1-甲基-5-苯基-3-丙基-1,2,4-三唑 | 915303-66-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 中文名称: 1-甲基-5-苯基-3-丙基-1,2,4-三唑
• 英文名称: 5-phenyl-1-methyl-3-n-propyl-1H-1,2,4-triazole
• 英文别名: 1-Methyl-5-phenyl-3-propyl-1H-1,2,4-triazole；1-methyl-5-phenyl-3-propyl-1,2,4-triazole
• CAS: 915303-66-1
• 化学式: C₁₂H₁₅N₃
• 分子量: 201.271
• InChiKey: LWGTWWGANHDJRJ-UHFFFAOYSA-N

物化性质

• 沸点：
  363.7±25.0 °C(Predicted)
• 密度：
  1.07±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  30.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-甲基-5-苯基-3-丙基-1,2,4-三唑 在 正丁基锂 、 zinc(II) chloride 作用下， 以 乙醚 、 二氯甲烷 、 正戊烷 为溶剂， 反应 1.5h， 生成
  参考文献：
  名称：

  Method of forming metal complex compound, and organic electroluminescence device

  摘要：

  提供形成发光有机金属配合物的方法，确保在有机电致发光器件中使用时具有高耐久性。例如，根据以下反应方案制备化合物106。

  公开号：

  US09062084B2
• 作为产物：
  描述：

  苯甲酰氯 在 三乙胺 作用下， 以 氯仿 、 水 为溶剂， 反应 30.0h， 生成 1-甲基-5-苯基-3-丙基-1,2,4-三唑
  参考文献：
  名称：

  JP6134566

  摘要：

  公开号：

文献信息

• Effect of co-ligand number on the optoelectronic properties of first- and second-generation heteroleptic green emissive iridium(iii) complex-cored dendrimers
  作者：Manikandan Koodalingam、Junhyuk Jang、Mile Gao、Paul L. Burn、Jos C. M. Kistemaker、Emma V. Puttock、Paul E. Shaw

  DOI：10.1039/d4tc02336f

  日期：——

  light-emitting dendrimers with heteroleptic or homoleptic iridium(III) complexes at the core, with one, two, or three first- or second-generation biphenyl-based dendrons attached to the 2-phenylpyridyl ligand that is involved in the emission of light. The 5-phenyl-1-methyl-3-n-propyl-1H-1,2,4-triazole co-ligand was not dendronised and was not involved in the emission process. The dendrimers with two emissive

  我们报告了以杂配或均配铱(III)络合物为核心的发光树枝状聚合物的开发，其中一个、两个或三个第一或第二代联苯树枝状大分子连接到2-苯基吡啶基配体上，该配体参与光的发射。 5-苯基-1-甲基-3-正丙基-1H-1,2,4-三唑共配体未树枝化并且不参与发射过程。发现具有两个发射配体的树枝状聚合物具有最高的溶液光致发光量子产率 (PLQY)，其大于 90%，与树枝状聚合物的生成无关。由于树枝状分子和表面基团对发射核心的屏蔽增强，第二代树枝状聚合物均比第一代树枝状聚合物具有更高的纯膜 PLQY。由纯薄膜和第二代树枝状聚合物与两个发射配体的客体：主体混合物制成的器件的最大外部量子效率最高（分别为 7.5% 和 15.8%），这归因于平衡电荷传输所需的相互作用与最小化导致非辐射过程的相互作用之间的关系。因此，我们已经证明，将树枝状聚合物的生成和发射树枝状配体的数量相结合是优化发光树枝状聚合物OLED性能的可行策略。
• METHOD OF FORMING METAL COMPLEX COMPOUND, AND ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：FUKUZAKI Eiji

  公开号：US20110050093A1

  公开（公告）日：2011-03-03

  To provide methods of forming fluorescence-producing organometallic complexes which can ensure high durability when used in organic electroluminescence devices. For example, a compound 106 is prepared in accordance with the following reaction scheme.
• METAL COMPLEX AND LIGHT-EMITTING DEVICE CONTAINING THE METAL COMPLEX
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20140374727A1

  公开（公告）日：2014-12-25

  A highly stable metal complex useful for the manufacture of a light-emitting device has an excellent lifetime property, particularly in a blue region, specifically a metal complex represented by Formula (1): wherein M is a metal atom; each R 0 independently represents a divalent linking group; i and j each independently represent 0 or 1; R P1 , R P2 , R P3 , R P4 , R P5 and R P6 resent each independently rep a hydrogen atom and the like, with a proviso that at least one of R P1 , R P2 , R P3 , R P4 , R P5 and R P6 is a dendron; m is an integer of from 1 to 3, n is an integer of from 0 to 2, and m+n is 2 or 3; and the portion represented by Formula (2): represents a bidentate ligand; wherein R x and R y are an atom bonding to the metal atom M, and each independently represents a carbon atom and the like.
• Method Of Forming Metal Complex Compound, And Organic Electroluminescence Device
  申请人：UDC IRELAND LIMITED

  公开号：US20150311455A1

  公开（公告）日：2015-10-29

  To provide methods of forming fluorescence-producing organometallic complexes which can ensure high durability when used in organic electroluminescence devices. For example, a compound 106 is prepared in accordance with the following reaction scheme.
• COMPOSITION AND LIGHT EMITTING DEVICE USING THE SAME
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20160164008A1

  公开（公告）日：2016-06-09

  A composition is provided containing a first phosphorescent compound (DB) having an emission spectrum whose maximum peak wavelength is from 400 nm to less than 480 nm and having a dendron and a second phosphorescent compound (DGR) having an emission spectrum whose maximum peak wavelength is from 480 nm to less than 680 nm and having a dendron.