2-(2-羟基苯基)苯甲醛 | 67608-60-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2-(2-羟基苯基)苯甲醛
• 英文名称: 2-(2-hydroxyphenyl)benzaldehyde
• 英文别名: 2-hydroxy-2'-formylbiphenyl；2-(2-Formylphenyl)phenol
• CAS: 67608-60-0
• 化学式: C₁₃H₁₀O₂
• mdl: MFCD13873896
• 分子量: 198.221
• InChiKey: HVLZLVXOMJFVNF-UHFFFAOYSA-N

物化性质

• 沸点：
  367.0±25.0 °C(Predicted)
• 密度：
  1.202±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-(2-羟基苯基)苯甲醛 在 Jones’ reagent 作用下， 以 丙酮 为溶剂， 生成 苯并[c]苯并吡喃-6-酮
  参考文献：
  名称：

  The Suzuki-Miyaura cross coupling reactions on solid support. Link to solution phase directed ortho metalation. The Leznoff acetal linker approach to biaryl and heterobiaryl aldehydes

  摘要：

  The synthesis of the titled compounds by Suzuki-Miyaura cross coupling on Merrifield resin - Leznoff acetal - linked halo benzaldehydes followed by mild acid hydrolysis is reported; synthetic utility for heterocycles based on solution phase Directed ortho Metalation chemistry is demonstrated. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(98)00779-5
• 作为产物：
  描述：

  2,N,N,-diethylcarbamyloxyphenyl boronic acid 在 四(三苯基膦)钯 盐酸 、 lithium aluminium tetrahydride 、 sodium 、 sodium carbonate 、 Merrifield resin 作用下， 反应 96.0h， 生成 2-(2-羟基苯基)苯甲醛
  参考文献：
  名称：

  The Suzuki-Miyaura cross coupling reactions on solid support. Link to solution phase directed ortho metalation. The Leznoff acetal linker approach to biaryl and heterobiaryl aldehydes

  摘要：

  The synthesis of the titled compounds by Suzuki-Miyaura cross coupling on Merrifield resin - Leznoff acetal - linked halo benzaldehydes followed by mild acid hydrolysis is reported; synthetic utility for heterocycles based on solution phase Directed ortho Metalation chemistry is demonstrated. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(98)00779-5

文献信息

• Oxidation of Polycyclic Aromatic Hydrocarbons Catalyzed by Iron Tetrasulfophthalocyanine FePcS: Inverse Isotope Effects and Oxygen Labeling Studies
  作者：Alexander Sorokin、Bernard Meunier

  DOI：10.1002/(sici)1099-0682(199809)1998:9<1269::aid-ejic1269>3.0.co;2-g

  日期：1998.9

  Iron(III) tetrasulfophthalocyanine (FePcS) was shown to catalyze the oxidation of polycyclic aromatic hydrocarbons by H2O2. Benzo[a]pyrene and anthracene were converted to the corresponding quinones while biphenyl-2,2′-dicarboxylic acid was the main product of phenanthrene oxidation. The mechanism of the anthracene oxidation by H2O2 in the presence of FePcS or by KHSO5 with iron(III) meso-tetrakis(3

  铁 (III) 四磺基酞菁 (FePcS) 被证明可催化 H2O2 对多环芳烃的氧化。苯并[a]芘和蒽被转化为相应的醌，而联苯-2,2'-二羧酸是菲氧化的主要产物。在 FePcS 存在下 H2O2 或 KHSO5 与铁 (III) 内消旋四(3,5-二磺基)卟啉 (FeTMPS)（参见图 1 的催化剂结构）氧化蒽的机理已通过使用进行了详细研究动力学同位素效应 (KIE) 和 18O 标记研究。在 FePcS/H2O2 和 FeTMPS/KHSO5 竞争氧化 [H10] 蒽和 [D10] 蒽的底物消耗上测量的 KIE 基本相同，分别为 0.75 ± 0.02 和 0.76 ± 0.06。第一氧化步骤中的这些逆 KIE 可以通过将亲电氧杂铁络合物添加到蒽的 sp2 碳中心以形成 σ 加合物期间 sp2 到 sp3 的杂化变化来解释（这种逆 KIE 通过更强的堆积相互作用增强与大环催化剂之间的氘
• CYCLIC COMPOUND, PRODUCTION PROCESS THEREOF, RADIATION-SENSITIVE COMPOSITION AND RESIST PATTERN FORMATION METHOD
  申请人：Takasuka Masaaki

  公开号：US20120282546A1

  公开（公告）日：2012-11-08

  Disclosed are: a cyclic compound which has high solubility in a safe solvent, is highly sensitive, enables the formation of a resist pattern having a good shape, and rarely causes resist pattern collapse; a process for producing the cyclic compound; a radiation-sensitive composition containing the cyclic compound; and a resist pattern formation method using the composition. Specifically disclosed are: a cyclic compound having a specific structure; a process for producing the cyclic compound; a radiation-sensitive composition containing the compound; and a resist pattern formation method using the composition.

  本发明涉及一种具有高溶解度、高灵敏度、能够形成良好形状的抗蚀图案，且很少引起抗蚀图案崩塌的环状化合物；一种制备该环状化合物的方法；一种含有该环状化合物的辐射敏感组合物；以及使用该组合物的抗蚀图案形成方法。具体揭示了一种具有特定结构的环状化合物，制备该环状化合物的方法，含有该化合物的辐射敏感组合物以及使用该组合物的抗蚀图案形成方法。
• CYCLIC COMPOUND, PROCESS FOR PRODUCTION THEREOF, RADIATION-SENSITIVE COMPOSITION, AND RESIST PATTERN FORMATION METHOD
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP2505576B1

  公开（公告）日：2019-04-24
• SOLLAZZO, G.;TONANI, R.;TRALDI, P., ORG. MASS SPECTROM., 23,(1988) N 7, C. 550-552
  作者：SOLLAZZO, G.、TONANI, R.、TRALDI, P.

  DOI：——

  日期：——
• AMBIENT TEMPERATURE LIQUID-FORM ORGANIC MATERIALS AND USE THEREOF
  申请人：Nakanishi Takashi

  公开号：US20130234125A1

  公开（公告）日：2013-09-12

  An organic material consisting of a π-conjugated molecule which is in a liquid form at ambient temperature and use thereof are provided. The ambient temperature liquid-form organic material according to the present invention consists of a π-conjugated molecule having 2 or more side chains, the 2 or more side chains are same or different side chains selected from the group consisting of a branched alkyl chain, an alkyl chain having a polymerization site at a terminal, an oligosiloxane chain, a fluorocarbon chain, an oligoethylene glycol chain and derivatives thereof, and each of the 2 or more side chains is bound directly or via a substituent to the π-conjugated molecule.