1-己基-3-甲基咪唑十二烷基硫酸盐 | 1005759-57-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 中文名称: 1-己基-3-甲基咪唑十二烷基硫酸盐
• 英文名称: 1-hexyl-3-methylimidazolium dodecylsulfate
• 英文别名: Dodecyl sulfate;1-hexyl-3-methylimidazol-3-ium；dodecyl sulfate;1-hexyl-3-methylimidazol-3-ium
• CAS: 1005759-57-8
• 化学式: C₁₀H₁₉N₂*C₁₂H₂₅O₄S
• 分子量: 432.668
• InChiKey: NDJMDYNYRKNTFV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.28
• 重原子数：
  29
• 可旋转键数：
  16
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  83.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  溴己烷 以 水 为溶剂， 反应 7.0h， 生成 1-己基-3-甲基咪唑十二烷基硫酸盐
  参考文献：
  名称：

  Aqueous-Biamphiphilic Ionic Liquid Systems: Self-Assembly and Synthesis of Gold Nanocrystals/Microplates

  摘要：

  Biamphiphilic ionic liquids (BAILs) based on 1,3-dialkylimidazolium cation and alkyl sulfate anions ([C(n)H(2n+1)mim][CmH2m+1OSO3]; n = 4, 6, or 8; m = 8, 12) have been synthesized and characterized for their self-assembling behavior in the aqueous medium. Effects of alteration of alkyl chain length in cation and anion on surfactant properties of BAILs have been examined from surface tension measurements. The effectiveness of surface tension reduction for BAILs has been found to be exceptionally higher as compared to single chain surface active ILs/conventional surfactants. The thermodynamics of the aggregation process has been studied using isothermal titration calorimetry (ITC) and temperature dependent conductivity experiments. Dynamic light scattering (DLS), nuclear magnetic resonance (NMR), and transmission electron microscopy (TEM) studies showed that BAILs formed distinct aggregated structures depending upon the amphiphilic character present in the cation and anion. BAILs ([C(n)H(2n+1)mim][CmH2m+1OSO3]) form micelles when n = 4, 6; m = 8, intermicellar aggregates when n = 4, 6; m = 12, and vesicles when n = 8; m = 8, 12. Gold nanoparticles and microplates have been synthesized in micellar and vesicle solutions of BAILs using a simple photoreduction method. The studies show the potential of BAILs for constructing micelles and supramolecular assemblies, such as bilayer vesicles, which are effective in preparation of nanomaterials of controlled size and morphology.

  DOI：

  10.1021/jp309717n

文献信息

• Complexation, dimerisation and solubilisation of methylene blue in the presence of biamphiphilic ionic liquids: a detailed spectroscopic and electrochemical study
  作者：Reshu Sanan、Tejwant Singh Kang、Rakesh Kumar Mahajan

  DOI：10.1039/c3cp54030h

  日期：——

  concentration as well as the nature of BAILs. Different interactional phenomena such as the formation of ion-pair complexes, dimers, and solubilisation of monomers of MB have been observed in different concentration regimes of BAILs. A quantitative evaluation of the process of interaction between MB and BAILs has been made in terms of various micellar and binding parameters exploiting UV-visible absorption

  氧化还原活性染料亚甲基蓝（MB）与表面活性双亲性离子液体（BAIL）的相互作用：1-丁基-3-甲基咪唑十二烷基硫酸盐，[C 4 mim] [C 12 OSO 3 ]和1-己基-3-甲基咪唑十二烷基硫酸盐[C 6 mim] [C 12 OSO 3]已经在水性介质中进行了研究，以探索表面活性剂离子液体（ILs）在染料-表面活性剂化学领域的候选资格。各种热力学，光谱学和电化学技术，例如电导率，稳态荧光，紫外可见吸收和循环伏安法（CV）已用于获得有关MB-BAIL相互作用的全面信息。可以看到MB的存在会增强BAIL的临界胶束浓度（cmc）。MB和BAIL之间的相互作用程度随BAIL的浓度和性质而变化。在不同的BAIL浓度方案中，已观察到不同的相互作用现象，例如离子对络合物的形成，二聚体和MB单体的增溶。已经通过利用紫外可见吸收和CV测量对各种胶束和结合参数进行了MB和BAIL相互作用过程的定量评估。疏水性相对较高[C6个MIM]
• Aggregation Behavior of Mixed Micellar System of Dodecyl Sulfate‐Based Surface‐Active Ionic Liquids and Anionic Surfactant in Aqueous Media
  作者：Harsh Kumar、Gagandeep Kaur

