N,N'-bis(3-methylphenyl)-N,N'-bis[3-(9-phenyl-9H-fluoren-9-yl)phenyl]-pyrene-1,6-diamine | 1292285-21-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: N,N'-bis(3-methylphenyl)-N,N'-bis[3-(9-phenyl-9H-fluoren-9-yl)phenyl]-pyrene-1,6-diamine
• 英文别名: N,N'-Bis(3-methylphenyl)-N,N'-bis[3-(9-phenyl-9H-fluoren-9-yl)phenyl]-pyrene-1,6-di amine；1-N,6-N-bis(3-methylphenyl)-1-N,6-N-bis[3-(9-phenylfluoren-9-yl)phenyl]pyrene-1,6-diamine
• CAS: 1292285-21-2
• 化学式: C₈₀H₅₆N₂
• 分子量: 1045.34
• InChiKey: XFDYBCQHRPMIGD-UHFFFAOYSA-N

物化性质

• 密度：
  1.262±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  21.7
• 重原子数：
  82
• 可旋转键数：
  10
• 环数：
  16.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  9-(3-溴苯基)-9-苯基-9H-芴 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 、 potassium tert-butylate 作用下， 以 甲苯 为溶剂， 反应 22.0h， 生成 N,N'-bis(3-methylphenyl)-N,N'-bis[3-(9-phenyl-9H-fluoren-9-yl)phenyl]-pyrene-1,6-diamine
  参考文献：
  名称：

  一种新的可交联的9,10-二苯基蒽衍生物，可作为宽带隙基质用于溶液处理的有机发光二极管†

  摘要：

  使用多层架构可以获得高效的有机发光二极管（OLED），其中电荷注入，传输和重组的过程在每一层中都得到了分离和优化。从溶液中处理这些结构需要采取策略，以避免重新溶解或破坏先前沉积的层。几份报告证明了可交联的空穴传输材料的发展，而较少的文献描述了这种用于多层OLED的宽带隙基质材料的合成和应用。在这项工作中，我们介绍了一种9-（4-（10-苯基蒽-9-基）苯基）-9 H-咔唑的可交联衍生物，其中含有苯乙烯部分（SPhPC），可通过自由基聚合。我们介绍了SPhPC的合成和表征，以及它在发光层中作为基质的应用，以证明溶液处理的蓝色OLED的概念。

  DOI：

  10.1039/c8tc05013a

文献信息

• Organic Compound, Light-Emitting Element, Display Module, Lighting Module, Light-Emitting Device, Display Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20150243892A1

  公开（公告）日：2015-08-27

  A light-emitting element with high emission efficiency. The light-emitting element includes a pair of electrodes and an EL layer between the pair of electrodes. In the light-emitting element, the EL layer contains at least a light-emitting material, the light-emitting material is a 1,6-bis(diphenylamino)pyrene derivative, and a structural change between an excited state and a ground state in the 1,6-bis(diphenylamino)pyrene derivative is smaller than that in a 1,6-bis(diphenylamino)pyrene derivative in which hydrogen is bonded to ortho positions of two phenyl groups of each of two diphenylamino groups.

  一个发光效率高的发光元件。该发光元件包括一对电极和一对电极之间的EL层。在发光元件中，EL层包含至少一种发光材料，发光材料为1,6-双(二苯基氨基)芘衍生物，且1,6-双(二苯基氨基)芘衍生物在激发态和基态之间的结构变化小于在每个二苯基氨基组的两个苯基的邻位上连接氢的1,6-双(二苯基氨基)芘衍生物。
• Organometallic Complex, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20160028027A1

  公开（公告）日：2016-01-28

  An object is to provide a novel organometallic complex. Another object is to provide an organometallic complex exhibiting green to blue phosphorescence. Another object is to provide an organometallic complex having deep HOMO and exhibiting green to blue phosphorescence. Another object is to provide a light-emitting element with high emission efficiency. Another object is to provide a light-emitting element exhibiting green to blue phosphorescence and having low drive voltage. To provide an organometallic complex which includes a 1,2,4-triazole skeleton and in which an N-carbazolyl group is bonded to the 3-position of the 1,2,4-triazole skeleton via a phenylene group, a phenyl group is bonded to the 4-position of the 1,2,4-triazole skeleton, the 2-position of the 1,2,4-triazole skeleton coordinates to iridium, and the phenylene group is bonded to the iridium. To provide a light-emitting element including the organometallic complex as an emission center.

