1-十四烷醇,14-巯基- | 131215-94-6

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醇
• 中文名称: 1-十四烷醇,14-巯基-
• 英文名称: 14-hydroxytetradecane-1-thiol
• 英文别名: 14-mercaptotetradecan-1-ol；14-Sulfanyltetradecan-1-OL
• CAS: 131215-94-6
• 化学式: C₁₄H₃₀OS
• 分子量: 246.458
• InChiKey: KIQDSYRSJKCHCM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  16
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  21.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  、 1-十四烷醇,14-巯基- 在 对甲苯磺酸 作用下， 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  CN116854615

  摘要：

  公开号：

文献信息

• Immobilization of biological molecules onto surfaces coated with monolayers
  申请人：Hodneland Christian

  公开号：US20090325262A1

  公开（公告）日：2009-12-31

  The present invention provides an article for immobilizing functional organic biomolecules through a covalent bond to a thiolate monolayer on a coinage metal surface. Also provided are methods for making the article and method for the immobilization of functional organic biomolecules on the article. The thiolate monolayer contains two moieties, one having an inert group that is resistant to reacting with biomolecules and one having a covalent bond forming group that reacts with the functional organic biomolecule to covalently immobilize it on the monolayer.

  本发明提供了一种通过共价键与硬币金属表面上的硫醇单层上的硫醇酸盐单层上的功能性有机生物分子固定的文章。还提供了制作该文章的方法以及将功能性有机生物分子固定在该文章上的方法。硫醇酸盐单层包含两种成分，一种具有惰性基团，对生物分子不易反应，另一种具有共价键形成基团，与功能性有机生物分子反应以共价固定在单层上。
• Thermoplastic resin composition
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：EP0513812A2

  公开（公告）日：1992-11-19

  A thermoplastic resin composition is disclosed, comprising (A) from 10 to 90% by weight of a hydroxy-substituted poly(phenylene ether) ether resin comprising p repeating units represented by formula (I): wherein m represents an integer of from 1 to 4; n represents an integer of from 0 to 3; the sum of m and n is not greater than 4; J represents (HO)a-R1-S-R2-, wherein a represents an integer of from 1 to 6; R' represents a halogen-substituted or unsubstituted polyvalent aliphatic hydrocarbon group having from 1 to 20 carbon atoms which may contain an oxygen atom in the carbon chain thereof or a halogen-substituted or unsubstituted polyvalent aromatic hydrocarbon group having from 1 to 20 carbon atoms; and R2 represents an alkylene group having from 2 to 20 carbon atoms; when m is 2 or more, the plural J groups may be the same or different; K represents a halogen atom, a primary or secondary alkyl group having from 1 to 20 carbon atoms, an alkenyl group having from 2 to 20 carbon atoms, a phenyl group, an aminoalkyl group having from 1 to 20 carbon atoms, a haloalkyl group having from 1 to 20 carbon atoms, an alkoxy group having from 1 to 20 carbon atoms, or a halohydrocarbonoxy group having from 1 to 20 carbon atoms; and when n is 2 or more, the plural K groups may be the same or different, and q repeating units represented by formula (II): wherein Q1, Q2, Q3, and Q4 each represent a hydrogen atom, a halogen atom, a primary or secondary alkyl group having from 1 to 20 carbon atoms, an alkenyl group having from 2 to 20 carbon atoms, a phenyl group, an aminoalkyl group having from 1 to 20 carbon atoms, a haloalkyl group having from 1 to 20 carbon atoms, an alkoxy group having from 1 to 20 carbon atoms, or a halohydrocarbonoxy group having from 1 to 20 carbon atoms, with p and q satisfying formulae: and (B) from 10 to 90% by weight of a thermoplastic resin selected from a saturated polyester resin and a polyamide resin. The composition is excellent in moldability and provides molded articles excellent in impact strength, heat resistance, and hue.

