phenanthro oxazole | 219-41-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: phenanthro oxazole
• 英文别名: phenanthrooxazole；Phenanthrooxazole；naphtho[2,1-e][1,3]benzoxazole
• CAS: 219-41-0
• 化学式: C₁₅H₉NO
• 分子量: 219.243
• InChiKey: JAUCCASEHMVMPM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  iridium(III) chloride 、 phenanthro oxazole 以 乙二醇乙醚 为溶剂， 反应 24.0h， 以92%的产率得到(PNTOZ)2Ir(Cl)2Ir(PNTOZ)2
  参考文献：
  名称：

  Metallic Compound and Organic Electroluminescence Device Comprising the Same

  摘要：

  本发明涉及一种由化学式1和化学式2表示的发光过渡金属化合物，以及包括该化合物的有机电致发光器件。在化学式1和2中，M为Ir、Pt、Rh、Re、Os等，m为2或3，n为0或1，m和n的总和为3，当M为Pt时，m和n的总和为2，X和Z相同或不同，为N或P，Y和Q为O、S或Se，R1和R5为氢、除芳香环取代基外的C1到C20烷基、环烷基、卤素、线性或支链取代基，包括至少一个卤素，或包括至少一个杂原子的线性或支链取代基，R2、R3、R4、R6、R7、R8、R9和R10为氢、C1到C20烷基、芳基、环烷基、卤素、线性或支链取代基，包括至少一个卤素，线性或支链取代基，包括至少一个杂原子，羰基、烯基或乙炔基，或可形成环，并且可以相同或不同。

  公开号：

  US20080200678A1
• 作为产物：
  描述：

  formic anhydride 、 1-Amino-2-oxy-phenanthren 在 sodium dodecyl-sulfate 作用下， 以 水 为溶剂， 反应 0.25h， 以71%的产率得到phenanthro oxazole
  参考文献：
  名称：

  Metallic Compound and Organic Electroluminescence Device Comprising the Same

  摘要：

  本发明涉及一种由化学式1和化学式2表示的发光过渡金属化合物，以及包括该化合物的有机电致发光器件。在化学式1和2中，M为Ir、Pt、Rh、Re、Os等，m为2或3，n为0或1，m和n的总和为3，当M为Pt时，m和n的总和为2，X和Z相同或不同，为N或P，Y和Q为O、S或Se，R1和R5为氢、除芳香环取代基外的C1到C20烷基、环烷基、卤素、线性或支链取代基，包括至少一个卤素，或包括至少一个杂原子的线性或支链取代基，R2、R3、R4、R6、R7、R8、R9和R10为氢、C1到C20烷基、芳基、环烷基、卤素、线性或支链取代基，包括至少一个卤素，线性或支链取代基，包括至少一个杂原子，羰基、烯基或乙炔基，或可形成环，并且可以相同或不同。

  公开号：

  US20080200678A1

文献信息

• [EN] ELECTRON BUFFERING MATERIALS, ELECTRON TRANSPORT MATERIALS AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME<br/>[FR] MATÉRIAUX TAMPON D'ÉLECTRONS, MATÉRIAUX DE TRANSPORT D'ÉLECTRONS ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LES COMPRENANT
  申请人：ROHM & HAAS ELECT MATERIALS KOREA LTD

  公开号：WO2017073942A1

  公开（公告）日：2017-05-04

  The present disclosure relates to an electron buffering material, and an organic electroluminescent device comprising a first electrode, a second electrode facing the first electrode, a light-emitting layer between the first electrode and the second electrode, and an electron transport zone and an electron buffering layer between the light-emitting layer and the second electrode. The organic electroluminescent device comprising the electron buffering material of the present disclosure has low driving voltage, excellent luminous efficiency, and long lifespan.

  本公开涉及一种电子缓冲材料，以及包括第一电极、面向第一电极的第二电极、位于第一电极和第二电极之间的发光层、以及位于发光层和第二电极之间的电子传输区和电子缓冲层的有机电致发光器件。采用本公开的电子缓冲材料制备的有机电致发光器件具有低驱动电压、优异的发光效率和长寿命。
• [EN] ORGANIC ELECTROLUMINESCENT COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE THEREOF<br/>[FR] COMPOSÉ ÉLECTROLUMINESCENT ORGANIQUE ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE ASSOCIÉ
  申请人：ROHM & HAAS ELECT MATERIALS KOREA LTD

  公开号：WO2020232655A1

  公开（公告）日：2020-11-26

  Presented is an organic electroluminescent compound and an organic electroluminescent device comprising the same. By comprising the organic electroluminescent compound of the present disclosure, it is possible to provide an organic electroluminescent device having an operating voltage lower than that of a conventional organic electroluminescent device and thus achieving higher power efficiency.

  提供了一种有机电致发光化合物和包括该化合物的有机电致发光器件。通过采用本公开的有机电致发光化合物，可以提供一个操作电压低于传统有机电致发光器件的有机电致发光器件，从而实现更高的功率效率。
• Metallic compound and organic electroluminescence device comprising the same
  申请人：Samsung Electronics Co., Ltd.