  一个目的是提供一种新型的有机金属配合物。另一个目的是提供一种显示绿色到蓝色磷光的有机金属配合物。另一个目的是提供一种具有深层HOMO并能显示绿色到蓝色磷光的有机金属配合物。另一个目的是提供一种具有高发射效率的发光元件。另一个目的是提供一种显示绿色到蓝色磷光且驱动电压低的发光元件。提供一种包括1,2,4-三唑骨架的有机金属配合物，其中，一个N-咔唑基团通过一个苯环基团与1,2,4-三唑骨架的3-位键合，一个苯基团与1,2,4-三唑骨架的4-位键合，1,2,4-三唑骨架的2-位与铱配位，并且苯环基团与铱键合。提供一种包括上述有机金属配合物作为发射中心的发光元件。
• MATERIAL FOR HOLE-TRANSPORT LAYER, MATERIAL FOR HOLE-INJECTION LAYER, ORGANIC COMPOUND, LIGHT-EMITTING DEVICE, LIGHT-EMITTING APPARATUS, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

  公开号：US20210005814A1

  公开（公告）日：2021-01-07

  A material for a hole-transport layer includes a monoamine compound. The first aromatic group, the second aromatic group, and the third aromatic group are bonded to the nitrogen atom of the monoamine compound. The first and second aromatic groups each independently include 1 to 3 benzene rings. One or both of the first and second aromatic groups have one or more hydrocarbon groups each having 1 to 12 carbon atoms each forming a bond only by the sp 3 hybrid orbitals. The total number of the carbon atoms in the hydrocarbon group in the first or second aromatic group is 6 or more. The total number of the carbon atoms in all of the hydrocarbon groups in the first and second aromatic groups is 8 or more. The third aromatic group is a substituted or unsubstituted monocyclic condensed ring or a substituted or unsubstituted bicyclic or tricyclic condensed ring.

  一种用于空穴传输层的材料包括单胺化合物。第一个芳基团、第二个芳基团和第三个芳基团均连接到单胺化合物的氮原子上。第一个和第二个芳基团每个独立地包括1到3个苯环。第一个和第二个芳基团中的一个或两个具有一个或多个各自具有1到12个碳原子的烃基团，这些烃基团仅通过sp3杂化轨道形成键。第一或第二芳基团中的烃基团中的碳原子总数为6个或更多。第一和第二芳基团中的所有烃基团中的碳原子总数为8个或更多。第三个芳基团是取代的或未取代的单环稠环，或是取代的或未取代的双环或三环稠环。
• ARYLAMINE COMPOUND, HOLE-TRANSPORT LAYER MATERIAL, HOLE-INJECTION LAYER MATERIAL, LIGHT-EMITTING DEVICE, LIGHT-EMITTING APPARATUS, ELECTRONIC APPARATUS, AND LIGHTING DEVICE
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

  公开号：US20210317069A1

  公开（公告）日：2021-10-14

  To provide a novel arylamine compound with a low refractive index. The provided arylamine compound includes at least one aromatic group. The aromatic group includes a first benzene ring, a second benzene ring, a third benzene ring, and at least three alkyl groups. The first benzene ring, the second benzene ring, and the third benzene ring are directly bonded in this order. The first benzene ring is bonded to nitrogen of amine. The first benzene ring may further include a substituted or unsubstituted phenyl group. The second benzene ring or the third benzene ring may further include an alkylated phenyl group. Each of first positions and third positions of two or more of the first to third benzene rings is independently bonded to another benzene ring, a benzene ring of the alkylated phenyl group, any of the at least three alkyl groups, or the nitrogen of the amine.

  提供一种低折射率的新型芳胺化合物。所提供的芳胺化合物包括至少一个芳香族基团。该芳香族基团包括第一苯环、第二苯环、第三苯环和至少三个烷基团。第一苯环、第二苯环和第三苯环按此顺序直接键合。第一苯环与胺的氮原子键合。第一苯环可进一步包括取代的或未取代的苯基团。第二苯环或第三苯环可进一步包括烷基化的苯基团。第一至第三苯环中的两个或多个第一位置和第三位置独立地键合到另一个苯环、烷基化苯基团的苯环、至少三个烷基团中的任一个或胺的氮原子。
• Organometallic Complex, Light-Emitting Element, Light-Emitting Device, Electronic Device and Lighting Device
  申请人：Inoue Hideko

  公开号：US20120098417A1

  公开（公告）日：2012-04-26

  Provided is a novel substance that can emit phosphorescence. Alternatively, provided is a novel substance with high emission efficiency. An organometallic complex in which a 4-arylpyrimidine derivative is a ligand and iridium is a central metal is provided. Specifically, an organometallic complex having a structure represented by a general formula (G1) is provided. In the general formula (G1), R 1 represents a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted aryl group having 6 to 10 carbon atoms, R 2 represents any of hydrogen, a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, and a substituted or unsubstituted phenyl group, R 3 represents hydrogen or a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, and Ar 1 represents a substituted or unsubstituted arylene group having 6 to 10 carbon atoms.

  提供了一种可以发射磷光的新型物质。或者，提供了一种具有高发射效率的新型物质。提供了一种有机金属配合物，其中4-芳基嘧啶衍生物是配体，镭是中心金属。具体地，提供了一种具有通用式（G1）表示的结构的有机金属配合物。在通用式（G1）中，R1代表具有1至4个碳原子的取代或未取代的烷基基团或具有6至10个碳原子的取代或未取代的芳基基团，R2代表氢、具有1至4个碳原子的取代或未取代的烷基基团，以及取代或未取代的苯基，R3代表氢或具有1至4个碳原子的取代或未取代的烷基基团，Ar1代表具有6至10个碳原子的取代或未取代的芳烃基团。