(E)-1-carbethoxy-2-(triethylsilyl)ethylene | 104014-91-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (E)-1-carbethoxy-2-(triethylsilyl)ethylene
• 英文别名: ethyl (E)-3-(triethylsilyl)propenoate；ethyl (E)-3-triethylsilylacrylate；ethyl (E)-3-triethylsilylprop-2-enoate
• CAS: 104014-91-7
• 化学式: C₁₁H₂₂O₂Si
• 分子量: 214.38
• InChiKey: CWDNYCKUEZQLTQ-MDZDMXLPSA-N

物化性质

• 沸点：
  236.3±23.0 °C(Predicted)
• 密度：
  0.882±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.15
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  三乙基硅烷 、 丙烯酸乙酯 在 十二羰基三钌 作用下， 以 苯 为溶剂， 反应 48.0h， 以12%的产率得到丙酸乙酯
  参考文献：
  名称：

  Single-operation synthesis of vinylsilanes from alkenes and hydrosilanes with the aid of Ru3(CO)12

  摘要：

  DOI：

  10.1021/jo00370a026

文献信息

• Stereodivergent Formation of Alkenylsilanes:syn oranti Hydrosilylation of Alkynes Catalyzed by a Cyclopentadienylcobalt(I) Chelate Bearing a Pendant Phosphane Tether
  作者：Li Yong、Karin Kirleis、Holger Butenschön

  DOI：10.1002/adsc.200606028

  日期：2006.5

  alkynes is catalyzed by the di-tert-butylphosphanylethylcyclopentadienylcobalt chelate 1. While the reaction of internal alkynes exclusively affords syn hydrosilylation products with triethylsilane, the reaction with triethoxysilane shows predominant anti stereoselectivity. Reactions of terminal alkynes are less selective with triethylsilane and result in cyclotrimerization when triethoxysilane is used

  炔烃的氢化硅烷化反应是由二叔丁基膦烷基乙基环戊二烯基钴螯合物1催化的。虽然内部炔烃的反应仅提供与三乙基硅烷的合成氢化硅烷化产物，但与三乙氧基硅烷的反应显示出主要的抗立体选择性。末端炔烃与三乙基硅烷的反应选择性较低，使用三乙氧基硅烷时会导致环三聚。
• Platinum(0) olefin complexes of a bulky terphenylphosphine ligand. Synthetic, structural and reactivity studies
  作者：Laura Ortega-Moreno、Riccardo Peloso、Celia Maya、Andrés Suárez、Ernesto Carmona

  DOI：10.1039/c5cc07308a

  日期：——

  A novel terphenylphosphine PMe2ArDipp2 (1) (Dipp = 2,6-iPr2C6H3) forms stable Pt(0) complexes with ethene and 3,3-dimethylbut-1-ene that behave as a source of the reactive Pt(PMe2ArDipp2) fragment. The complexes are efficient...

  一种新型的三苯膦PMe 2 Ar Dipp2（1）（Dipp = 2,6- i Pr 2 C 6 H 3）与乙烯和3,3-二甲基丁-1-烯形成稳定的Pt（0）络合物，它们作为乙烯的来源反应性Pt（PMe 2 Ar Dipp2）片段。配合物很有效...
• Amination of vinylsilanes and vinylgermanes containing an activated double bond
  作者：V. Dirnens、D.I. Barabanov、E. Liepiņš、L.M. Ignatovich、E. Lukevics

  DOI：10.1016/0022-328x(92)83396-y

  日期：1992.9

  Mixtures of alkyl esters of 2-triethylsilyl(germyl)- and (E)-3-triethylsilyl(germyl)acrylic acids were obtained by hydrosilylation and hydrogermylation of alkyl esters of propiolic acids. Alkyl esters of organosilicon(germanium) β-amino(hydrazino)propionic acids were obtained by amination of the alkyl esters of 2-triethylsilyl(germyl)acrylic acids.

  通过丙酸烷基酯的氢化硅烷化和加氢麦芽糖化反应，获得2-三乙基甲硅烷基（锗烷基）-和（E）-3-三乙基甲硅烷基（锗烷基）丙烯酸的烷基酯的混合物。有机硅（锗）β-氨基（肼基）丙酸的烷基酯是通过对2-三乙基甲硅烷基（锗烷基）丙烯酸的烷基酯进行胺化而获得的。
• Hydrosilylation of alkynes catalysed by platinum on titania
  作者：Francisco Alonso、Robison Buitrago、Yanina Moglie、Javier Ruiz-Martínez、Antonio Sepúlveda-Escribano、Miguel Yus

  DOI：10.1016/j.jorganchem.2010.09.068

  日期：2011.1

  The heterogeneous hydrosilylation of alkynes catalysed by platinum on titania is reported. A variety of hydrosilanes react with both terminal and internal alkynes to furnish the corresponding vinyl silanes in high yields and short reaction times as well as in a regio- and stereoselective manner. The catalyst can be easily recovered and reused in several consecutive cycles. (C) 2010 Elsevier B.V. All rights reserved.
• Single-operation synthesis of vinylsilanes from alkenes and hydrosilanes with the aid of Ru3(CO)12
  作者：Yoshio Seki、Kenji Takeshita、Kazuaki Kawamoto、Shinji Murai、Noboru Sonoda

  DOI：10.1021/jo00370a026

  日期：1986.10