1-甲基-4-[2-(4-甲基苯氧基)乙氧基]苯 | 15149-11-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 1-甲基-4-[2-(4-甲基苯氧基)乙氧基]苯
• 英文名称: 1,1'-[ethane-1,2-diylbis(oxy)]bis(4-methylbenzene)
• 英文别名: 1,2-bis(4-methylphenoxy)ethane；1,2-bis(p-methylphenoxy)ethane；1,2-bis-p-tolyloxy-ethane；1,2-Bis-p-tolyloxy-aethan；1.2-Di-p-tolyloxy-aethan；α.β-Di-p-kresoxy-aethan；1-Methyl-4-[2-(4-methylphenoxy)ethoxy]benzene
• CAS: 15149-11-8
• 化学式: C₁₆H₁₈O₂
• 分子量: 242.318
• InChiKey: UIFAEJQCFLEWCF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-甲基-4-[2-(4-甲基苯氧基)乙氧基]苯 在 N-溴代丁二酰亚胺(NBS) 、 过氧化苯甲酰 作用下， 以 四氯化碳 、 乙腈 为溶剂， 反应 72.35h， 生成
  参考文献：
  名称：

  1,1'-（（（乙烷-1,2-二基双（氧））双（4,1-亚苯基））双（亚甲基））双吡啶和溴化双喹啉衍生物的1 H和13 C NMR光谱分配。

  摘要：

  DOI：

  10.1002/mrc.4468
• 作为产物：
  描述：

  1-(2-溴乙氧基)-4-甲基苯 在 potassium cyanide 、 乙醇 、 水 作用下， 生成 1-甲基-4-[2-(4-甲基苯氧基)乙氧基]苯
  参考文献：
  名称：

  Schreiber, Chemische Berichte, 1891, vol. 24, p. 190

  摘要：

  DOI：

文献信息

• BASE GENERATOR
  申请人：Eternal Chemical Co., Ltd.

  公开号：US20130172569A1

  公开（公告）日：2013-07-04

  The present invention provides a base generator having the structure of formula (1): wherein R 1 , R 2 , R 3 , R 4 , R 5 , and Y circle around (−)} are defined as in the specification. The base generator of the present invention can be used for imidization of a polyimide precursor, promoting crosslinking of epoxy monomers, or crosslinking of polyurethane or polyurea.

  本发明提供了一种具有公式（1）结构的碱发生器： 其中R1、R2、R3、R4、R5和Ycircle around (−)}如说明书中所定义。本发明的碱发生器可用于聚酰亚胺前体的酰亚胺化，促进环氧单体交联，或聚氨酯或聚脲的交联。
• RECORDING MATERIAL PRODUCED USING NON-PHENOL COMPOUND
  申请人：NIPPON SODA CO., LTD.

  公开号：US20150284321A1

  公开（公告）日：2015-10-08

  An object of the present invention is to provide a recording material or a recording sheet using, as a color-developing agent, a non-phenol compound that is a safe compound in no danger of corresponding to an endocrine disruptor and is good in color developing performance. The non-phenol compound used in the present invention is at least one selected from the group consisting of compounds represented by the following formulas (I) to (III).

  本发明的目的是提供一种使用非酚类化合物作为显色剂的记录材料或记录纸，该非酚类化合物是一种安全化合物，不会对应到内分泌干扰物，并且在显色性能方面表现良好。本发明中使用的非酚类化合物至少选自以下化合物所代表的化合物组，其化学式为(I)至(III)。
• Thermosensitive recording material and color developer compound therefor
  申请人：——

  公开号：US20040071187A1

  公开（公告）日：2004-04-15

  A thermosensitive recording material has a support and a thermosensitive coloring layer formed thereon containing a leuco dye and a color developer capable of inducing color formation in the leuco dye upon application of heat thereto, with the color developer including at least one compound (A) having in a molecule thereof at least two aromatic ring moieties with specific structures, selected from the group consisting of an aromatic ring moiety having at least one carboxyl group and electron-attracting functional group, an aromatic ring moiety having at least one carboxyl group and electron-donating functional group, and an aromatic ring moiety having at least one carboxyl group, free of the electron-attracting and electron-donating functional groups. An aromatic carboxylic acid compound serving as the above-mentioned compound (A) and the producing method thereof are also disclosed.

