9-(4-methoxyphenyl)-3,4,6,7-tetrahydro-3,6-diphenyl-2H-xanthene-1,8(5H,9H)-dione | 1229039-62-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 9-(4-methoxyphenyl)-3,4,6,7-tetrahydro-3,6-diphenyl-2H-xanthene-1,8(5H,9H)-dione
• 英文别名: 9-(4-methoxyphenyl)-3,6-diphenyl-3,4,5,6,7,9-hexahydro-2H-xanthene-1,8-dione
• CAS: 1229039-62-6
• 化学式: C₃₂H₂₈O₄
• 分子量: 476.572
• InChiKey: CQYARGWLFBAYIH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  36
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  5-phenyl-cyclohexane-1,3-dione 、 4-甲氧基苯甲醛 在 nano-zirconia-supported on sulfonic acid 作用下， 以 neat (no solvent) 为溶剂， 反应 1.9h， 以91%的产率得到9-(4-methoxyphenyl)-3,4,6,7-tetrahydro-3,6-diphenyl-2H-xanthene-1,8(5H,9H)-dione
  参考文献：
  名称：

  Nano-zirconia as an excellent nano support for immobilization of sulfonic acid: a new, efficient and highly recyclable heterogeneous solid acid nanocatalyst for multicomponent reactions

  摘要：

  报告了一种新型的、高效的、可回收的纳米催化剂——纳米氧化锆支撑的磺酸，用于合成多组分反应。

  DOI：

  10.1039/c5nj02430g

文献信息

• TiO₂-coated magnetite nanoparticle-supported sulfonic acid as a new, efficient, magnetically separable and reusable heterogeneous solid acid catalyst for multicomponent reactions
  作者：Ali Amoozadeh、Sanaz Golian、Salman Rahmani

  DOI：10.1039/c5ra06515a

  日期：——

  TiO₂-coated magnetite nanoparticles-supported sulfonic acid (nano-Fe₃O₄–TiO₂–SO₃H (n-FTSA)) is synthesized by the immobilization of –SO₃H groups on the surface of nano-Fe₃O₄–TiO₂.

  TiO₂涂覆的磁铁矿纳米颗粒支撑磺酸（纳米Fe₃O₄–TiO₂–SO₃H (n-FTSA)）是通过将-SO₃H基团固定在纳米Fe₃O₄–TiO₂表面合成的。
• Nano-WO 3 -supported sulfonic acid: New, efficient and high reusable heterogeneous nano catalyst
  作者：Ali Amoozadeh、Salman Rahmani

  DOI：10.1016/j.molcata.2014.09.020

  日期：2015.1

  Nano-WO3-supported sulfonic acid [n-WO3-SO3H (n-WSA)] is easily prepared from the reaction of nano WO3 with chlorosulfonic acid as sulfonating agent. This new catalyst is characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), FT-IR spectroscopy, thermal gravimetric analysis (TGA), pH analysis and Hammett acidity function. Nano-WO3-supported sulfonic acid is used as an efficient and recyclable catalyst for some organic reactions such as synthesis of 1,8-dioxo-octahydroxanthene, tetrahydrobenzoxanthene and benzimidazolo quinazolinone derivatives. All of the reactions are very fast and the yields are excellent. The used catalyst was easily separated and reused for 10 runs without appreciable loss of its catalytic activity. (C) 2014 Elsevier B.V. All rights reserved.
• Green Synthesis of 1,8-Dioxo-octahydroxanthene Derivatives Using Catalytic Amount of H₂SO₄in Water
  作者：Rui-Hua Wang、Bin Cui、Wen-Tao Zhang、Guang-Fan Han

  DOI：10.1080/00397910903162825

  日期：2010.5.19

  An green and convenient approach to the synthesis of 3,6,9-aryl-1,8-dioxo-1,2,3,4,5,6,7,8-octahydroxanthene derivatives from appropriate aromatic aldehydes and 5-aryl-1,3-cyclo-hexanedione in the presence of two drops of concentrated H2SO4 as a catalyst in water is described. This method provides several advantages such as environmental friendliness, low cost, excellent yields, and simple workup procedure.
• Nano-zirconia as an excellent nano support for immobilization of sulfonic acid: a new, efficient and highly recyclable heterogeneous solid acid nanocatalyst for multicomponent reactions
  作者：Ali Amoozadeh、Salman Rahmani、Mehrnoosh Bitaraf、Fatemeh Bolghan Abadi、Elham Tabrizian

  DOI：10.1039/c5nj02430g

  日期：——

  Nano-zirconia-supported sulfonic acid as a novel, highly efficient and recyclable heterogeneous nanocatalyst is reported for the synthesis of multicomponent reactions.

  报告了一种新型的、高效的、可回收的纳米催化剂——纳米氧化锆支撑的磺酸，用于合成多组分反应。