cyclohexenylmethyl acrylate | 132576-38-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: cyclohexenylmethyl acrylate
• 英文别名: cyclohexen-1-ylmethyl prop-2-enoate
• CAS: 132576-38-6
• 化学式: C₁₀H₁₄O₂
• 分子量: 166.22
• InChiKey: NQUSVAQGTYCOGL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  苯膦酸 、 cyclohexenylmethyl acrylate 在 三甲基氯硅烷 、 N,N-二异丙基乙胺 作用下， 以 二氯甲烷 为溶剂， 以69%的产率得到3-[hydroxy(phenyl)phosphinoyl]-2-(2-methylenecyclohexyl)propanoic acid
  参考文献：
  名称：

  A Modular Rearrangement Approach toward Medicinally Relevant Phosphinic Structures

  摘要：

  An unprecedented coupling of a P-C and a C-C bond-forming event in a practical operation was developed to access medicinally relevant phosphinic structures. The strategy relies on an Ireland-Claisen rearrangement triggered by the phospha-Michael addition of silyl phosphonites to allyl acrylates. This protocol was extended to a more versatile three-component variant that utilizes phosphinic acids, acryloyl chlorides, and allylic alcohols as starting materials.

  DOI：

  10.1021/ol902004p
• 作为产物：
  描述：

  3-甲氧基环己烯 、 丙烯酸 、 对甲苯磺酸 、 4-甲氧基苯酚 以 甲苯 为溶剂， 以The CHA was obtained in an amount of 96.5 grams (73% yield)的产率得到cyclohexenylmethyl acrylate
  参考文献：
  名称：

  Radical-curable adhesive compositions, reaction products of which

  摘要：

  本发明涉及一种基于自由基固化的粘合剂组合物，其中包括一个（甲基）丙烯酸酯组合物；一种选自不饱和环状、双环和三环（甲基）丙烯酸酯和环氧化的烷基、环烷基、双环和三环（甲基）丙烯酸酯的共反应剂；以及一种自由基固化诱导组合物。根据本发明的组合物反应产物表现出优异的耐热降解性。

  公开号：

  US06150479A1

文献信息

• A catalytic role of Cu(II) for conjugate addition of grignard reagents. A completely different behavior from organocuprates.
  作者：Youji Aoki、Isao Kuwajima

  DOI：10.1016/s0040-4039(00)88514-7

  日期：1990.1

  Different from lithium dialkylcuprates, Cu(II) catalyzed conjugate addition of Grignard reagents to allylic esters of α,β-unsaturated carboxylates has been effected in the presence of TMS-Cl, and the resulting allyl silyl keteneacetals further undergo rearrangement to afford 2-allyl 3-alkyl carboxylic acids in good yields.

  与二烷基铜酸锂不同，在TMS-Cl的存在下，Cu（II）催化了格氏试剂向α，β-不饱和羧酸酯的烯丙基酯的共轭加成反应，所得的烯丙基甲硅烷基烯酮缩醛进一步进行重排生成2-烯丙基3-烷基羧酸产率高。
• RUBBER COMPOSITION LOWERED IN HEAT BUILD-UP AND ROLLS
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0878503A1

  公开（公告）日：1998-11-18

  A rubber composition having a reduced heat build-up, which comprises (a) 100 wt. parts of an elastomer capable of being crosslinked by an organic peroxide crosslinking agent, (b) 10 - 150 wt. parts of a metal salt of an α,β-ethylenically unsaturated carboxylic acid, (c) 5 to 100 wt. parts of magnesium oxide having a BET specific surface area not larger than 25 m2/g, and (d) 0.1 to 30 wt. parts of an organic peroxide crosslinking agent. A roll having an outer peripheral surface portion composed of a vulcanizate of the rubber composition. The roll has high strengths and reduced heat build-up, and is especially suitable for use under a high load.