  一种热敏感记录材料具有支撑体和在其上形成的热敏感着色层，其中该着色层含有一种白色染料和一种色素显色剂，能够在施加热量时诱导白色染料发生显色反应，其中色素显色剂包括至少一种化合物（A），其分子中至少含有两个具有特定结构的芳香环基团，所述芳香环基团选自具有至少一个羧基和电子吸引基团的芳香环基团、具有至少一个羧基和电子给予基团的芳香环基团以及不含电子吸引和电子给予功能基团的芳香环基团。还公开了作为上述化合物（A）的芳香羧酸化合物及其生产方法。
• RECORDING MATERIAL COMPRISING DIPHENYL SULFONE DERIVATIVE AND NOVEL DIPHENYL SULFONE DERIVATIVE COMPOUND
  申请人：NIPPON SODA CO., LTD.

  公开号：EP1557408A1

  公开（公告）日：2005-07-27

  The present invention provides a recording material which has excellent background stability, specifically heat resistance and heat and humidity resistance of the background. The recording material containing a color forming dye is characterized by containing at least one kind of diphenylsulfone derivative represented by the general formula (I): (wherein R1 and R2 each represents a hydrogen atom or a C1 to C6 alkyl group, n represents an integer of 1 to 6, R3 and R4 each represents a halogen atom, a C1 to C6 alkyl group, etc., p and q each represents an integer of 0 to 4, X represents OR5 or NR6R7 wherein R5 represents a C1 to C6 alkyl group, a C1 to C6 hydroxyalkyl group, or a C1 to C6 alkoxy-C1 to C6 alkyl group, and R6 and R7 each represents a hydrogen atom, a C1 to C6 alkyl group, etc).

  本发明提供了一种具有优异背景稳定性的记录材料，特别是具有优异的耐热性和耐热潮湿性的背景。含有一种颜色形成染料的记录材料的特征在于其至少含有一种由通式（I）表示的二苯砜衍生物：（其中R1和R2分别表示氢原子或C1至C6烷基，n表示1至6的整数，R3和R4分别表示卤素原子、C1至C6烷基等，p和q分别表示0至4的整数，X表示OR5或NR6R7，其中R5表示C1至C6烷基、C1至C6羟基烷基或C1至C6烷氧基-C1至C6烷基，R6和R7分别表示氢原子、C1至C6烷基等）。
• Modifier compounds
  申请人：Appleton Papers Inc.

  公开号：US20020007091A1

  公开（公告）日：2002-01-17

  The present invention is a novel class of compounds useful in useful in thermally-responsive record material of the type comprising a substrate having provided thereon in substantially contiguous relationship an electron donating dye precursor, and an acidic developer material. The novel compound of the invention is a compound of the formula 1 wherein P is selected from 2 wherein R 1 , is selected from hydrogen, alkoxy, and aralkoxy; wherein R 2 is aralkoxyalkoxy when P is phenyl, and R 2 is selected from aralkoxyalkoxy or alkoxyalkoxy when P is naphthyl. Said alkyl moieties are each independently from one to eight carbons, said aryl moieties each independently being unsubstituted or substituted by alkyl (C 1 -C 8 ), alkoxy (C 1 -C 8 ) or halogen. The compounds of the invention enable manufacture of thermally responsive record material of the invention having the unexpected and remarkable properties of enhanced image intensity or density, and/or improved thermal response. The compounds of the invention also find use in diverse applications such as emolients and softening agents for creams, lots and cosmetics.

  本发明是一种新型化合物类，适用于热响应记录材料，该材料包括基底，在基底上具有电子给体染料前体和酸性显影剂，二者之间呈现出相互接触的关系。本发明的新型化合物是式1的化合物，其中P选自式2，式2中R1选自氢、烷氧基和芳基烷氧基；当P为苯基时，R2为芳基烷氧基烷氧基；当P为萘基时，R2选自芳基烷氧基烷氧基或烷氧基烷氧基。所述烷基基团独立地为1-8个碳，所述芳基基团独立地未被取代或被烷基（C1-C8）、烷氧基（C1-C8）或卤素取代。本发明的化合物使得制造热响应记录材料具有出乎意料和显著的增强图像强度或密度和/或改善热响应的特性。本发明的化合物还可用于各种应用，如润肤剂和柔软剂等化妆品。