：Buchang Shi、Ying Ji、Hossein A. Dabbagh、Burtron H. Davis

  DOI：10.1021/jo00083a028

  日期：1994.2

  Decyl acetate and decene pyrolysis under the same reaction conditions show that the formation of the minor products during the pyrolysis of esters occurs by a parallel, and not a secondary, reaction. The radioactivity observed in the CO2 and CO produced during the pyrolysis of 1-hexyl acetate-1-C-14 and the radioactivity in the methane from the pyrolysis of 1-hexyl acetate-2-C-14 strongly suggested a radical reaction pathway for the formation of the minor products. Considering the above results together with the radioactivity data of gas samples from the pyrolysis of 1-decyl-1-C-14 acetate, 1-hexyl-1 -C-14 acetate, and 1-heptadecyl-1-C-14 acetate leads to the conclusion that the mechanism of pyrolysis of esters may be viewed as a cyclo-D(E)D(N)A(N) mechanism for the formation of the major alkene product and a radical mechanism for the formation of minor products. A useful synthetic procedure for the preparation of high carbon number alkenes (>10) also results from this study.
• WATANABE, SHOJI;FUJITA, TSUTOMU;SUGA, KYOICHI;KURAMOCHI, TADAO;SUGAHARA, +, YUKAGAKU, 1982, 31, N 7, 452-455
  作者：WATANABE, SHOJI、FUJITA, TSUTOMU、SUGA, KYOICHI、KURAMOCHI, TADAO、SUGAHARA, +

  DOI：——

  日期：——