5,7-Ditert-butyl-3,3-dimethylphosphindole | 239449-79-7

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 5,7-Ditert-butyl-3,3-dimethylphosphindole
• CAS: 239449-79-7
• 化学式: C₁₈H₂₇P
• 分子量: 274.386
• InChiKey: JUMGNCMUKZWKNT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.61
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  5,7-Ditert-butyl-3,3-dimethylphosphindole 在 硫酸 作用下， 生成 5,7-ditert-butyl-3,3-dimethyl-2H-phosphindole 1-oxide
  参考文献：
  名称：

  Generation and reactivity of a 3H-phosphaindene: the first 3H-phosphole

  摘要：

  By gas-phase pyrolysis over a solid base the title compound has been prepared as a 1:1 mixture with its hydration product and characterised spectroscopically; the hindered C=P double bond is surprisingly unreactive. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)00999-5
• 作为产物：
  描述：

  2,4,6-tri-t-butylphenylphosphonous dichloride 在 吡啶 、 sodium carbonate 作用下， 反应 1.0h， 生成 5,7-Ditert-butyl-3,3-dimethylphosphindole
  参考文献：
  名称：

  Generation and reactivity of a 3H-phosphaindene: the first 3H-phosphole

  摘要：

  By gas-phase pyrolysis over a solid base the title compound has been prepared as a 1:1 mixture with its hydration product and characterised spectroscopically; the hindered C=P double bond is surprisingly unreactive. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)00999-5

文献信息

• Aitken, R. Alan; Cowley, Alan H.; Gabbai, Francois P., Phosphorus, Sulfur and Silicon and the Related Elements, 1996, vol. 111, p. 182
  作者：Aitken, R. Alan、Cowley, Alan H.、Gabbai, Francois P.、Masamba, Wayiza

  DOI：——

  日期：——
• Generation and reactivity of a 3H-phosphaindene: the first 3H-phosphole
  作者：R.Alan Aitken、P.Nicholas Clasper、Neil J. Wilson

  DOI：10.1016/s0040-4039(99)00999-5

  日期：1999.7

  By gas-phase pyrolysis over a solid base the title compound has been prepared as a 1:1 mixture with its hydration product and characterised spectroscopically; the hindered C=P double bond is surprisingly unreactive. (C) 1999 Elsevier Science Ltd. All rights reserved.