2-(二丁基氨基)乙基丙-2-烯酸酯 | 7709-10-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2-(二丁基氨基)乙基丙-2-烯酸酯
• 英文名称: 2-(dibutylamino)ethyl acrylate
• 英文别名: acrylic acid-(2-dibutylamino-ethyl ester)；Acrylsaeure-(2-dibutylamino-aethylester)；2-(Dibutylamino)ethyl prop-2-enoate
• CAS: 7709-10-6
• 化学式: C₁₃H₂₅NO₂
• 分子量: 227.347
• InChiKey: UOZJCRSVUOQDNJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  16
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-溴辛烷 、 2-(二丁基氨基)乙基丙-2-烯酸酯 在 4-甲氧基苯酚 作用下， 生成
  参考文献：
  名称：

  Antibacterial Composition

  摘要：

  An antibacterial composition according to an exemplary embodiment of the present technology comprises one or more compounds comprising a quaternary ammonium structure having an acrylate group or a methacrylate group, in which a critical micelle concentration of the compound comprising the quaternary ammonium structure is 0.1 wt % to 3 wt %.

  公开号：

  US20240108001A1
• 作为产物：
  描述：

  2-(二丁氨基)乙醇 、 丙烯酰氯 在 三乙胺 、 对苯二酚 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 生成 2-(二丁基氨基)乙基丙-2-烯酸酯
  参考文献：
  名称：

  丙烯酸2-（二丁氨基）乙酯作为Ru（bpy）3 2+电致发光的高效共反应物;用于选择性检测半胱氨酸

  摘要：

  通过二丁基氨基乙醇和丙烯酰氯之间的直接一步反应，成功合成了Ru（bpy）3 2+电致发光（ECL），丙烯酸2-（二丁基氨基）乙酯（DBAEA）的高效共反应物。由于DBAEA的烯烃基团和Pt电极之间的相互作用，利用DBAEA作为共反应剂的ECL强度显着提高，分别是常规共反应物二丁胺乙醇和三丙胺的10倍和17倍。由于半胱氨酸可以通过共轭加成/环化反应特异性去除DBAEA的丙烯酸酯基团，因此Ru（bpy）3 2+的ECL强度/ DBAEA被有选择地拒绝。因此，通过这种新颖的ECL系统检测到半胱氨酸对其他氨基酸具有高选择性。线性范围在10μM至200μM之间，检出限为1.15μM。检测了Dulbecco改良Eagle培养基（DMEM）中的半胱氨酸，回收率令人满意。

  DOI：

  10.1016/j.electacta.2019.135117

文献信息

• [EN] NITROGEN-CONTAINING ORGANOSILICON COMPOUND, METHOD OF MANUFACTURE, AND METHOD OF TREATING SURFACES<br/>[FR] COMPOSE ORGANOSILICIE CONTENANT DE L'AZOTE, PROCEDE DE PRODUCTION ET PROCEDE DE TRAITEMENT DE SURFACES
  申请人：DOW CORNING TORAY SILICONE

  公开号：WO2004087719A1

  公开（公告）日：2004-10-14

  A new nitrogen-containing organosilicon compound contains tertiary amine groups and carbonyl groups wherein the tertiary amine groups are selected from R1R2N- (where R1 and R2 are the same or different univalent hydrocarbon groups of 1-15 carbon atoms), alicyclic amino groups, or heterocyclic amino groups containing in their rings one or more tertiary amine groups.

  一种新的含氮有机硅化合物包含三级胺基团和羰基团，其中三级胺基团选自R1R2N-（其中R1和R2是1-15个碳原子的相同或不同的一价碳氢基团）、脂环氨基团，或在其环中含有一个或多个三级胺基团的杂环氨基团。
• OPTICAL DEVICE WITH ANTISTATIC PROPERTY
  申请人：Klun Thomas P.

  公开号：US20120288675A1

  公开（公告）日：2012-11-15

  An optical device having a first optical member, a second optical member, and an antistatic layer disposed between the first optical member and the second optical member wherein the antistatic layer contains the reaction product of a mixture comprising at least one polymerizable onium salt having an anion and at least one non-onium polymerizable monomer, oligomer, or polymer.

  一种光学装置，包括第一光学元件、第二光学元件和位于第一光学元件和第二光学元件之间的抗静电层，其中抗静电层包含至少一个可聚合的离子型盐及至少一个非离子型可聚合单体、低聚物或聚合物的混合物的反应产物。
• PARTICLES FOR ELECTROPHORETIC DISPLAYS
  申请人：Merck Patent GmbH

  公开号：US20150129817A1

  公开（公告）日：2015-05-14

  This invention relates to particles comprising a pigment core particle encapsulated by a polymer, a process for their preparation, electrophoretic fluids comprising such particles, and electrophoretic display devices comprising such fluids.

