1-氯-2-[2-氯-1-(4-氯苯基)乙基]苯 | 13312-58-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-氯-2-[2-氯-1-(4-氯苯基)乙基]苯
• 英文名称: 1-chloro-2-(2-chlorophenyl)-2-(4-chlorophenyl)ethane
• 英文别名: 1-Chlor-2-<2-chlorphenyl>-2-<4-chlorphenyl>-aethan；Benzene, 1-chloro-2-(2-chloro-1-(4-chlorophenyl)ethyl)-；1-chloro-2-[2-chloro-1-(4-chlorophenyl)ethyl]benzene
• CAS: 13312-58-8
• 化学式: C₁₄H₁₁Cl₃
• 分子量: 285.6
• InChiKey: NZTOLWBXRJOJED-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2903999090

反应信息

• 作为反应物：
  描述：

  1-氯-2-[2-氯-1-(4-氯苯基)乙基]苯 、 sodium ethanolate 以91%的产率得到
  参考文献：
  名称：

  BALON, YA. G.;SHULMAN, M. D., YKP. XIM. ZH., 57,(1991) N, S. 191-195

  摘要：

  DOI：
• 作为产物：
  描述：

  2,4'-二氯二苯甲酮 在 吡啶 、 lithium aluminium tetrahydride 、 氯化亚砜 作用下， 生成 1-氯-2-[2-氯-1-(4-氯苯基)乙基]苯
  参考文献：
  名称：

  1,1-Dichloro-2-(o-chlorophenyl)-2-(p-chlorophenyl)ethane and Related Compounds¹

  摘要：

  DOI：

  10.1021/jo01059a110

文献信息

• Rh(<scp>iii</scp>)-Catalysed solvent-free hydrodehalogenation of alkyl halides by tertiary silanes
  作者：N. Almenara、S. Azpeitia、M. A. Garralda、M. A. Huertos

  DOI：10.1039/c8dt03703e

  日期：——

  Efficient catalytic reduction of CDCl3 and other alkyl halides, including persistent organic pollutants, by different tertiary silanes using the unsaturated silyl-hydrido-Rh(III) complex Rh(H)[SiMe2(o-C6H4SMe)](PPh3)2}[BArF4] as a pre-catalyst is accomplished. The reactions are performed in a solvent-free manner. On account of experimental evidence, a simplified catalytic cycle is suggested for the

  使用不饱和甲硅烷基-氢化物-Rh（III）配合物Rh（H）[SiMe 2（o -C 6 H 4 SMe）] ，通过不同的叔硅烷有效催化还原CDCl 3和其他烷基卤，包括持久性有机污染物。完成了作为预催化剂的（PPh 3）2 } [BAr F 4 ]。反应以无溶剂的方式进行。由于实验证据，建议简化的催化循环用于CDCl 3的加氢脱卤。
• Isomer-selective and enantiomer-selective determination of DDT and related compounds using chiral high-resolution gas chromatography/mass spectrometry and chiral HPLC.
  作者：Hans-Rudolf. Buser、Markus D. Mueller

  DOI：10.1021/ac00111a030

  日期：1995.8.1

  The composition of technical DDT was investigated using achiral and chiral high-resolution gas chromatography (HRGC) and electron-ionization mass spectrometry (EI-MS), 2,4'-DDT and 2,4'-DDD, two important components of technical DDT, were enantiomerically resolved by chiral HRGC with silylated beta-cyclodextrin and by chiral highperformance chromatography (HPLC) with permethylated gamma-cyclodextrin as chiral selectors, The (+)- and (-)-enantiomers were assigned by chiral HPLC using chiroptical measurements, Enantiopure isolates were then used to identify these enantiomers in chiral HRGC analyses, Previous data indicated (+)- and (-)-2,4'-DDT to have S- and R-configuration, respectively, brat the absolute configurations for (+)- and (-)-2,4'-DDD were hitherto unknown, They were now assigned via the reductive dechlorination of the individual 2,4'-DDT enantiomers which proceeded stereoselectively to the corresponding 2,4'-DDD enantiomers, The results showed (+)- and (-)-2,4'-DDD to have R- and S-configuration, respectively, The enantiomers of 2,4'-DDD thus have reversed signs of rotation for polarized light compared to the enantiomers of 2,4'-DDT with the same configuration, The enantiomer resolution of several additional chiral compounds in technical DDT is reported; enantiomeric ratios of approximate to 1.0 indicated all chiral compounds to be present as racemates in the technical and in the synthetic reference materials, We report the first enantioselective determinations of technical DDT; the methods presented should also be applicable to the analysis of environmental and biological samples.
• 1,1-Dichloro-2-(o-chlorophenyl)-2-(p-chlorophenyl)ethane and Related Compounds¹
  作者：Takeshi Inoi、Peter Gericke、W. J. Horton

  DOI：10.1021/jo01059a110

  日期：1962.12
• BALON, YA. G.;SHULMAN, M. D., YKP. XIM. ZH., 57,(1991) N, S. 191-195
  作者：BALON, YA. G.、SHULMAN, M. D.

  DOI：——

  日期：——