2-(甲基氨基)乙基丙-2-烯酸酯 | 7709-08-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2-(甲基氨基)乙基丙-2-烯酸酯
• 英文名称: 2-(methylamino)ethyl acrylate
• 英文别名: 2-(methylamino)ethyl prop-2-enoate
• CAS: 7709-08-2
• 化学式: C₆H₁₁NO₂
• 分子量: 129.159
• InChiKey: ULEVTQHCVWIDPC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  9
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  38.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-(2,3-epoxypropoxy)benzophenone 、 2-(甲基氨基)乙基丙-2-烯酸酯 在 乙醇 作用下， 反应 4.0h， 以56%的产率得到2-[[3-(4-benzoylphenoxy)-2-hydroxypropyl]-methylamino]ethyl prop-2-enoate
  参考文献：
  名称：

  可聚合光敏单体、基于其的光敏聚合物及生物材料表面改性方法

  摘要：

  本发明涉及一种可聚合光敏单体、基于其的光敏聚合物及生物材料表面改性方法。本发明通过合成一种可聚合光敏单体，将其与亲水粘附性单体和活性单体进行聚合得到一种新结构的光敏聚合物，以此作为生物材料表面和生物活性分子间的“桥梁”，可以实现将生物活性分子共价负载到材料表面，增强材料的生物相容性。

  公开号：

  CN110835307B

文献信息

• Hydroxylamine esters as polymerization initiators
  申请人：——

  公开号：US20030216494A1

  公开（公告）日：2003-11-20

  The invention relates to novel cyclic and open-chain hydroxylamine esters and polymerizable compositions comprising these hydroxylamine esters and an ethylenically unsaturated monomer or oligomer. The invention also relates to use as polymerization initiators and to the use of known hydroxylamine esters selected from the group consisting of HALS compounds and the novel hydroxylamine esters for the controlled degradation of polypropylene and for achieving a controlled increase in the molecular weight of polyethylene.

  该发明涉及新型环状和开链羟胺酯以及包括这些羟胺酯和乙烯基不饱和单体或寡聚物的可聚合组合物。该发明还涉及用作聚合引发剂以及用于控制聚丙烯降解和实现聚乙烯分子量控制增加的已知羟胺酯，所述羟胺酯来自HALS化合物和新颖羟胺酯的组合。
• Emulsion composition of modified polypropylene
  申请人：Ozaki Hiroyuki

  公开号：US20070004847A1

  公开（公告）日：2007-01-04

  An emulsion composition of a modified polypropylene. It can have exceedingly improved emulsion stability because the modified polypropylene used has extremely high solubility in solvents and is easily emulsifiable. The modified-polypropylene emulsion composition comprises water and a modified polypropylene dispersed and emulsified therein, and is characterized in that the modified polypropylene has a racemic diad content [r] of 0.12 to 0.88 and has hydrophilic functional groups in a number of 0.5 or larger on the average per molecular chain of the polypropylene.

  一种改性聚丙烯的乳液组合物。它可以具有极大改善的乳液稳定性，因为所使用的改性聚丙烯在溶剂中具有极高的溶解度，并且易于乳化。改性聚丙烯乳液组合物包括水和分散和乳化其中的改性聚丙烯，其特征在于改性聚丙烯的嘧啶二聚物含量[r]为0.12至0.88，并且在聚丙烯的每条分子链上平均有0.5个或更多的亲水性功能基团。
• [EN] FLUORENE DERIVATIZED MONOMERS AND POLYMERS FOR VOLUME BRAGG GRATINGS<br/>[FR] MONOMÈRES ET POLYMÈRES DÉRIVÉS DE FLUORÈNE POUR DES RÉSEAUX DE BRAGG VOLUMIQUES
  申请人：FACEBOOK TECH LLC

  公开号：WO2020227264A1

  公开（公告）日：2020-11-12

  The disclosure provides recording materials include fluorene derivatized monomers and polymers for use in volume Bragg gratings, including, but not limited to, volume Bragg gratings for holography applications. Several fluorene structures are disclosed: simply substituted fluorenes, cardo-fluorenes, and spiro-fluorenes. Fluorene derivatized polymers in Bragg gratings applications lead to materials with higher refractive index, low birefringence, and high transparency. Fluorene derivatized monomers/polymers can be used in any volume Bragg gratings materials, including two-stage polymer materials where a matrix is cured in a first step, and then the volume Bragg grating is written by way of a second curing step of a monomer.

  本公开提供的记录材料包括衍生自芴的单体和聚合物，用于体积布拉格光栅，包括但不限于用于全息应用的体积布拉格光栅。公开了几种芴结构：简单取代的芴，卡多芴和螺旋芴。在布拉格光栅应用中，衍生自芴的聚合物导致具有较高折射率，低双折射和高透明度的材料。衍生自芴的单体/聚合物可用于任何体积布拉格光栅材料，包括两阶段聚合物材料，在第一步中固化基体，然后通过第二次固化单体的方式编写体积布拉格光栅。
• POLYVINYL ULTRAVIOLET LIGHT ABSORBERS FOR PERSONAL CARE
  申请人：Maleski Robert Joseph

  公开号：US20090185988A1

  公开（公告）日：2009-07-23

  UV-absorbing polymers and copolymers suitable for Composition into sunscreens for the protection of human skin. The UV-absorbing chromophoric monomers chosen are simple and easily synthesized. With the correct choice of chromophoric monomer or mixture of monomers, protection against UV-A radiation or against both UV-A and UV-B radiation can be achieved. With the correct choice of comonomer, copolymers produced as aqueous latex emulsions or as Polyethylene Glycol solutions can also be achieved.

  适用于组成防晒霜以保护人类皮肤的UV吸收聚合物和共聚物。选择的UV吸收色团单体简单易合成。通过正确选择色团单体或混合物，可实现对UV-A辐射或对UV-A和UV-B辐射的保护。通过正确选择共聚单体，也可以生产水乳液乳胶或聚乙二醇溶液中的共聚物。
• Stimuli-Responesive Hydrogel,Production Method Of Stimuli-Responsive Hydrogel,And Polymer Actuator Using Stimuli-Responsive Hydrogel
  申请人：Ito Hidetoshi

  公开号：US20070196492A1

  公开（公告）日：2007-08-23

  A stimuli-responsive polymer hydrogel is provided. The stimuli-responsive polymer hydrogel has a high breaking strength and excellent stimuli-responsive function and is highly stable with elapse of time. The stimuli-responsive polymer hydrogel is capable of gelating as a result of absorbing and swelling with water and capable of changing its degree of swelling and/or volume in response to a stimulus and contains a water-insoluble polymer as a phase separation structure.

  提供了一种刺激响应性高分子水凝胶。该刺激响应性高分子水凝胶具有高断裂强度和优异的刺激响应功能，并且随着时间的流逝具有高度的稳定性。该刺激响应性高分子水凝胶能够吸收和膨胀水分以形成凝胶，并能够对刺激做出响应而改变其膨胀程度和/或体积，并包含一种水不溶性高分子作为相分离结构。