2,3,6,7-tetrakis(heptyloxy)phenanthrene-9,10-dione | 1426954-30-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2,3,6,7-tetrakis(heptyloxy)phenanthrene-9,10-dione
• 英文别名: 2,3,6,7-Tetraheptoxyphenanthrene-9,10-dione；2,3,6,7-tetraheptoxyphenanthrene-9,10-dione
• CAS: 1426954-30-4
• 化学式: C₄₂H₆₄O₆
• 分子量: 664.967
• InChiKey: OCEAPSDWPMTORS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14
• 重原子数：
  48
• 可旋转键数：
  28
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,3,6,7-tetrakis(heptyloxy)phenanthrene-9,10-dione 在 potassium hydroxide 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 1.5h， 生成
  参考文献：
  名称：

  Fluorogenic Diels–Alder reactions of novel phencyclone derivatives

  摘要：

  With the aim of obtaining fluorogenic Diels-Alder reactions, novel phencyclone derivatives were synthesized. In a short time and under convenient reaction conditions, the formation of Diels-Alder adducts was observed by color-change and up to 33-fold enhancement of fluorescence. The modification of thymidine and deoxycytidine derivatives with a maleimide side chain and their usage in fluorogenic Diels-Alder reaction is also reported. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.01.095
• 作为产物：
  描述：

  1,2-bis-(3,4-diheptoxyphenyl)ethanedione 在 三氟代氧化钒(V) 、 三氟化硼乙醚 作用下， 以 二氯甲烷 为溶剂， 反应 1.0h， 以75%的产率得到2,3,6,7-tetrakis(heptyloxy)phenanthrene-9,10-dione
  参考文献：
  名称：

  Fluorogenic Diels–Alder reactions of novel phencyclone derivatives

  摘要：

  With the aim of obtaining fluorogenic Diels-Alder reactions, novel phencyclone derivatives were synthesized. In a short time and under convenient reaction conditions, the formation of Diels-Alder adducts was observed by color-change and up to 33-fold enhancement of fluorescence. The modification of thymidine and deoxycytidine derivatives with a maleimide side chain and their usage in fluorogenic Diels-Alder reaction is also reported. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.01.095

文献信息

• Fluorogenic Diels–Alder reactions of novel phencyclone derivatives
  作者：Engin Aytac Aydin、Hans-Josef Altenbach

  DOI：10.1016/j.tetlet.2013.01.095

  日期：2013.4

  With the aim of obtaining fluorogenic Diels-Alder reactions, novel phencyclone derivatives were synthesized. In a short time and under convenient reaction conditions, the formation of Diels-Alder adducts was observed by color-change and up to 33-fold enhancement of fluorescence. The modification of thymidine and deoxycytidine derivatives with a maleimide side chain and their usage in fluorogenic Diels-Alder reaction is also reported. (C) 2013 Elsevier Ltd. All rights reserved.