  本发明涉及一种由聚合物包覆的颜料核心颗粒组成的粒子，其制备过程，包含这些粒子的电泳流体以及包含这些流体的电泳显示设备。
• Hydrophilic interpolymers of acrylic acid and an olefin or a styrene
  申请人：The B.F. GOODRICH Company

  公开号：EP0047009A1

  公开（公告）日：1982-03-10

  Highly water absorbent polymers are obtained by polymerizing 70 to 93 weight percent of acrylic acid and 7 to 30 weight percent of a comonomer selected from a-olefins having 6 to 18 carbon atoms, styrene and substituted styrenes. The polymerization can be carried out in the presence of a free radical catalyst in which case the polymer is thereafter preferably neutralized with a base. Alternatively, carboxylic groups are neutralized prior to polymerization by subjecting the monomer mixture either to radiation or to UV light in the presence of a photoinitiator. Such polymers are useful in the manufacture of articles which absorb water or body fluids.

  高吸水性聚合物是由 70 至 93 重量百分比的丙烯酸和 7 至 30 重量百分比的共聚单体聚合而成，共聚单体选自具有 6 至 18 个碳原子的 a-烯烃、苯乙烯和取代的苯乙烯。聚合反应可在自由基催化剂存在下进行，在这种情况下，聚合物随后最好用碱中和。或者，在聚合之前，先将单体混合物置于有光引发剂存在的辐射或紫外线下，使羧基中和。这种聚合物可用于制造吸水或体液的物品。
• Uv curable coatings containing oxalanilide stabilizers, method of curing; and coated substrates therefrom
  申请人：PPG INDUSTRIES, INC.

  公开号：EP0333008A2

  公开（公告）日：1989-09-20

  Disclosed is a coating composition which crosslinks upon exposure to ultraviolet radiation to produce a transparent coating. The coating composition comprises: (A) from 4 to 10 percent of an oxalanilide ultraviolet light (UV) stabilizer dissolved in the coating composition, the UV stabilizer corresponding to the formula in which R is C₆₋₂₂ alkyl or C₆₋₂₂ alkoxy, R₁ and R₂ are independently hydrogen, C₁₋₈ alkyl, C₁₋₁₂ alkoxy, C₁₋₁₂ alkylthio, phenoxy or phenylthio, provided that R₁ and R₂ may not both be selected from alkylthio, phenoxy and phenylthio, and R₃ is hydrogen or C₁₋₈ alkyl; (B) from 20 to 80 percent of a radiation sensitive monomer having at least two addition polymerizable unsaturated bonds; (C) from 0.1 to 5.0 percent of a photopolymerization initiator; and (D) from 80 to 20 percent of an acrylic addition polymer having at least one amino group and having a number average molecular weight of about 8,000 - 70,000, the addition polymer being derived from a mixture of copolymerizable ethylenically unsaturated monomers containing a monomeric ethylenically unsaturated amine. The percentage of components (A), (B), (C) and (D) are by weight based on nonvolatile components (i.e., solids) of the coating composition. Also disclosed is a method of coating comprising: (I) applying to the metallized surface of a metallized, plastic substrate a film of the coating composition of the invention and (II) curing the film by exposing it to ultraviolet radiation. Also disclosed is a metallized plastic substrate having directly adhered to the metallized surface thereof, a transparent, crosslinked film produced by the method of the invention.

  本发明公开了一种涂料组合物，该组合物在暴露于紫外线辐射时会发生交联，从而产生透明涂层。该涂料组合物包括： (A) 4%至 10%的草酰苯胺紫外线（UV）稳定剂溶解在涂料组合物中，该 UV 稳定剂对应于式 其中 R 是 C₆₋₂₂ 烷基或 C₆₋₂₂ 烷氧基，R₁ 和 R₂ 独立地是氢、C₁₋₈ 烷基、C₁₋₁₂ 烷氧基、C₁₋₁₂ 烷硫基、苯氧基或苯硫基、苯氧基或苯硫基，但 R₁ 和 R₂ 不能同时选自烷基硫基、苯氧基和苯硫基，且 R₃ 是氢或 C₁₋₈ 烷基；(B) 20%至 80%的辐射敏感单体，该单体具有至少两个可加成聚合的不饱和键； (C) 0.1%至 5.0%的光聚合引发剂；以及 (D) 80%至 20%的丙烯酸加成聚合物，该加成聚合物具有至少一个氨基，其平均分子量约为 8,000 - 70,000，该加成聚合物来自含有单体乙烯基不饱和胺的可共聚乙烯基不饱和单体的混合物。组分 (A)、(B)、(C) 和 (D) 的重量百分比是基于涂料组合物的非挥发性组分（即固体）。 还公开了一种涂布方法，包括：(I) 在金属化塑料基材的金属化表面上涂布本发明涂料组合物薄膜；(II) 将薄膜置于紫外线辐射下固化。 本发明还公开了一种金属化塑料基材，其金属化表面直接附着一层用本发明方法制得的透明交联薄膜。