4-(octyloxy)benzophenone | 35820-92-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(octyloxy)benzophenone
• 英文别名: (4-(Octyloxy)phenyl)(phenyl)methanone；(4-octoxyphenyl)-phenylmethanone
• CAS: 35820-92-9
• 化学式: C₂₁H₂₆O₂
• 分子量: 310.436
• InChiKey: WTJWFFXZUSGGKB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  23
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-(octyloxy)benzophenone 在 正丁基锂 、 三溴化硼 、 对甲苯磺酸 作用下， 以 四氢呋喃 、 正己烷 、 二氯甲烷 、 甲苯 为溶剂， 反应 13.5h， 生成 1-（4-羟基苯）-1,2,2-三苯乙烯
  参考文献：
  名称：

  Optical Properties and Photo-Oxidation of Tetraphenylethene-Based Fluorophores

  摘要：

  AbstractWe report the optical properties of tetraphenylethene (TPE) and other TPE derivatives functionalised with an octyl group (TPE‐OCT) and polyethyleneglycol group (TPE‐PEG) in the side chain. We compared TPE‐OCT and TPE‐PEG with TPE in both organic solvents and under aqueous conditions. All materials exhibit aggregation‐induced emission, however, uncommonly, TPE‐PEG seems to aggregate in aqueous solution with enhanced photoluminescence quantum efficiency (PLQE) relative to that in organic solvents. All three materials can be photo‐oxidised in solution to their diphenylphenanthrene derivative by irradiation with UV light (at both ≈1 and ≈5 mW cm−2), with a subsequent enhancement in PL efficiency. The electron‐donating ether group increases the rate of oxidation relative to bare TPE and also photo‐oxidation was shown to be solvent and concentration dependent. Finally, photo‐oxidation was also demonstrated in the aggregate state.

  DOI：

  10.1002/chem.201202715
• 作为产物：
  描述：

  1-溴辛烷 、 4-羟基-二苯甲酮 在 potassium carbonate 作用下， 以 丙酮 为溶剂， 反应 24.0h， 以94%的产率得到4-(octyloxy)benzophenone
  参考文献：
  名称：

  荧光无溶剂纤维素离子络合物对耐热发光涂料材料

  摘要：

  通过羧甲基纤维素与含四苯基乙烯的铵表面活性剂之间的静电制备，开发了一种新型的荧光纤维素离子络合物，该络合物具有热致液晶特性。在紫外激发下，由于表面活性剂的聚集诱导发射特性，所报道的无溶剂纤维素材料发出明亮的发光和优异的量子产率。展示了在高温和水性条件下显示出良好的热稳定性、防水性和初步标记和涂层的新复合物。

  DOI：

  10.1016/j.dyepig.2022.110611

文献信息

• Chemiluminescence Resonance Energy Transfer Efficiency and Donor–Acceptor Distance: from Qualitative to Quantitative
  作者：Jinhui Lou、Xiaofang Tang、Haoke Zhang、Weijiang Guan、Chao Lu

  DOI：10.1002/anie.202102999

  日期：2021.6

  Since its birth in 1967, the utilization of chemiluminescence resonance energy transfer (CRET) has made substantial progress in a variety of fields for its unique features. However, the quantitative relationship between CRET efficiency and donor–acceptor distance has not yet been determined owing to the difficulty in designing the variable lengths between chemiluminescent donors and acceptors. Herein

  自1967年诞生以来，化学发光共振能量转移（CRET）的利用以其独特的功能在各个领域都取得了长足的进步。但是，由于难以设计化学发光供体和受体之间的可变长度，因此尚未确定CRET效率与供体-受体距离之间的定量关系。本文中，我们合成了三种具有聚集诱导发射（AIE）特征的四苯基乙烯（TPE）固定的阳离子表面活性剂。首次定量证明了CRET效率与鲁米诺供体与TPE受体之间距离的六次方成反比。在该贡献中公开的细节提供了有力的证据，表明CRET遵循Förster共振理论。
• Optically anisotropic material, process for producing it, and retardation plate and liquid crystal display device using same
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0617111A1

  公开（公告）日：1994-09-28

  By using an optically anisotropic film having the optical axis substantially parallel to the normal line of the film and comprising a polymer of a liquid crystal oligomer having positive anisotropy of refractive index and showing nematic or smectic phase, or by lamining the optically anisotropic film and a transparent or semitransparent polymer film, or by combining the optically anisotropic film with a uniaxially oriented retardation film, it is possible to obtain a composite retardation plate with a large viewing angle, and this retardation plate can be applied to a liquid crystal display device.

  光学各向异性薄膜的光轴与薄膜的法线基本平行，由具有正各向异性折射率的液晶低聚物聚合物组成，并显示向列相或共晶相、或将光学各向异性薄膜与透明或半透明聚合物薄膜层叠，或将光学各向异性薄膜与单轴取向的缓凝薄膜结合，可获得具有大视角的复合缓凝板，这种缓凝板可应用于液晶显示设备。
• CURABLE COMPOSITION AND CURED PRODUCT THEREOF
  申请人：Showa Denko K.K.

  公开号：EP2415794A1

  公开（公告）日：2012-02-08

  The present invention provides a curable composition having a proper viscosity and excellent handling properties, and a cured product that is obtainable by curing the curable composition and has excellent transparency, heat resistance and resistance to environment and a low Abbe's number, and further can effectively decrease chromatic aberration by the combined use with a material having a high Abbe's number. The curable composition is characterized by comprising (a) silica fine particles, (b) a (meth)acrylate compound having at least two ethylenic unsaturated groups and having no ring structure, (c) a (meth)acrylate compound having at least two ethylenic unsaturated groups and having an aromatic ring structure and (d) a polymerization initiator, wherein the silica particles (a) are surface treated by a specific silane compound (e) and a specific silane compound (f).

