2-[(diphenylphosphanyl)methyl]-1,1,1,3,3,3-hexafluoro-propan-2-ol | 98331-76-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-[(diphenylphosphanyl)methyl]-1,1,1,3,3,3-hexafluoro-propan-2-ol
• 英文别名: 2-[(diphenylphosphanyl)methyl]-1,1,1,3,3,3-hexafluoropropan-2-ol；3-diphenylphosphino-1,1,1-trifluoro-2-trifluoromethyl-2-propanol；2-Propanol, 2-[(diphenylphosphino)methyl]-1,1,1,3,3,3-hexafluoro-；2-(diphenylphosphanylmethyl)-1,1,1,3,3,3-hexafluoropropan-2-ol
• CAS: 98331-76-1
• 化学式: C₁₆H₁₃F₆OP
• 分子量: 366.243
• InChiKey: GORJRRDZPJZJNO-UHFFFAOYSA-N

物化性质

• 沸点：
  379.4±42.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  2-[(diphenylphosphanyl)methyl]-1,1,1,3,3,3-hexafluoro-propan-2-ol 在 KOH 、 HCl 作用下， 以 乙醇 、 N,N-二甲基甲酰胺 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Complexes of hybrid ligands. Synthesis, reactions, and structures of platinum complexes derived from a diphenylphosphino-substituted fluorinated tertiary alcohol

  摘要：

  DOI：

  10.1021/ic00251a008
• 作为产物：
  描述：

  3,3,3,-三氟-2-(三氟甲基)-1,2-氧化丙烯 、 二苯基膦 以 四氢呋喃 为溶剂， 反应 48.0h， 以41%的产率得到2-[(diphenylphosphanyl)methyl]-1,1,1,3,3,3-hexafluoro-propan-2-ol
  参考文献：
  名称：

  Facile preparation and synthetic applications of LiCH2C(CF3)2OLi

  摘要：

  Bromohydrin BrCH2C(CF3)(2)OH readily reacts with two equivalents of n-BuLi at -78 degreesC to produce the corresponding dilithium derivative LiCH2C(CF3)(2)OLi in high yield. This dilithiated derivative reacts selectively, acting as a C-nucleophile, with a variety of electrophiles such as R2PCl, carbonyl compounds, and epoxides, to give electron-deficient phosphines R2PCH2C(CF3)(2)OH, 1,3- and 1,4-diols, correspondingly. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-1139(02)00154-9

文献信息

• [EN] COMPOUNDS COMPRISING PHOSPHORUS-CONTAINING METAL COMPLEXES<br/>[FR] COMPOSES COMPRENANT DES COMPLEXES METALLIQUES CONTENANT DU PHOSPHORE
  申请人：DU PONT

  公开号：WO2004016710A1

  公开（公告）日：2004-02-26

  Compounds comprising phosphorus-containing metal complexes can be used in electroluminescent devices and have an emission maximum closer to the blue region of the visible light spectrum. The complexes can be used within an organic active layer in electronic devices, such as displays, detectors, voltaic cells, solid-state lighting, illumination devices or the like. The complexes may also be used as catalysts or as indicators in other applications. The new compounds can be used without the need of a host material. In non-limiting embodiments, Pt or Ir may be used for the metal atom within the complex, one ligand may include a phosphorus-containing bidentate ligand, and another ligand may include a monoanionic bidentate ligand. The phosphorus-containing bidentate ligand may include a benzyl group, a phenoxy group, a phenylamino group, or the like.

  含磷金属配合物的化合物可用于电致发光器件，并且其发射峰值更接近可见光谱的蓝色区域。这些配合物可用于电子器件中的有机活性层，如显示器、探测器、伏打电池、固态照明、照明设备等。这些配合物也可用作催化剂或其他应用中的指示剂。这些新化合物可在无需宿主材料的情况下使用。在非限制性实施例中，金属原子可以使用Pt或Ir，一个配体可以包括含磷的双齿配体，另一个配体可以包括单阴离子双齿配体。含磷的双齿配体可以包括苄基、苯氧基、苯胺基等。
• In situ NMR and EXAFS studies of the homogeneous alkene oligomerisation catalyst Ni(cod)₂–Ph₂PCH₂C(CF₃)₂OH
  作者：Paul Andrews、John Evans

  DOI：10.1039/c39930001246

  日期：——

  NMR and extended X-ray absorption fine structure (EXAFS) studies indicate that the nickel coordination sphere of the highly active alkene Oligomerisation catalyst formed on addition of Ph2PCH2C(CF3)2OH to Ni(cod)2(cod = cycloocta-1,5-diene) is [graphic ommitted]rcub;HPh2PCH2C(CH3)2OH}.

