3-methylphenyl-3-(9-phenyl-9H-fluoren-9-yl)phenylamine | 1292285-22-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 3-methylphenyl-3-(9-phenyl-9H-fluoren-9-yl)phenylamine
• 英文别名: N-(3-methylphenyl)-3-(9-phenyl-9H-fluoren-9-yl)phenylamine；3-methyl-N-[3-(9-phenylfluoren-9-yl)phenyl]aniline
• CAS: 1292285-22-3
• 化学式: C₃₂H₂₅N
• 分子量: 423.557
• InChiKey: CSFUABKNUYKBTO-UHFFFAOYSA-N

物化性质

• 沸点：
  567.8±29.0 °C(Predicted)
• 密度：
  1.184±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  33
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  三叔丁基膦 、 3-methylphenyl-3-(9-phenyl-9H-fluoren-9-yl)phenylamine 在 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 作用下， 以 正己烷 、 甲苯 为溶剂， 生成 N,N'-bis(3-methylphenyl)-N,N'-bis[3-(9-phenyl-9H-fluoren-9-yl)phenyl]-pyrene-1,6-diamine
  参考文献：
  名称：

  Light-Emitting Element, Light-Emitting Device, Electronic Device, Lighting Device, and Pyrene-Based Compound

  摘要：

  提供了一种高效的发光元件，能够提供多种发射颜色，不易恶化，并且即使发光层具有堆叠结构，也可以最小化外部量子效率的降低。提供了低功耗和长寿命的发光器件、电子器件和照明装置。发光元件包括多个发光层，这些层在一对电极之间堆叠。发光层分别包含主体材料和客体材料。发光层的客体材料是具有不同HOMO水平但具有基本相同LUMO水平且发出不同颜色的光的物质。使用发光元件制造了发光器件、电子器件和照明装置。

  公开号：

  US20130087773A1
• 作为产物：
  描述：

  3-溴苯甲酮 在 盐酸 、 tris-(dibenzylideneacetone)dipalladium(0) 、 正丁基锂 、 三叔丁基膦 、 potassium tert-butylate 、 溶剂黄146 作用下， 以 四氢呋喃 、 2-甲基四氢呋喃 、 水 、 甲苯 为溶剂， 反应 31.0h， 生成 3-methylphenyl-3-(9-phenyl-9H-fluoren-9-yl)phenylamine
  参考文献：
  名称：

  一种新的可交联的9,10-二苯基蒽衍生物，可作为宽带隙基质用于溶液处理的有机发光二极管†

  摘要：

  使用多层架构可以获得高效的有机发光二极管（OLED），其中电荷注入，传输和重组的过程在每一层中都得到了分离和优化。从溶液中处理这些结构需要采取策略，以避免重新溶解或破坏先前沉积的层。几份报告证明了可交联的空穴传输材料的发展，而较少的文献描述了这种用于多层OLED的宽带隙基质材料的合成和应用。在这项工作中，我们介绍了一种9-（4-（10-苯基蒽-9-基）苯基）-9 H-咔唑的可交联衍生物，其中含有苯乙烯部分（SPhPC），可通过自由基聚合。我们介绍了SPhPC的合成和表征，以及它在发光层中作为基质的应用，以证明溶液处理的蓝色OLED的概念。

  DOI：

  10.1039/c8tc05013a

文献信息

• Organometallic Complex, Light-Emitting Element, Light-Emitting Device, Electronic Device and Lighting Device
  申请人：Inoue Hideko

  公开号：US20120098417A1

  公开（公告）日：2012-04-26

  Provided is a novel substance that can emit phosphorescence. Alternatively, provided is a novel substance with high emission efficiency. An organometallic complex in which a 4-arylpyrimidine derivative is a ligand and iridium is a central metal is provided. Specifically, an organometallic complex having a structure represented by a general formula (G1) is provided. In the general formula (G1), R 1 represents a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aryl group having 6 to 10 carbon atoms, R 2 represents any of hydrogen, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, and a substituted or unsubstituted phenyl group, R 3 represents hydrogen or a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, and Ar 1 represents a substituted or unsubstituted arylene group having 6 to 10 carbon atoms.

  提供了一种可以发射磷光的新型物质。或者，提供了一种具有高发射效率的新型物质。提供了一种有机金属配合物，其中4-芳基嘧啶衍生物是配体，镭是中心金属。具体地，提供了一种具有通用式（G1）表示的结构的有机金属配合物。在通用式（G1）中，R1代表具有1至4个碳原子的取代或未取代的烷基基团或具有6至10个碳原子的取代或未取代的芳基基团，R2代表氢、具有1至4个碳原子的取代或未取代的烷基基团，以及取代或未取代的苯基，R3代表氢或具有1至4个碳原子的取代或未取代的烷基基团，Ar1代表具有6至10个碳原子的取代或未取代的芳烃基团。
• Light-Emitting Device, Electronic Device, and Lighting Device Utilizing Phosphorescence
  申请人：Seo Satoshi

  公开号：US20120274201A1

  公开（公告）日：2012-11-01

  A new light-emitting device utilizing phosphorescence is provided. Further, an electronic device and a lighting device which utilize phosphorescence are provided. One embodiment of the present invention is a light-emitting device including a phosphorescent organometallic iridium complex comprising iridium and either pyrimidine having an aryl group at the 4-position or 1,3,5-triazine having an aryl group at the 2-position. One of nitrogen in the pyrimidine or 1,3,5-triazine is coordinated to the iridium. Also, each of the pyrimidine and 1,3,5-triazine has a substituent such as an alkyl group or an aryl group. Further the ortho position of the aryl group which is bonded to the 4-position of the pyrimidine or the 2-position of the 1,3,5-triazine is bonded to the iridium.

