dicyclohexyl itaconate | 15700-62-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: dicyclohexyl itaconate
• 英文别名: methylene-succinic acid dicyclohexyl ester；Methylen-bernsteinsaeure-dicyclohexylester；Dicyclohexyl 2-methylidenebutanedioate
• CAS: 15700-62-6
• 化学式: C₁₇H₂₆O₄
• 分子量: 294.391
• InChiKey: GFHMGSFDHKDJSG-UHFFFAOYSA-N

物化性质

• 沸点：
  391.0±17.0 °C(Predicted)
• 密度：
  1.07±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.76
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-碘苯胺 、 dicyclohexyl itaconate 在 palladium diacetate sodium acetate 、 三苯基膦 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 20.0h， 以75%的产率得到cyclohexyl 2-(2-oxo-1H-quinolin-3-yl)acetate
  参考文献：
  名称：

  An approach for quinolines via palladium-catalyzed Heck coupling followed by cyclization

  摘要：

  2-Iodoaniline reacts with alpha,beta-unsaturated carbonyl compounds in DMF at 100 degrees C in the presence of a catalytic amount of a palladium catalyst along with a base to afford the corresponding quinolones or quinolines in moderate to good yields. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.04.001
• 作为产物：
  描述：

  甲基丁二酸 、 环己醇 生成 dicyclohexyl itaconate
  参考文献：
  名称：

  聚氯乙烯树脂的增塑剂

  摘要：

  DOI：

  10.1021/ie50548a035

文献信息

• [EN] SURFACTANTS<br/>[FR] TENSIOACTIFS
  申请人：AMYRIS INC

  公开号：WO2012103156A1

  公开（公告）日：2012-08-02

  This application relates to derivatives of hydrocarbon terpenes (e.g., myrcene or farnesene), to methods of making the derivatives, and to the use of the derivatives as surfactants.

  这个应用涉及到碳氢化合物萜类化合物（例如，肉豆蔻烯或芬尼烯）的衍生物，制备这些衍生物的方法，以及将这些衍生物用作表面活性剂的用途。
• Acid-degradable resin compositions containing ketene-aldehyde copolymer
  申请人：Sudo Atsushi

  公开号：US20050130057A1

  公开（公告）日：2005-06-16

  It is intended to provide compositions to be used in resists and the like for forming fine patterns with a high sensitivity and a high resolution by increasing the difference in the solubilities between exposed parts and unexposed parts. Acid-degradable compositions contain a polymer having a repeating unit represented by the following general formula (I): wherein R 1 and R 2 independently represent hydrogen atom, halogen atom, C 1-20 hydrocarbon group, a heterocyclic group, a cyano group, a nitro group, C(═O)R 4 group, S(O) n R 4 group, P(═O)(R 4 ) 2 group or M(R 4 ) 3 group; R 3 represents C 1-20 hydrocarbon group or a heterocyclic group: R 4 represents C 1-20 hydrocarbonoxy group, C 1-20 hydrocarbon group, C 1-20 hydrocarbonthio group or mono- or di-C 1-20 hydrocarbonamino group; M represents a silicon, germanium, tin or lead atom; and n is 0, 1 or 2 , and an acid or a compound capable of generating an acid in response to an external stimulus.

  本发明旨在提供用于制备高灵敏度和高分辨率细微图案的抗蚀剂等组合物，通过增加曝光部分和未曝光部分之间的溶解度差异。可降解酸性组合物包含具有以下通式（I）所表示的重复单元的聚合物：其中，R1和R2独立地表示氢原子、卤素原子、C1-20碳氢基团、杂环基团、氰基团、硝基团、C（═O）R4基团、S（O）nR4基团、P（═O）（R4）2基团或M（R4）3基团；R3表示C1-20碳氢基团或杂环基团；R4表示C1-20碳氢氧基团、C1-20碳氢基团、C1-20碳氢硫基团或单烷基或二烷基氨基基团；M表示硅、锗、锡或铅原子；n为0、1或2，以及一种酸或能够响应外部刺激产生酸的化合物。
• Acrylic Acid-Based Polymer and Method of Producing the Same
  申请人：Kubo Hideo