  本发明公开了一种热塑性树脂组合物，其中包括 (A) 10% 至 90% （按重量计）的羟基取代的聚（亚苯基醚）醚树脂，该树脂包含由式 (I) 代表的 p 个重复单元： 其中 m 代表 1 至 4 的整数；n 代表 0 至 3 的整数；m 和 n 之和不大于 4；J 代表 (HO)a-R1-S-R2-，其中 a 代表 1 至 6 的整数；R' 代表具有 1 至 20 个碳原子的卤素取代或未取代的多价脂族烃基，其碳链中可含有一 个氧原子，或具有 1 至 20 个碳原子的卤素取代或未取代的多价芳族烃基；以及 R2 代表具有 2 至 20 个碳原子的亚烷基；当 m 为 2 或 2 个以上时，多个 J 基团可以相同或不同；K 代表卤素原子、具有 1 至 20 个碳原子的伯或仲烷基、具有 2 至 20 个碳原子的烯基、苯基、具有 1 至 20 个碳原子的氨基烷基、具有 1 至 20 个碳原子的卤代烷基、具有 1 至 20 个碳原子的烷氧基或具有 1 至 20 个碳原子的卤代烃氧基；当 n 为 2 或 2 个以上时，多个 K 基团可以相同或不同、 和 q 个由式 (II) 代表的重复单元： 其中 Q1、Q2、Q3 和 Q4 分别代表氢原子、卤素原子、具有 1 至 20 个碳原子的伯或仲烷基、具有 2 至 20 个碳原子的烯基、苯基、具有 1 至 20 个碳原子的氨基烷基、具有 1 至 20 个碳原子的卤代烷基、具有 1 至 20 个碳原子的烷氧基或具有 1 至 20 个碳原子的卤代烃氧基，p 和 q 满足式： 和 (B) 10%至 90%（按重量计）的热塑性树脂，选自饱和聚酯树脂和聚酰胺树脂。该组合物具有优异的可模塑性，可提供抗冲击强度、耐热性和色调优异的模塑制品。
• Polymer parts
  申请人：Sony DADC Austria AG

  公开号：EP2792471A1

  公开（公告）日：2014-10-22

  A method of producing a polymer part comprising the following steps: (a) incorporating a hydrophobic small molecule into the polymer before, during or after manufacture of the polymer part, the hydrophobic small molecule and the polymer being essentially inert to one another; and (b) annealing the polymer part to induce migration of the hydrophobic small molecules to a surface of the polymer part to provide that surface with a specified degree of hydrophobicity defined by the combination of the polymer and the hydrophobic small molecule; is described. Polymer parts made according to the method are also described.

  一种生产聚合物部件的方法，包括以下步骤：(a) 在制造聚合物部件之前、期间或之后，将疏水性小分子掺入聚合物中，疏水性小分子和聚合物基本上互为惰性；以及 (b) 对聚合物部件进行退火处理，促使疏水性小分子迁移到聚合物部件的表面，使该表面具有由聚合物和疏水性小分子的组合确定的特定疏水性。还描述了根据该方法制造的聚合物部件。
• Method of producing a polymer part and polymer part
  申请人：STRATEC CONSUMABLES GmbH

  公开号：US10611890B2

  公开（公告）日：2020-04-07

  A method of producing a polymer part comprising the following steps: (a) incorporating a hydrophobic small molecule into the polymer before, during or after manufacture of the polymer part, the hydrophobic small molecule and the polymer being essentially inert to one another; and (b) annealing the polymer part to induce migration of the hydrophobic small molecules to a surface of the polymer part to provide that surface with a specified degree of hydrophobicity defined by the combination of the polymer and the hydrophobic small molecule; is described. Polymer parts made according to the method are also described.

  一种生产聚合物部件的方法，包括以下步骤：(a) 在制造聚合物部件之前、期间或之后，将疏水性小分子掺入聚合物中，疏水性小分子和聚合物基本上互为惰性；以及 (b) 对聚合物部件进行退火处理，促使疏水性小分子迁移到聚合物部件的表面，使该表面具有由聚合物和疏水性小分子的组合确定的特定疏水性。还描述了根据该方法制造的聚合物部件。
• Polymer slides having hydrophobic small molecules
  申请人：STRATEC Consumables GmbH

  公开号：US10800895B2

  公开（公告）日：2020-10-13

  A plurality of polymer slides, each having a polymer part with a first polymer surface portion uncoated and a second surface portion coated with a metal. The first and second surface portions each have different surface coating properties and have respective first and second specified degrees of hydrophobicity which are different from each other. A hydrophobic small molecule is located in the polymer part of each polymer slide, and the hydrophobic small molecule and the polymer are essentially inert to one another. Adjacent polymer slides are arranged in a manner that the first polymer surface of one slide faces a metal coated second surface portion of another slide. The hydrophobic small molecule evaporates from said first polymer surface portion of the polymer part of one polymer slide onto the adjacent metal coated second surface portion of another polymer slide.

  多个聚合物载玻片，每个载玻片都有一个聚合物部分，第一聚合物表面部分没有涂层，第二表面部分涂有金属。第一和第二表面部分各自具有不同的表面涂层特性，并具有各自不同的第一和第二疏水性。疏水小分子位于每个聚合物载玻片的聚合物部分，疏水小分子和聚合物之间基本上是惰性的。相邻聚合物载玻片的排列方式是，一个载玻片的第一聚合物表面朝向另一个载玻片的第二表面金属涂层部分。疏水小分子从一个聚合物载玻片的聚合物部分的第一聚合物表面蒸发到相邻的另一个聚合物载玻片的涂有金属的第二表面部分上。