2,4,6-三溴苯硫酚 | 57730-98-0

• 物质功能分类: 化学试剂 - 有机试剂 - 硫醇/硫酚
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯硫酚类
• 中文名称: 2,4,6-三溴苯硫酚
• 中文别名: 邻磺酰胺苯甲酸甲酯；2-甲酸甲酯苯磺酰胺；甲磺胺；邻甲酸甲酯苯磺酰胺
• 英文名称: 2,4,6-tribromobenzenethiol
• 英文别名: 2,4,6-tribromo-thiophenol；2.4.6-Tribrom-1-mercapto-benzol；2.4.6-Tribrom-phenylmercaptan；2,4,6-Tribrom-thiophenol；2,4,6-tribromo benzenethiol；2,4,6-Tribromthiophenol；2,4,6-Tribromothiophenol
• CAS: 57730-98-0
• 化学式: C₆H₃Br₃S
• 分子量: 346.868
• InChiKey: CSGWTASASRPRAX-UHFFFAOYSA-N

物化性质

• 熔点：
  115.5-115.9 °C
• 沸点：
  328.8±42.0 °C(Predicted)
• 密度：
  2.303±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,4,6-三溴苯硫酚 在 air 作用下， 生成 1,2-bis(2,4,6-tribromophenyl)disulfane
  参考文献：
  名称：

  Management of the Guarani Aquifer System

  摘要：

  With an extension of 1.2 million square kilometers, the Guarani Aquifer System is one of the largest transboundary groundwater systems in the world. It underlies parts of Argentina, Brazil, Paraguay, and Uruguay and was only relatively recently recognized as a transboundary resource. The four countries are now in the process of starting up a project to elaborate and implement a common institutional and technical framework for managing and preserving the Guarani Aquifer System for current and future generations. This paper briefly presents the Guarani Aquifer System Project. The preparation process is described due to its particular interest for other similar multi-country endeavors. Following the presentation of the project, the paper takes a forward-looking approach and analyzes the applicability of current international law for transboundary groundwater resources in the context Of the Guarani Aquifer System. It concludes that while the basic principles espoused by international law relating to transboundary groundwater resources management are valid, they do not provide very specific guidance. The Guarani Aquifer System is unique and its complex features make it an eclectic case, which already is obliging all stakeholders to work out innovative measures - in the legal, institutional, technical, scientific, social, and economic realms - to develop appropriate activities for its sustainable management.

  DOI：

  10.1080/02508060308691684
• 作为产物：
  描述：

  dithiocarbonic acid S,S'-bis-(2,4,6-tribromo-phenyl ester) 在 氢氧化钾 作用下， 生成 2,4,6-三溴苯硫酚
  参考文献：
  名称：

  THE ACTION OF HALOGENS AND OF ALKYL HALIDES UPON THE SALTS OF TRIBROMOTHIOPHENOL¹

  摘要：

  DOI：

  10.1021/ja01345a034

文献信息

• 一种功能三胺单体及其制备方法和应用
  申请人：湖南工业大学

  公开号：CN108976138A

  公开（公告）日：2018-12-11

  本发明公开了一种功能三胺单体及其制备方法和用途。本发明从三或四取代苯环单体出发，经Suzuki反应一步反应或经Suzuki反应、还原反应两步反应制备功能三胺单体。本发明把常见的杂环或者苯环等刚性结构引入三胺单体，显著提高了单体的热稳定性，同时可显著提高由本发明提供的三胺单体制备的聚合物的热稳定性和机械性能，以及加工性能，还可以改善其在电及磁等方面的性能。本发明中涉及的功能三胺单体的制备方法工艺简单，纯化容易，因而适于工业生产。本发明的功能三胺单体可用于合成超支化和功能化聚酰胺、聚酰亚胺、聚酰胺酰亚胺和聚酯酰亚胺等聚合物。
• RESIN FOR LENS WITH HIGH REFRACTIVE INDEX AND LENS COMPOSED OF IT
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0112927A1

  公开（公告）日：1984-07-11

  A resin for lens with a high refractive index prepared by compolymerizing one or more benzenedicarboxylic acid esters substituted by halogen in the nucleus and represented by the formula (I), (wherein X represents CI or Br, n represents 2 or 4, m represents 0 or 1, and R represents H or methyl) with one or more monofunctional monomers having a refractive index of 1.55 or more as homopolymer and being radical-polymerizable, and lens composed of it are disclosed. This resin for preparing lens has a high refractive index and is excellent in workability (such as grindability) and impact resistance. In addition, the monofunctional monomer(s) and the bifunctional monomer(s) are well compatible with each other upon copolymerization, and polymerication distortion difficultly takes place.