  核磁共振和扩展 X 射线吸收精细结构 (EXAFS) 研究表明，Ph2PCH2C(CF3)2OH 加入 Ni(cod)2（cod = 环辛烷-1,5-二烯）后形成的高活性烯烃低聚催化剂的镍配位层为 [图形省略]rcub;HPh2PCH2C(CH3)2OH}。
• Electroluminescent bis-cyclometalled iridium compounds and devices made with such compounds
  申请人：Ionkin Sergey Alex

  公开号：US20070259205A1

  公开（公告）日：2007-11-08

  One embodiment of this invention is bis-cyclometalled electroluminescent complexes of iridium(III). Another embodiment of this invention is electronic devices in which the active layer includes an bis-cyclometalled electroluminescent Ir(III) complex.

  本发明的一种实施例是铱（III）的双环金属电致发光配合物。本发明的另一种实施例是电子器件，其中活性层包括双环金属电致发光Ir（III）配合物。
• ORGANIC ELECTRIC FIELD LIGHT EMITTING ELEMENT AND PRODUCTION THEREFOR
  申请人：Mitsubishi Chemical Corporation

  公开号：EP1857521A1

  公开（公告）日：2007-11-21

  A composition for an organic electroluminescent device is a composition for forming an organic light emitting layer of an organic electroluminescent device by wet coating process. The composition contains a phosphorescent material, a charge transport material, and a solvent, in which the phosphorescent material and the charge transport material are each an unpolymerized organic compound, and the first oxidation potential of the phosphorescent material ED+, the first reduction potential of the phosphorescent material ED-, the first oxidation potential of the charge transporting material ET+, and the first reduction potential of the charge transporting material ET- satisfy the following condition: ET-+0.1≤ED-

  一种用于有机电致发光器件的组合物是一种用于通过湿涂层工艺形成有机电致发光器件的有机发光层的组合物。该组合物包含磷光材料、电荷传输材料和溶剂，其中磷光材料和电荷传输材料均为未聚合的有机化合物，磷光材料的第一氧化电位 ED+、磷光材料的第一还原电位 ED-、电荷传输材料的第一氧化电位 ET+、电荷传输材料的第一还原电位 ET- 满足以下条件：ET-+0.1≤ED-
• Compounds comprising phosphorus-containing metal complexes
  申请人：——

  公开号：US20040068132A1

  公开（公告）日：2004-04-08

  Compounds comprising phosphorus-containing metal complexes can be used in electroluminescent devices and have an emission maximum closer to the blue region of the visible light spectrum. The complexes can be used within an organic active layer in electronic devices, such as displays, detectors, voltaic cells, solid-state lighting, illumination devices or the like. The complexes may also be used as catalysts or as indicators in other applications. The new compounds can be used without the need of a host material. In non-limiting embodiments, Pt or Ir may be used for the metal atom within the complex, one ligand may include a phosphorus-containing bidentate ligand, and another ligand may include a monoanionic bidentate ligand. The phosphorus-containing bidentate ligand may include a benzyl group, a phenoxy group, a phenylamino group, or the like.

  由含磷金属络合物组成的化合物可用于电致发光装置，其发射最大值更接近可见光光谱的蓝色区域。这些配合物可用于电子设备中的有机活性层，如显示器、探测器、伏特电池、固态照明、照明设备等。这些复合物还可用作催化剂或其他应用中的指示剂。新化合物的使用无需宿主材料。在非限制性实施例中，铂或铱可用于配合物中的金属原子，一种配体可包括含磷双齿配体，另一种配体可包括单阴离子双齿配体。含磷双齿配体可包括苄基、苯氧基、苯胺基等。