  公开号：US20090111961A1

  公开（公告）日：2009-04-30

  Disclosed are an acrylic acid-based polymer which is a star polymer containing a repeating unit derived from an (α-lower alkyl)acrylic ester represented by formula (I): (wherein R 1 represents a hydrogen atom or a lower alkyl group, and R 2 represents an organic group having a polar group) in an arm portion; an acrylic acid-based polymer containing a repeating unit derived from an poly(α-lower alkyl)acrylic ester and a repeating unit derived from an (α-lower alkyl)acrylic ester represented by formula (I), and a method for producing a polymer through living polymerization, comprising forming an oligomer having a polymerization active end, which is an oligomer higher than an average 1.0-mer and lower than an average 4.0-mer or an average 4.0-mer, and polymerizing using the oligomer having a polymerization active end as an initiating species.

  本发明涉及一种基于丙烯酸的星型聚合物，其包含来自式（I）所表示的（α-较低烷基）丙烯酸酯的重复单元的臂部分；以及一种基于丙烯酸的聚合物，其包含来自聚（α-较低烷基）丙烯酸酯和式（I）所表示的（α-较低烷基）丙烯酸酯的重复单元，并且本发明还提供了通过活性聚合制备聚合物的方法，包括形成具有聚合活性端的寡聚体，该寡聚体高于平均1.0-聚体但低于平均4.0-聚体或平均4.0-聚体，并以具有聚合活性端的寡聚体作为引发物种进行聚合。
• ACRYLIC ACID-BASED POLYMER AND METHOD OF PRODUCING THE SAME
  申请人：Kubo Hideo

  公开号：US20110046333A1

  公开（公告）日：2011-02-24

  Disclosed are an acrylic acid-based polymer which is a star polymer containing a repeating unit derived from an (α-lower alkyl)acrylic ester represented by formula (I): (wherein R 1 represents a hydrogen atom or a lower alkyl group, and R 2 represents an organic group having a polar group) in an arm portion; an acrylic acid-based polymer containing a repeating unit derived from an poly(α-lower alkyl)acrylic ester and a repeating unit derived from an (α-lower alkyl)acrylic ester represented by formula (I), and a method for producing a polymer through living polymerization, comprising forming an oligomer having a polymerization active end, which is an oligomer higher than an average 1.0-mer and lower than an average 4.0-mer or an average 4.0-mer, and polymerizing using the oligomer having a polymerization active end as an initiating species.

  本文揭示了一种基于丙烯酸的星形聚合物，其包含由公式(I)表示的(α-低烷基)丙烯酸酯衍生的重复单元的臂部分；一种基于丙烯酸的聚合物，其中包含由聚(α-低烷基)丙烯酸酯和由公式(I)表示的(α-低烷基)丙烯酸酯衍生的重复单元，并且通过活性聚合法制备聚合物的方法，包括形成具有聚合活性端的寡聚物，该寡聚物高于平均1.0-聚体但低于平均4.0-聚体或平均4.0-聚体，并使用具有聚合活性端的寡聚物作为引发物种进行聚合。
• CROSS-LINKABLE NITRILE RUBBER COMPOSITION AND CROSS-LINKED RUBBER
  申请人：Ikeda Shinya

  公开号：US20100256294A1

  公开（公告）日：2010-10-07

  A cross-linkable nitrile rubber composition containing a highly saturated nitrile rubber (a) having an α,β-ethylenically unsaturated nitrile monomer unit and a carboxyl-group containing monomer unit and having an iodine value of 120 or less, a cross-linking agent (b), and a specific cyclic amidine and/or cyclic amidinium salt (c) is provided. Preferably, the cross-linking agent (b) is a polyamine-based cross-linking agent (d), and more preferably, the carboxyl-group containing monomer unit is an α,β-ethylenically unsaturated dicarboxylic acid monoester monomer unit.

  提供了一种可交联的丁腈橡胶组合物，其中包含高度饱和的丁腈橡胶（a），其具有α，β-乙烯基不饱和丙烯腈单体单元和含羧基单体单元，并且碘值小于或等于120，交联剂（b）和特定的环状酰胺和/或环状酰胺盐（c）。优选，交联剂（b）是基于多胺的交联剂（d），更优选，含羧基单体单元是α，β-乙烯基不饱和二羧酸单酯单体单元。