  本发明公开了一种具有高折射率的镜片用树脂，其制备方法是将一种或多种核内被卤素取代且由式（I）表示的苯二甲酸酯（其中 X 代表 CI 或 Br，n 代表 2 或 4，m 代表 0 或 1，R 代表 H 或甲基）与一种或多种折射率为 1.55 或以上且可进行自由基聚合的单官能团单体进行均聚，并由其组成镜片。 这种镜片用树脂具有高折射率，且加工性（如研磨性）和抗冲击性优异。 此外，单官能团单体和双官能团单体在共聚时彼此相容性良好，不易发生聚合变形。
• Method for producing of polyarylene sulfides
  申请人：IDEMITSU PETROCHEMICAL CO. LTD.

  公开号：EP0215312A1

  公开（公告）日：1987-03-25

  Disclosed is a method for producing a polyarylene sulfide comprising contacting a dihalogenated aromatic compound with an alkali metal sulfide in a polar solvent, wherein a halogenated aromatic compound containing active hydrogen is present in the reaction system.

  本发明公开了一种生产聚芳基硫醚的方法，该方法包括在极性溶剂中将二卤代芳香族化合物与碱金属硫化物接触，其中反应体系中存在含有活性氢的卤代芳香族化合物。
• PYRIMIDINE DERIVATIVE, PRODUCTION THEREOF, AND ANDROGEN INHIBITOR
  申请人：OTSUKA PHARMACEUTICAL CO., LTD.

  公开号：EP0503099A1

  公开（公告）日：1992-09-16

  A pyrimidine derivative represented by general formula (I), a pharmaceutically acceptable salt thereof, and an androgen inhibitor comprising the same having an excellent effect of treating prostatic hyperplasia, female hypertrichosis, and male baldness or pimple: wherein R¹ represents hydrogen or hydroxyl; R² represents hydrogen, lower alkoxycarbonyl, lower alkoxy, halogen, lower alkyl, C₃ to C₈ cycloalkyl, lower alkoxycarbonyl lower alkyl, carboxyl, carboxylated lower alkyl, CONHR, cyano, phenyl, phenylated lower alkyl, lower alkanoyloxy lower alkyl, benzoyl, lower alkanoyl or hydroxylated lower alkyl; R³ represents hydrogen, hydroxy, lower alkyl, C₃ to C₈ cycloalkyl, halogenated lower alkyl or phenyl; R⁴ represents hydrogen, lower alkyl or lower alkoxy, R⁵ represents hydrogen, lower alkyl, lower alkoxy lower alkyl or halogenated lower alkyl.

  一种由通式(I)代表的嘧啶衍生物、其药学上可接受的盐，以及由其组成的雄激素抑制剂，具有治疗前列腺增生、女性多毛症、男性秃头或丘疹的良好效果：其中，R¹代表氢或羟基；R²代表氢、低级烷氧基羰基、低级烷氧基、卤素、低级烷基、C₃至C₈环烷基、低级烷氧基羰基低级烷基、羧基、羧化低级烷基、CONHR、氰基、苯基、苯基化低级烷基、低级烷酰氧基低级烷基、苯甲酰基、低级烷酰基或羟化低级烷基；R³ 代表氢、羟基、低级烷基、C₃至 C₈ 环烷基、卤代低级烷基或苯基；R⁴ 代表氢、低级烷基或低级烷氧基，R⁵ 代表氢、低级烷基、低级烷氧基低级烷基或卤代低级烷基。
• MONOMOLECULAR CONDUCTIVE COMPLEX, CONDUCTIVE SELF-ASSEMBLED FILM AND ASSEMBLY OF ELECTRODE COMPOSED OF METAL AND SEMICONDUCTOR MAKING USE OF THE SAME
  申请人：TOKYO INSTITUTE OF TECHNOLOGY

  公开号：EP1862453A1

  公开（公告）日：2007-12-05

  Enediyne compounds of the formula: (1) characterized in that the structure thereof is very simple and the production process is easy, and that the molecular length thereof is shorter than those of compounds having been proposed. Consequently, electrode assemblies comprising any of these enediyne compounds are highly promising in the application to nanomolecular wiring (nanomolecular wire) whose production has been difficult.

  式（1）的烯二炔化合物：(1)的烯二乙烯化合物，其特点是结构非常简单，生产工艺简单，分子长度比已提出的化合物短。因此，由这些烯二炔化合物组成的电极组件在应用于纳米分子布线（纳米分子线）方面具有很大的前景，而纳米分子线的生产一直很困难。