3,4-Dinitro-hexan | 22482-64-0

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 英文名称: 3,4-Dinitro-hexan
• 英文别名: 3,4-dinitro-hexane；3,4-Dinitrohexane
• CAS: 22482-64-0
• 化学式: C₆H₁₂N₂O₄
• 分子量: 176.172
• InChiKey: BQLWHDVPNRTGRM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  91.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  反-3-已烯 在 二氧化氮 作用下， 以 正己烷 为溶剂， 反应 0.08h， 生成 3,4-Dinitro-hexan
  参考文献：
  名称：

  Golding, Peter; Powell, Joy L.; Ridd, John H., Journal of the Chemical Society. Perkin transactions II, 1996, # 5, p. 813 - 820

  摘要：

  DOI：

文献信息

• Controlled Odor Mimic Permeation System
  申请人：Furton Kenneth G.

  公开号：US20080295783A1

  公开（公告）日：2008-12-04

  The primary aspect of the Controlled Odor Mimic Permeation System (COMPS) is that it provides a field deployable instant and reproducible source of known amounts of target odors. This technology consists of a permeable polymer container (chosen to suit target odor and release rate required), stored inside a non-permeable package. The design allows for the pre-equilibration of the target odors such that the outer surface of the inner package can saturate with odor during storage. Removal of the inner item then provides an instant and reproducible source of known target vapor flux. We have successfully demonstrated this technology by placing the target odor chemicals within permeable membranes such as low density polyethylene which are then sealed within a non-permeable membranes such as metallized polyester. This design has multiple advantages including preventing cross contamination when storing multiple odor targets (5-10 targets are commonly employed) as well as being light-weight disposable, low unit cost potential, no external power/operating unit/machinery/hardware, simple to use and providing a known reproducible concentration of the target odors to the detector in the field. The applications of these COMPS include the whole range of biological (e.g. detector dog) and electronic (e.g. field sensors) detectors with examples such as explosives (e.g. 2-ethyl-1-hexanol simulating plasticized explosives), drugs (e.g. 3,4-methylenedioxybenzaldehyde simulating ecstasy), human remains (including dimethyl disulfide and pentanoic acid) and live human scent (including 5-heptene-2-one and nonanol).

  受控气味模拟渗透系统（COMPS）的主要方面是，它提供了一个现场可部署的即时和可重复的目标气味已知量源。该技术由一个渗透性聚合物容器（选择适合目标气味和所需释放速率的容器）组成，存放在一个非渗透性包装内。该设计允许目标气味预平衡，使内包装的外表面在存储期间饱和。然后，移除内部物品即可提供已知目标蒸汽通量的即时和可重复的源。我们已经成功地通过将目标气味化学品放置在渗透膜内（例如低密度聚乙烯），然后密封在非渗透膜内（例如金属化聚酯），展示了这项技术。这种设计具有多个优点，包括在存储多个气味目标（通常使用5-10个目标）时防止交叉污染，轻量级一次性，低单位成本潜力，无需外部电源/操作单元/机械/硬件，易于使用并在现场为检测器提供已知可重复的目标气味浓度。这些COMPS的应用包括整个生物（例如检测犬）和电子（例如现场传感器）检测器的范围，例如爆炸物（例如模拟塑化炸药的2-乙基-1-己醇），毒品（例如模拟迷幻药的3,4-亚甲二氧基苯甲醛），人体遗骸（包括二甲基二硫化物和戊酸）和活体人体气味（包括5-庚烯-2-酮和辛醇）。
• Oxidation of nitronates with persulfate and with silver ions
  作者：Alfred H. Pagano、Harold Shechter

  DOI：10.1021/jo00827a002

  日期：1970.2
• Electrolysis of primary nitroalkanes
  申请人：BAHNER CARL T

  公开号：US02485803A1

  公开（公告）日：1949-10-25
• BRANCHED COMPOUNDS AND THEIR USE IN SENSORS
  申请人：ISIS INNOVATION LIMITED

  公开号：EP1973983A1

  公开（公告）日：2008-10-01
• SYSTEM AND METHOD FOR DETECTING A MEDICAL CONDITION IN A SUBJECT
  申请人：Biosense Medical Ltd

  公开号：EP3102026A1

  公开（公告）日：2016-12-14