  一种可减少热积累的橡胶组合物，其中包括：(a) 100 重量份可被有机过氧化物交联剂交联的弹性体；(b) 10 - 150 重量份的α，β-乙烯基不饱和羧酸的金属盐；(c) 5 - 100 重量份的氧化镁，其 BET 比表面积不大于 25 m2/g；(d) 0.1 - 30 重量份的有机过氧化物交联剂。辊子的外周表面部分由橡胶组合物硫化而成。该辊强度高，热量积聚少，特别适合在高负荷下使用。
• MIXTURE COMPOSITION OF SYNTHETIC RESIN AND RUBBER
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0972798A1

  公开（公告）日：2000-01-19

  The present invention is directed to a polymer blend having improved properties comprising: (A) 90 to 10 % by weight of a thermoplastic or thermosetting resin; and (B) 10 to 90 % by weight of a shear-treated rubber obtained by subjecting a nitrile group-containing highly saturated copolymer rubber to a high-shear treatment in the presence of an anti-oxidant so as to lower the Mooney viscosity of the copolymer rubber by 15 units or more, said shear-treated rubber having a Mooney viscosity of 5 to 135, a molecular weight distribution (Mw/Mn) of 3.0 to 5.0 and a storage stability characterized by that the incremental increase in the Mooney viscosity of said shear-treated rubber during a 30 day storage under an ambient condition in air is not more than 10 units.

  本发明涉及一种具有改进性能的聚合物混合物，它包括(A) 90%至 10%（重量百分比）的热塑性或热固性树脂；以及 (B) 10%至 90%（重量百分比）的剪切处理过的橡胶，该橡胶是通过在抗氧化剂存在下对含有腈基的高饱和共聚橡胶进行高剪切处理，从而使共聚橡胶的门尼粘度降低 15 个单位或更多，所述剪切处理过的橡胶的门尼粘度为 5 至 135，分子量分布（Mw/Mn）为 3.经剪切处理的橡胶的门尼粘度为 5 至 135，分子量分布（Mw/Mn）为 3.0 至 5.0，贮存稳定性为在空气中环境条件下贮存 30 天期间，经剪切处理的橡胶的门尼粘度增量不超过 10 个单位。
• OXYGEN-ABSORBING RESIN COMPOSITION, OXYGEN-ABSORBING MOLDED ARTICLE, PACKAGING MATERIAL AND PACKAGING CONTAINER
  申请人：Zeon Corporation

  公开号：EP2128197A1

  公开（公告）日：2009-12-02

  [PROBLEMS] To provide an oxygen-absorbing resin composition which does not require incorporating a transition metal compound thereinto, which has excellent oxygen absorbability at room temperature, which releases little smell on oxygen absorption, and which can produce a shaped article having excellent transparency; an oxygen-absorbing shaped article comprising the oxygen-absorbing resin composition; and a packaging material and a packaging container each comprised of the shaped article. [MEANS FOR SOLVING PROBLEMS] Disclosed is an oxygen-absorbing resin composition comprising a resin composition (A) that comprises an oxygen-absorbing resin (A1) having a cycloene structure in the molecule and a softener (A2) and has a glass transition temperature of from -30°C to +30°C, as dispersed in a resin (B) having an oxygen permeability of from 100 cc to 500 cc 20 µm/m2·day·atom (25°C, 65 % RH). The softening agent (A2) is preferably liquid paraffin or polybutene. The resin (B) is preferably a (terephthalic acid)/(cyclohexanedimethanol) copolymer polyester or a polyamide resin.

  问题 提供一种吸氧树脂组合物，该组合物无需在其中加入过渡金属化合物，在室温下具有极佳的吸氧性能，吸氧时释放的气味极少，并且可以生产出具有极佳透明度的异型制品；一种包含该吸氧树脂组合物的吸氧异型制品；以及由该异型制品组成的包装材料和包装容器。 [解决问题的方法］ 本发明公开了一种吸氧树脂组合物，它包括一种树脂组合物 (A)，该树脂组合物包括分子中具有环烯结构的吸氧树脂 (A1) 和一种软化剂 (A2)，其玻璃化转变温度为 -30°C 至 +30°C，该树脂组合物分散在一种树脂 (B) 中，该树脂 (B) 的氧气渗透率为 100 cc 至 500 cc 20 µm/m2-day-atom (25°C, 65 % RH)。软化剂（A2）最好是液体石蜡或聚丁烯。树脂 (B) 最好是（对苯二甲酸）/（环己烷二甲醇）共聚聚酯或聚酰胺树脂。
• Thermally resistant anaerobically curable compositions
  申请人：HENKEL IP & HOLDING GMBH

  公开号：US10100226B2

  公开（公告）日：2018-10-16

  The present invention relates to anaerobically curable compositions demonstrating resistance to elevated temperature conditions.

  本发明涉及可耐受高温条件的厌氧固化组合物。