1-乙酰氧基-4,4-二甲基-己烷 | 5947-22-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 1-乙酰氧基-4,4-二甲基-己烷
• 英文名称: 1-acetoxy-4,4-dimethyl-hexane
• 英文别名: 4,4-Dimethylhexyl acetate；4,4-dimethylhexyl acetate
• CAS: 5947-22-8
• 化学式: C₁₀H₂₀O₂
• 分子量: 172.268
• InChiKey: DXOBTNNTPVUEOU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  magnesium,2-methylbutane,chloride 在 lead(IV) acetate 、 calcium carbonate 、 过氧化苯甲酰 作用下， 以 苯 为溶剂， 反应 5.0h， 生成 1-乙酰氧基-4,4-二甲基-己烷
  参考文献：
  名称：

  饱和脂族醇的四乙酸铅氧化—IV：六元环醚的形成

  摘要：

  具有不允许1，5-环化的结构的饱和脂族醇的四乙酸铅氧化，得到的四氢吡喃衍生物的产率不超过16％。由4，4-二甲基-1-戊醇形成的少量重排的醚2-乙基-2-甲基四氢呋喃表明环化反应是通过具有碳酸根离子特征的中间体进行的。

  DOI：

  10.1016/s0040-4020(01)98366-8

文献信息

• US9490480B2
  申请人：——

  公开号：US9490480B2

  公开（公告）日：2016-11-08
• [EN] MOLECULAR PRECURSORS FOR LITHIUM ION BATTERY CATHODE MATERIALS<br/>[FR] PRÉCURSEURS MOLÉCULAIRES POUR MATÉRIAUX DE CATHODE POUR ACCUMULATEURS LITHIUM-ION
  申请人：PRECURSOR ENERGETICS INC

  公开号：WO2014004776A2

  公开（公告）日：2014-01-03

  Lithium-cobalt, lithium-manganese and lithium-nickel molecular precursor compounds, compositions and processes for making cathodes for lithium ion batteries. The molecular precursor compounds are soluble and provide processes to make stoichiometric cathode materials with solution-based processes. The cathode material can be, for example, a lithium cobalt oxide, a lithium cobalt phosphate, a lithium cobalt silicate, a lithium manganese oxide, a lithium manganese phosphate, a lithium manganese silicate, a lithium nickel oxide, a lithium nickel phosphate, or a lithium nickel silicate. Cathodes can be made as bulk material in a solid form or in solution, or in various forms including thin films.
• [EN] MOLECULAR PRECURSORS FOR SYNTHESIS OF LITHIUM-IRON-CONTAINING CATHODE MATERIALS<br/>[FR] PRÉCURSEURS MOLÉCULAIRES POUR LA SYNTHÈSE DE MATÉRIAUX DE CATHODE CONTENANT DU LITHIUM- FER
  申请人：PRECURSOR ENERGETICS INC

  公开号：WO2014004789A2

  公开（公告）日：2014-01-03

  Lithium-iron molecular precursor compounds, compositions and processes for making a cathode for lithium ion batteries. The molecular precursor compounds are soluble and provide processes to make stoichiometric cathode materials with solution-based processes. The cathode material can be, for example, a lithium iron oxide, a lithium iron phosphate, or a lithium iron silicate. Cathodes can be made as bulk material in a solid form or in solution, or in various forms including thin films.
• [EN] PROCESSES AND COMPOSITIONS FOR MULTI-TRANSITION METALCONTAINING CATHODE MATERIALS USING MOLECULAR PRECURSORS<br/>[FR] PROCÉDÉS ET COMPOSITIONS POUR MATÉRIAUX DE CATHODE CONTENANT DES MÉTAUX DE TRANSITION MULTIPLES AU MOYEN DE PRÉCURSEURS MOLÉCULAIRES
  申请人：PRECURSOR ENERGETICS INC

  公开号：WO2014004817A2

  公开（公告）日：2014-01-03

  Processes and compositions for multi-transition metal-containing cathode materials for lithium ion batteries. Processes encompass providing a composition which can be a mixture of molecular precursor compounds having the formulas [LiM(x+)(OR)1+x] and [Li2M(x+)(OR)2+x]. The metal atoms, M, can be Ni, V, Co, Mn, or Fe, and the -OR groups can be alkoxy, aryloxy, heteroaryloxy, alkenyloxy, siloxy, phosphinate, phosphonate, and phosphate. The compositions can be converted and annealed to provide cathode materials.
• Lead tetraacetate oxidation of saturated aliphatic alcohols—IV
  作者：M.Lj. Mihailović、Ž. C̆eković、D. Jeremić

  DOI：10.1016/s0040-4020(01)98366-8

  日期：1965.1

  The lead tetraacetate oxidation of saturated aliphatic alcohols, with structures which do not permit 1,5-cyclization, gave tetrahydropyran derivatives in yields not exceeding 16%. The formation of a small amount of the rearranged ether, 2-ethyl-2-methyltetrahydrofuran, from 4,4-dimethyl-1-pentanol indicates that the cyclization reaction proceeds via an intermediate with carbonium ion character.

  具有不允许1，5-环化的结构的饱和脂族醇的四乙酸铅氧化，得到的四氢吡喃衍生物的产率不超过16％。由4，4-二甲基-1-戊醇形成的少量重排的醚2-乙基-2-甲基四氢呋喃表明环化反应是通过具有碳酸根离子特征的中间体进行的。