N-(2-ethylhexylglycine) | 67348-21-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-(2-ethylhexylglycine)
• 英文别名: 2-(2-ethylhexylamino)acetic acid；N-(2-Ethylhexyl)glycine
• CAS: 67348-21-4
• 化学式: C₁₀H₂₁NO₂
• 分子量: 187.282
• InChiKey: CBDIGYHWHBLJKB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  49.3
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-(2-ethylhexylglycine) 、 足球烯 、 2,3-二甲氧基苯甲醛 以 邻二氯苯 为溶剂， 反应 2.0h， 以41%的产率得到
  参考文献：
  名称：

  High LUMO energy pyrrolidinofullerenes as promising electron-acceptor materials for organic solar cells

  摘要：

  适当设计的带有电子供体烷氧基团的吡咯烷基富勒烯在有机太阳能电池中表现出增强的VOC和转换效率。

  DOI：

  10.1039/c5tc02509e
• 作为产物：
  描述：

  2-乙基己胺 、 溴乙酸 以 乙醇 、 水 为溶剂， 反应 20.0h， 以68%的产率得到N-(2-ethylhexylglycine)
  参考文献：
  名称：

  High LUMO energy pyrrolidinofullerenes as promising electron-acceptor materials for organic solar cells

  摘要：

  适当设计的带有电子供体烷氧基团的吡咯烷基富勒烯在有机太阳能电池中表现出增强的VOC和转换效率。

  DOI：

  10.1039/c5tc02509e

文献信息

• [EN] ANTI-BACTERIAL COMPOUNDS<br/>[FR] COMPOSES ANTIBACTERIENS
  申请人：GIVAUDAN SA

  公开号：WO2006026875A1

  公开（公告）日：2006-03-16

  Acid compounds of formula (I) wherein Y is selected from O and NH, wherein X is selected from CO and CH2, and wherein R2 is a branched saturated or unsaturated hydrocarbon moiety selected from C7-C15, that are useful as antibacterial or antifungal compounds in consumer products.

  化合物的结构式（I），其中Y选择自O和NH，X选择自CO和CH2，R2选择自C7-C15的支链饱和或不饱和碳氢基团，这些化合物在消费产品中作为抗菌或抗真菌化合物非常有用。
• Pyrrolidino [60] and [70]fullerene homo- and heterodimers as electron acceptors for OPV
  作者：Sule Erten-Ela、Carmen Villegas、Juan Luis Delgado、Nazario Martín

  DOI：10.1039/c4nj01709a

  日期：——

  New homo- and heterodimers involving [60] and [70]fullerenes have been synthesized and used to prepare organic solar cells.

  新的包括[60]和[70]富勒烯的同型和异型二聚体已被合成并用于制备有机太阳能电池。
• Härtbare Polyesterformmassen
  申请人：BASF Aktiengesellschaft

  公开号：EP0271816A2

  公开（公告）日：1988-06-22

  Härtbare Polyesterformmassen, enthaltend ein Gemisch aus A. einem ethylenisch ungesättigten Polyester oder einem endständigen ungesättigten Vinylester, B. copolymerisierbaren Monomeren, C. faserförmigen Verstärkungsmitteln D. pulverförmigen Füllstoffen, E. organischen Radikalinitiatoren, F. einem Viskositätserniedriger, G. üblichen Zusatzstoffen. Der Viskositätserniedriger ist ein tertiäres oder sekundäres Amin, das eine langkettige Alkyl- oder Acylgruppe sowie eine Carboxylgruppe trägt.

  可固化聚酯模塑组合物，含有以下混合物 A. 乙烯基不饱和聚酯或末端不饱和乙烯基酯、 B. 可共聚单体 C. 纤维状增强剂 D. 粉末状填料 有机自由基引发剂 F. 降粘剂 G. 传统添加剂。 降粘剂是一种带有长链烷基或酰基和羧基的叔胺或仲胺。
• Efficient post-polymerization functionalization of conducting poly(3,4-ethylenedioxythiophene) (PEDOT) via ‘click’-reaction
  作者：Hang-Beom Bu、Günther Götz、Egon Reinold、Astrid Vogt、Sylvia Schmid、José L. Segura、Raúl Blanco、Rafael Gómez、Peter Bäuerle

  DOI：10.1016/j.tet.2010.12.022

  日期：2011.2

  The possibility to functionalize polymers after a successful polymerization process is often an important challenge in macromolecular science. Herein, modified electrodes based on azide-containing potentio-dynamically electropolymerized PEDOT derivatives are reported. This reactive coatings are subsequently modified under mild heterogeneous conditions by copper-catalyzed Huisgen 1,3-dipolar cycloaddition with terminal alkynes, the so-called 'click'-reaction. A series of terminal alkynes have been successfully used for the facile immobilization of neutral, electron-accepting and electron-donating units to the conducting PEDOT with high conversion efficiencies showing the broad scope of the strategy. The route is devoid of the limitations generated by the various steric and electronic impacts of the substituents when attached to the monomer before polymerization. (C) 2010 Elsevier Ltd. All rights reserved.
• Donor−Acceptor Conjugates of Lanthanum Endohedral Metallofullerene and π-Extended Tetrathiafulvalene
  作者：Yuta Takano、M. Ángeles Herranz、Nazario Martín、Shankara Gayathri Radhakrishnan、Dirk M. Guldi、Takahiro Tsuchiya、Shigeru Nagase、Takeshi Akasaka

  DOI：10.1021/ja100665q

  日期：2010.6.16

  Stable donor acceptor conjugates (2, 3) involving an endohedral metallofullerene, La(2) @ l(h)-C(80), and pi-extended tetrathiafulvalene (exTTF) have been synthesized by highly regioselective 1,3-dipolar cycloadditions of exTTF-containing azomethine ylides to the endofullerene, yielding exclusively [5,6] metallofulleropyrrolidines with C(1) symmetry in high yields (68-77%). The cyclic voltammograms (CVs) of the conjugates reveal the redox active character of the system due to the presence of both donor and acceptor groups, that is, exTTF and La(2) @ l(h)-C(80), respectively. Furthermore, the electrochemically reversible character of the endofullerene confirms the presence of the [5,6] adduct. Despite the relatively close proximity between the exTTF and the endohedral metallofullerene (EMF), only a weak electronic interaction was observed in the ground state, as evidenced by absorption spectroscopy and CV measurements of 2 and 3. On the other hand, in the excited state the fast formation of a radical ion-pair state (i.e., 6.0 x 10(10) s(-1)), that is, the reduction of the electron accepting La(2)@C(80) and the oxidation of exTTF, evolves with lifetimes as long as several ns (3.0 x 10(8) s(-1)) in toluene. Transient absorption spectroscopy experiments confirmed these observations.