  本发明提供了一种具有适当粘度和优异操作性能的可固化组合物，以及一种通过固化该可固化组合物而获得的固化产品，该固化产品具有优异的透明度、耐热性和耐环境性以及较低的阿贝数，并且通过与具有较高阿贝数的材料结合使用，可进一步有效降低色差。 该可固化组合物的特点是由以下部分组成：(a) 二氧化硅细颗粒；(b) 具有至少两个乙烯基不饱和基团且无环状结构的（甲基）丙烯酸酯化合物；(c) 具有至少两个乙烯基不饱和基团且具有芳香环状结构的（甲基）丙烯酸酯化合物；(d) 聚合引发剂，其中二氧化硅颗粒（a）由特定硅烷化合物（e）和特定硅烷化合物（f）进行表面处理。
• INORGANIC NON-METAL MINERAL COMPOSITE MATERIAL CARRYING TITANIUM DIOXIDE LAYER, AND PREPARATION PROCESS AND USE THEREOF
  申请人：Shanghai World-Prospect Chemtech Co. Ltd.

  公开号：EP2752239A1

  公开（公告）日：2014-07-09

  The invention discloses composite materials, comprising an inorganic nonmetallic mineral as a support and a nanotitania layer loaded on the support, wherein the layer is comprised of a plurality of titania nanospheres, and the titania nanosphere is comprised of a plurality of nanotitania single particles. The invention also discloses composite materials further comprising one or more functional layers loaded on the nanotitania layer. The above composite materials may not only take advantage of the high refractive index and the high covering power of the nanotitania layer, but also make use of the good photocatalytic activity of the small single nanoparticles. Therefore, the application fields of the composite materials are expanded, and the comprehensive performances of the final products are improved. Furthermore, the composite materials can be more readily coated by other functional layer(s) to prepare functionally strengthened or multi-functional composite materials. The invention also discloses methods for preparing the composite materials, which may be carried out with a simple process at low cost. The composite materials of the invention have wide applications and may be used as an additive with good compatibility in various industrial fields.

  本发明公开了复合材料，包括作为支撑物的无机非金属矿物和负载在支撑物上的纳米二氧化钛层，其中该层由多个二氧化钛纳米球组成，二氧化钛纳米球由多个纳米二氧化钛单颗粒组成。本发明还公开了复合材料，进一步包括负载在纳米二氧化钛层上的一个或多个功能层。上述复合材料不仅可以利用纳米二氧化钛层的高折射率和高遮盖力，还可以利用单个纳米小颗粒良好的光催化活性。因此，复合材料的应用领域得到了拓展，最终产品的综合性能也得到了提高。此外，复合材料还可以更方便地包覆其他功能层，制备功能强化或多功能复合材料。本发明还公开了制备复合材料的方法，其工艺简单，成本低廉。本发明的复合材料具有广泛的应用前景，可作为添加剂以良好的兼容性应用于各个工业领域。
• CURABLE COMPOSITION AND APPLICATION THEREFOR
  申请人：Showa Denko K.K.

  公开号：EP2813521A1

  公开（公告）日：2014-12-17

  Provided is a curable composition with one or more properties improved as compared with conventional curable compositions, the improved properties being selected from transparency and heat resistance of a cured product formed from the compostion and storage stability, handling property and moldability of the composition. The curable composition includes (A) silica fine particles surface-modified with at least one silane compound including at least (A1) a polymerizable silane compound of the general formula (1), (B) a (meth)acrylate compound, and (C) a polymerization initiator,         SiR1aR2bRc(OR)4-a-b-c     (1) wherein R1 is a C11-20 hydrocarbon group having an ethylenic unsaturated group, or a substituted C11-20 hydrocarbon group having an ethylenic unsaturated group and having an ether bond and/or an ester bond; R2 is a hydrogen atom or a C1-4 hydrocarbon group; R3 is a halogen atom; R4 is a hydrogen atom or a C1-10 hydrocarbon group; a is an integer of 1 to 3; b is an integer of 0 to 2; c is an integer of 0 to 3; the sum of a and b is 1 to 3; the sum of a, b and c is 1 to 4.

  本发明提供了一种可固化组合物，与传统的可固化组合物相比，该组合物的一种或多种特性得到了改善，改善的特性选自该组合物形成的固化产品的透明度和耐热性，以及该组合物的储存稳定性、处理特性和成型性。可固化组合物包括：(A)用至少一种硅烷化合物进行表面改性的二氧化硅微粒，该硅烷化合物至少包括(A1)通式(1)的可聚合硅烷化合物，(B)(甲基)丙烯酸酯化合物和(C)聚合引发剂、 SiR1aR2bRc(OR)4-a-b-c (1) 其中 R1 是具有乙烯基不饱和基团的 C11-20 烃基，或具有乙烯基不饱和基团并具有醚键和/或酯键的取代 C11-20 烃基；R2 是氢原子或 C1-4 烃基；R3 是卤素原子； R4 是氢原子或 C1-10 烃基； a 是 1 至 3 的整数； b 是 0 至 2 的整数； c 是 0 至 3 的整数； a 和 b 之和是 1 至 3； a、b 和 c 之和是 1 至 4。