2,3-环氧丙基甲酸酯 | 73376-04-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2,3-环氧丙基甲酸酯
• 英文名称: 2,3-epoxypropyl formate
• 英文别名: formic acid-(2,3-epoxy-propyl ester)；Ameisensaeure-(2,3-epoxy-propylester)；glycidyl formate；2-Oxiranylmethyl formate；oxiran-2-ylmethyl formate
• CAS: 73376-04-2
• 化学式: C₄H₆O₃
• 分子量: 102.09
• InChiKey: CIXFJOIWHPRYJT-UHFFFAOYSA-N

物化性质

• 沸点：
  63-64 °C(Press: 22 Torr)
• 密度：
  1.193±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  7
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  38.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,3-环氧丙基甲酸酯 、 溶剂黄146 生成 Acetic acid 2-formyloxy-1-hydroxymethyl-ethyl ester
  参考文献：
  名称：

  摘要：

  The formation of epoxy derivatives as intermediate products in the oxidation of allyl alcohol, ally] formate, and allyl acetate in acetic acid was proved. Intermediate epoxy compounds undergo further transformations: They react with acetic acid to give glycerol esters or are converted into polyethers of glycerol and its esters. The rate constants for transformations of 2,3-epoxypropanol, 2,3-epoxypropyl formate, and 2,3-epoxypropyl acetate along these pathways were measured. Higher selectivity of glycerol ester formation from allyl formate was substantiated.

  DOI：

  10.1023/a:1019694502327
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 乙醚 、 sodium hydride 作用下， 生成 2,3-环氧丙基甲酸酯
  参考文献：
  名称：

  N-oxyalkyl-p-aminobenzoyl glutamates

  摘要：

  公开号：

  US02629734A1

文献信息

• Olefin epoxidation with .alpha.-substituted hydroperoxides
  作者：J. Rebek、R. McCready

  DOI：10.1021/ja00537a033

  日期：1980.8
• REBEK J. JR.; MCCREADY R., J. AMER. CHEM. SOC., 1980, NO 17, 5602-5605
  作者：REBEK J. JR.、 MCCREADY R.

  DOI：——

  日期：——
• N-oxyalkyl-p-aminobenzoyl glutamates
  申请人：UPJOHN CO

  公开号：US02629734A1

  公开（公告）日：1953-02-24
• ——
  作者：E. V. Fedevich

  DOI：10.1023/a:1019694502327

  日期：——

  The formation of epoxy derivatives as intermediate products in the oxidation of allyl alcohol, ally] formate, and allyl acetate in acetic acid was proved. Intermediate epoxy compounds undergo further transformations: They react with acetic acid to give glycerol esters or are converted into polyethers of glycerol and its esters. The rate constants for transformations of 2,3-epoxypropanol, 2,3-epoxypropyl formate, and 2,3-epoxypropyl acetate along these pathways were measured. Higher selectivity of glycerol ester formation from allyl formate was substantiated.