  DOI：10.1002/jsde.12486

  日期：2021.3

  micellization behavior of dodecyl sulfate‐based ionic liquids, i.e., 1‐propyl‐3‐methylimidazolium dodecyl sulfate [C3mim][DS] and 1‐hexyl‐3‐methylimidazolium dodecyl sulfate [C6mim][DS] with sodium dodecyl sulfate (SDS), is investigated at (298.15, 308.15, and 318.15) K in aqueous medium. For this, the conductometric measurements are carried out to evaluate the critical micelle concentrations (cmc), ideal

  十二烷基硫酸盐基离子液体的混合胶束化行为，即1-丙基-3-甲基咪唑十二烷基硫酸盐[C 3 mim] [DS]和1-己基-3-甲基咪唑十二烷基硫酸盐[C 6 mim] [DS]与钠的混合胶束化行为在水性介质中以（298.15、308.15和318.15）K研究十二烷基硫酸盐（SDS）。为此，进行电导测量以评估临界胶束浓度（CMC），理想临界胶束浓度（CMC *），抗衡离子解离度（g），热力学参数，离子液体的胶束摩尔分数和相互作用参数（β）基于文献中提出的不同建议模型的混合系统。进一步的表面张力测量已进行了确认的值CMC获得通过对所有研究的系统的电导率研究298.15 K.其他表面的参数，如在表面张力的CMC（γ CMC），表面压力（ᴨ CMC），表面过量（Γ最大），和每分子最小面积（A分钟），也已被评估两个系统。
• Further investigation of the biodegradability of imidazolium ionic liquids
  作者：Jitendra R. Harjani、Jeff Farrell、M. Teresa Garcia、Robert D. Singer、Peter J. Scammells

  DOI：10.1039/b900787c

  日期：——

  In continuation of our earlier investigations, this report presents a rationale behind the design of a series of imidazolium based ionic liquids and their biodegradation using the CO2 headspace test (ISO 14593 method, OECD 310). The effect on biodegradability of these salts through variation of the N-substituted side chains of imidazolium ions was examined further through incorporation of various functional groups and increased alkyl chain lengths. A series of anions containing moieties known to be biodegradable were also incorporated into a number of imidazolium based salts and examined in a similar fashion.

  本报告延续了我们之前的研究，介绍了一系列咪唑离子液体的设计原理，以及使用二氧化碳顶空试验（ISO 14593 方法，OECD 310）对其进行生物降解的情况。通过加入各种官能团和增加烷基链长度，进一步研究了咪唑离子 N 取代侧链的变化对这些盐类生物降解性的影响。一系列含有已知可生物降解分子的阴离子也被加入到一些咪唑盐中，并以类似的方式进行了研究。
• Ionic liquids
  申请人：——

  公开号：US20040262578A1

  公开（公告）日：2004-12-30

  This invention relates to novel ionic liquids with the general formula [cation] [R′—SO 4 ] in which R′ is a branched or linear, saturated or unsaturated, aliphatic or alicyclic functionalized or non-functionalized hydrocarbon chain with 3-36 carbon atoms. These novel ionic liquids can be used e.g. as solvents or solvent additives in chemical reactions, as extraction agents or as heat carriers.

  本发明涉及一种新型离子液体，其通式为[阳离子] [R′—SO4]，其中R′是具有3-36个碳原子的分支或线性、饱和或不饱和、脂肪族或环烷基的功能化或非功能化烃链。这些新型离子液体可以用作化学反应中的溶剂或溶剂添加剂、提取剂或热载体等。
• Ionic Liquids
  申请人：Wasserscheid Peter

  公开号：US20080033178A1

  公开（公告）日：2008-02-07

  Low melting ionic compounds of the general formula (cation) (R′SO 4 ) in which R′ is a branched or linear, saturated or unsaturated, aliphatic or alicyclic functionalized or non-functionalized hydrocarbon chain with 3-36 carbon atoms are provided. These compounds can serve as ionic liquids, e.g. as solvents or solvent additives in chemical reactions, as extraction agents or as heat carriers. The compounds comprise a cation and anionic sulfate ester.

  提供了一般公式为（阳离子）（R′SO4）的低熔点离子化合物，其中R′是具有3-36个碳原子的支链或线性、饱和或不饱和、脂肪族或脂环族的功能化或非功能化碳氢链。这些化合物可以作为离子液体，例如作为化学反应中的溶剂或溶剂添加剂、萃取剂或热载体。这些化合物包括一个阳离子和阴离子硫酸酯。