  提供了一种利用磷光的新型发光装置。此外，还提供了利用磷光的电子设备和照明设备。本发明的一个实施例是包括铱和在4-位具有芳基的嘧啶或在2-位具有芳基的1,3,5-三嗪的磷光有机金属铱配合物的发光装置。嘧啶或1,3,5-三嗪中的氮原子之一与铱配位。此外，嘧啶和1,3,5-三嗪中的每一个都具有诸如烷基或芳基等取代基。而且，与嘧啶的4-位或1,3,5-三嗪的2-位结合的芳基的邻位与铱结合。
• Composite material, light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：Ogita Kaori

  公开号：US09385328B2

  公开（公告）日：2016-07-05

  A composite material which includes an organic compound and an inorganic compound and has a high carrier-transport property is provided. A composite material having a good property of carrier injection into an organic compound is provided. A composite material in which light absorption due to charge-transfer interaction is unlikely to occur is provided. A composite material having a high visible-light-transmitting property is provided. A composite material including a hydrocarbon compound and an inorganic compound exhibiting an electron-accepting property with respect to the hydrocarbon compound is provided. The hydrocarbon compound has a substituent bonded to a naphthalene skeleton, a phenanthrene skeleton, or a triphenylene skeleton and has a molecular weight of 350 to 2000, and the substituent has one or more rings selected from a benzene ring, a naphthalene ring, a phenanthrene ring, and a triphenylene ring.

  提供一种包括有机化合物和无机化合物并具有高载流子传输性能的复合材料。提供一种具有良好载流子注入性能的复合材料。提供一种不太可能发生由于电荷转移相互作用而引起的光吸收的复合材料。提供一种具有高可见光透射性能的复合材料。提供一种包括烃化合物和对烃化合物具有电子受体性质的无机化合物的复合材料。烃化合物具有连接到萘骨架、菲骨架或三苯基骨架的取代基，分子量为350至2000，取代基中有一个或多个从苯环、萘环、菲环和三苯基环中选择的环。
• [EN] ORGANOMETALLIC COMPLEX, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE AND LIGHTING DEVICE<br/>[FR] COMPLEXE ORGANOMÉTALLIQUE, ÉLÉMENT ÉMETTANT DE LA LUMIÈRE, DISPOSITIF ÉMETTANT DE LA LUMIÈRE, DISPOSITIF ÉLECTRONIQUE ET DISPOSITIF D'ÉCLAIRAGE
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2012053627A1

  公开（公告）日：2012-04-26

  Provided is a novel substance that can emit phosphorescence. Alternatively, provided is a novel substance with high emission efficiency. An organometallic complex in which a 4-arylpyrimidine derivative is a ligand and iridium is a central metal is provided. Specifically, an organometallic complex having a structure represented by a general formula (G1) is provided. In the general formula (G1), R1 represents a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aryl group having 6 to 10 carbon atoms, R2 represents any of hydrogen, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, and a substituted or unsubstituted phenyl group, R3 represents hydrogen or a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, and Ar1 represents a substituted or unsubstituted arylene group having 6 to 10 carbon atoms.

  提供了一种可以发出磷光的新物质。另外，提供了一种具有高发射效率的新物质。提供了一种有机金属配合物，其中4-芳基嘧啶衍生物是配体，镭是中心金属。具体地，提供了一种具有由通用公式（G1）表示的结构的有机金属配合物。在通用公式（G1）中，R1代表具有1至4个碳原子的取代或未取代的烷基基团，或具有6至10个碳原子的取代或未取代芳基基团，R2代表氢、具有1至4个碳原子的取代或未取代的烷基基团，以及取代或未取代的苯基，R3代表氢或具有1至4个碳原子的取代或未取代的烷基基团，Ar1代表具有6至10个碳原子的取代或未取代的芳烃基团。
• [EN] DIBENZO[c,g]CARBAZOLE COMPOUND, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, DISPLAY DEVICE, LIGHTING DEVICE AND ELECTRONIC DEVICE<br/>[FR] COMPOSÉ DIBENZO[C,G]CARBAZOLE, ÉLÉMENT ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTROLUMINESCENT, DISPOSITIF D'AFFICHAGE, DISPOSITIF D'ÉCLAIRAGE ET DISPOSITIF ÉLECTRONIQUE
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2013015144A1

  公开（公告）日：2013-01-31

  Provided is a novel compound which can be used for a transport layer or as a host material or a light-emitting material in a light-emitting element and with which a high-performance light-emitting element can be manufactured. A dibenzo[c,g]carbazole compound in which an aryl group having 14 to 30 carbon atoms and including at least anthracene is bonded to nitrogen of a dibenzo[c,g]carbazole derivative is synthesized. By use of the dibenzo[c,g]carbazole compound, a light-emitting element having very good characteristics can be obtained.

  提供了一种新型化合物，可用作光发射元件中的传输层或主体材料或发光材料，利用该化合物可以制造高性能的发光元件。合成了一种二苯并[c,g]咔唑化合物，其中含有14至30个碳原子的芳基团，至少包括蒽，与二苯并[c,g]咔唑衍生物的氮键合。通过使用二苯并[c,g]咔唑化合物，可以获得具有非常良好特性的发光元件。