  公开号：US07968715B2

  公开（公告）日：2011-06-28

  The present invention relates to a light-emitting transition metal compound represented by the Chemical Formula 1 and Chemical Formula 2 and an organic electroluminescence device including the same. In the Chemical Formulae 1 and 2, M is Ir, Pt, Rh, Re, Os, and the like, m is 2 or 3, n is 0 or 1, the sum of m and n is 3, provided that the sum of m and n is 2 when M is Pt, X, and Z are the same or different, N or P, and Y and Q are O, S, or Se, R1 and R5 are hydrogen, a C1 to C20 alkyl excluding an aromatic cyclic substituent, a cycloalkyl, a halogen, a linear or branched substituent including at least one halogen, or a linear or branched substituent including at least one heteroatom, and R2, R3, R4, R6, R7, R8, R9, and R10 are hydrogen, a C1 to C20 alkyl, an aryl, a cycloalkyl, a halogen, a linear or branched substituent including at least one halogen, a linear or branched substituent including at least one heteroatom, carbonyl, vinyl, or acetylenyl, or may form a cycle, and may be the same or different.

  本发明涉及一种由化学式1和化学式2所表示的发光过渡金属化合物和包括该化合物的有机电致发光装置。在化学式1和2中，M为Ir、Pt、Rh、Re、Os等，m为2或3，n为0或1，m和n的和为3，当M为Pt时，m和n的和为2，X和Z为相同或不同的N或P，Y和Q为O、S或Se，R1和R5为氢、不包括芳香环取代基的C1到C20烷基、环烷基、卤素、至少包括一个卤素的线性或支链取代基，或至少包括一个杂原子的线性或支链取代基，而R2、R3、R4、R6、R7、R8、R9和R10为氢、C1到C20烷基、芳基、环烷基、卤素、至少包括一个卤素的线性或支链取代基、至少包括一个杂原子的线性或支链取代基、羰基、乙烯基或乙炔基，或者可以形成一个环，它们可以相同或不同。
• Process for production of vinyl chloride polymer
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP0172427A2

  公开（公告）日：1986-02-26

  This process is a process for production of a vinyl chloride polymer by suspension polymerization or emulsion polymerization of vinyl chloride monomer or a mixture of vinyl chloride monomer with a vinyl monomer copolymerizable with said vinyl chloride monomer in an aqueous medium, characterized in that the polymerization is carried out in a polymerizer, the inner wall surface and portions of the auxiliary equipment thereof which may come into contact with the monomer during polymerization being previously coated with a scaling preventive comprising at least one selected from dyes, pigments and aromatic or heterocyclic compounds having at least 5 conjugated π bonds, while controlling the chloride ion concentration in the reaction mixture to not higher than 100 ppm. According to said process, scaling onto the inner wall surface of a polymerizer, etc. during polymerization can be prevented effectively and surely.

  该工艺是通过氯乙烯单体或氯乙烯单体与可与所述氯乙烯单体共聚的乙烯基单体混合物在水介质中进行悬浮聚合或乳液聚合来生产氯乙烯聚合物的工艺，其特征在于聚合是在聚合器中进行的、内壁表面及其辅助设备中可能在聚合过程中与单体接触的部分事先涂上一层防垢剂，该防垢剂至少包括一种选自染料、颜料和至少有 5 个共轭 π 键的芳香族或杂环化合物的防垢剂，同时控制反应混合物中的氯离子浓度不高于 100 ppm。根据上述工艺，可有效、可靠地防止聚合过程中聚合器等内壁表面结垢。
• Polymerization process characterized by a two layer coating against scale formation deposited using a steam carrier
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：EP0934955A1

  公开（公告）日：1999-08-11

  An improved process for producing a polymer by polymerizing a monomer having an ethylenic double bond in a polymerization vessel having a polymer scale preventive coating film on its inner wall surfaces, etc. is provided. The coating film is formed by coating a first coating liquid containing a compound selected from the group consisting of an aromatic compound having 5 or more conjugated π bonds and a heterocyclic compound having 5 or more conjugated π bonds, and then coating a second coating liquid on the first layer. The first and second coating liquids are applied by means of steam as a carrier. The second layer has a surface having a contact angle to water of less than 60° after its surface has been brought into contact with a solution of mixture of water and a vinyl chloride monomer in a weight ratio of 1:1, at 50°C for 1 hour. This process can shorten the time for forming the coating film to improve productivity, can improve the effect of preventing adhesion of polymer scale, can make colored particles less mix into polymer products obtained by this process, can lessen fish eyes and initial discoloring of formed products and can improve the quality of polymeric products and their formed or molded products.

  本发明提供了一种通过在聚合容器中聚合具有乙烯双键的单体来生产聚合物的改进工艺，该聚合容器的内壁表面等处具有聚合物防垢涂膜。该涂膜是通过涂覆第一涂覆液形成的，第一涂覆液含有选自具有 5 个或更多共轭 π 键的芳香族化合物和具有 5 个或更多共轭 π 键的杂环化合物的一组化合物，然后在第一层上涂覆第二涂覆液。第一种和第二种涂覆液通过蒸汽作为载体进行涂覆。第二层表面与水和氯乙烯单体重量比为 1:1 的混合物溶液在 50°C 下接触 1 小时后，其表面与水的接触角小于 60°。这种工艺可以缩短涂膜的形成时间，从而提高生产率；可以提高防止聚合物鳞片附着的效果；可以使有色颗粒较少地混入通过这种工艺获得的聚合物产品中；可以减少成型产品的鱼眼和初期褪色现象；可以提高聚合物产品及其成型或模塑产品的质量。