Cyanomethyl-methacrylat | 7726-87-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Cyanomethyl-methacrylat
• 英文别名: Cyanomethyl 2-methylprop-2-enoate
• CAS: 7726-87-6
• 化学式: C₆H₇NO₂
• 分子量: 125.127
• InChiKey: KXTNMKREYTVOMX-UHFFFAOYSA-N

物化性质

• 沸点：
  90-91 °C(Press: 10 Torr)
• 密度：
  1.048±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  50.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Cyanomethyl-methacrylat 在 一水合肼 作用下， 以 乙醇 为溶剂， 生成 methylene bis methacrylamide
  参考文献：
  名称：

  Synthesis of α,β-Unsaturated Carboxylic Hydrazides

  摘要：

  DOI：

  10.1246/bcsj.41.2521
• 作为产物：
  描述：

  甲基丙烯酸 、 氯乙腈 在 三乙胺 、 对苯二酚 作用下， 生成 Cyanomethyl-methacrylat
  参考文献：
  名称：

  Alkyl-Oxygen Cleavage of α, β-Unsaturated Esters with Secondary Amines

  摘要：

  DOI：

  10.1246/bcsj.40.2706

文献信息

• Methods of manufacturing deodorants, and deodorants resulting thereof
  申请人：Hu Jinlian

  公开号：US20050232880A1

  公开（公告）日：2005-10-20

  This invention provides a deodorant capable of releasing deodorant agents at certain temperatures and having improved adherence to textiles. The deodorant of this invention includes polymer particles formed by reacting a main monomer of (N-substituted alkyl)acrylamide, a functional monomer for bonding the polymer particles to a fibrous substrate, and a cross-linking agent. A deodorant agent is loaded to the polymer particles.

  这项发明提供了一种能够在特定温度释放除臭剂并具有改善对纺织品附着性的除臭剂。该发明的除臭剂包括由反应主单体（N-取代烷基）丙烯酰胺、用于将聚合物颗粒与纤维基质结合的功能单体以及交联剂形成的聚合物颗粒。除臭剂被加载到聚合物颗粒中。
• [EN] CH-ACIDIC METHACRYLIC ESTERS FOR THE PREPARATION OF AQUEOUS POLYMER DISPERSIONS<br/>[FR] ESTERS MÉTHACRYLIQUES CH-ACIDES POUR LA PRÉPARATION DE DISPERSIONS POLYMÈRES AQUEUSES
  申请人：EVONIK OPERATIONS GMBH

  公开号：WO2020016037A1

  公开（公告）日：2020-01-23

  The present invention relates to CH-acidic methacrylic esters and also copolymers obtainable from CH-acidic methacrylic esters. Furthermore, the present invention relates to coating compositions comprising these copolymers.

  本发明涉及CH-酸性甲基丙烯酸酯，以及可由CH-酸性甲基丙烯酸酯获得的共聚物。此外，本发明涉及包含这些共聚物的涂料组合物。
• (METH)ACRYLATE MONOMER, POLYMER AND COATING AGENT
  申请人：Schuetz Thorben

  公开号：US20110130509A1

  公开（公告）日：2011-06-02

  The present invention relates to a (meth)acrylate monomer of the general formula (I) in which R 1 is hydrogen or a methyl group, X is oxygen or a group of the formula NR′ in which R′ is hydrogen or a radical having 1 to 6 carbon atoms, R 2 is an alkylene group having 1 to 22 carbon atoms, Y is oxygen, sulphur or a group of the formula NR″, in which R″ represents hydrogen or a radical having 1 to 6 carbon atoms, and R 3 is an unsaturated radical having 8 carbon atoms and at least two double bonds. The present invention further relates to a process for preparing the monomers set out above, to polymers obtainable from this monomer mixture, and to coating materials which comprise the stated polymers.

  本发明涉及一种通式（I）的（甲基）丙烯酸酯单体，其中R1为氢或甲基基团，X为氧或式NR′的基团，其中R′为氢或具有1至6个碳原子的基团，R2为具有1至22个碳原子的烷基基团，Y为氧、硫或式NR″的基团，其中R″表示氢或具有1至6个碳原子的基团，而R3为具有8个碳原子和至少两个双键的不饱和基团。本发明还涉及一种制备上述单体的方法，以及从该单体混合物得到的聚合物和包含所述聚合物的涂料材料。
• Process for synthesis of polymer compositions, polymer compositions obtainable by the process, and use of the same
  申请人：RohMax Additives GmbH

  公开号：US20030060587A1

  公开（公告）日：2003-03-27

  The present invention relates to a process for synthesis of polymer compositions with reduced catalyst content, wherein ethylenically unsaturated monomers containing less than 0.5 wt % of ethylenically unsaturated monomers with at least one carboxylic group, sulfonic acid group and/or at least one phosphonic acid group relative to the total weight of the ethylenically unsaturated monomers are polymerized by means of initiators containing a transferable group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts and, after the polymerization, the catalyst contained in the polymer is at least partly separated. For this purpose, the polymer composition is filtered, after the polymerization, in the presence of at least one filter aid which contains at least 0.5 wt%, relative to the total weight of the filter aid, of repeating units that contain at least one carboxylic acid group, sulfonic acid group and/or at least one phosphonic acid group.

  本发明涉及一种合成聚合物组合物的过程，其具有降低催化剂含量的效果。在该过程中，含有少于0.5重量％的至少含有一个羧基，磺酸基和/或至少一个膦酸基的乙烯基不饱和单体相对于乙烯基不饱和单体的总重量进行聚合，通过含有可转移原子团的引发剂和至少一种过渡金属的催化剂，在与可以形成与金属催化剂或催化剂配合物的配体一起的情况下进行聚合，在聚合之后，聚合物中的催化剂至少部分被分离。为此，在聚合之后，通过至少一种过滤助剂过滤聚合物组合物，该过滤助剂相对于总重量含有至少0.5重量％的重复单元，其中包含至少一个羧酸基，磺酸基和/或至少一个膦酸基。
• Organic antimony compound, process for producing the same, living radical polymerization initiator, process for producing polymer using the same, and polymer
  申请人：Yamago Shigeru

  公开号：US20090299008A1

  公开（公告）日：2009-12-03

  An organoantimony compound represented by the formula (1), processes for producing polymers with use of the compound, and polymers wherein R 1 and R 2 are C 1 -C 8 alkyl, aryl, substituted aryl or an aromatic heterocyclic group, R 3 and R 4 are each a hydrogen atom or C 1 -C 8 alkyl, and R 5 is aryl, substituted aryl, an aromatic heterocyclic group, oxycarbonyl or cyano.

  一种有机锑化合物，其化学式表示为（1），使用该化合物生产聚合物的方法，以及其中R1和R2为C1-C8烷基，芳基，取代芳基或芳香族杂环基，R3和R4分别为氢原子或C1-C8烷基，R5为芳基，取代芳基，芳香族杂环基，氧羰基或氰基的聚合物。