9-phenanthrenyltrichlorosilane | 1187327-65-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 9-phenanthrenyltrichlorosilane
• 英文别名: Trichloro(phenanthren-9-yl)silane；trichloro(phenanthren-9-yl)silane
• CAS: 1187327-65-6
• 化学式: C₁₄H₉Cl₃Si
• 分子量: 311.67
• InChiKey: GTEIOLMBBAEESH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.86
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  三硅醇苯基-笼形聚倍半硅氧烷 、 9-phenanthrenyltrichlorosilane 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 以79%的产率得到(9-phenanthrenyl)phenyl₇Si₈O₁₂
  参考文献：
  名称：

  Asymmetric aryl polyhedral oligomeric silsesquioxanes (ArPOSS) with enhanced solubility

  摘要：

  Four new asymmetric Polyhedral Oligomeric SilSesquioxanes (POSS) with the formula (Aryl)Phenyl(7)-Si(8)O(12), where Aryl = 1-naphthyl, 2-naphthyl, 9-phenanthrenyl, and 1-pyrenyl, have been synthesized in reasonable yield and high purity. These compounds were characterized with (1)H, (13)C, (29)Si NMR and elemental combustion analysis. These compounds possess polycyclic aromatic functionality, which disrupts symmetry to improve solubility in organic solvents and aromatic polymers, without significant impact on thermal stability. Published by Elsevier B. V.

  DOI：

  10.1016/j.jorganchem.2011.03.035
• 作为产物：
  描述：

  9-溴菲 在 magnesium 、 四氯化硅 作用下， 以 四氢呋喃 为溶剂， 以58%的产率得到9-phenanthrenyltrichlorosilane
  参考文献：
  名称：

  Asymmetric aryl polyhedral oligomeric silsesquioxanes (ArPOSS) with enhanced solubility

  摘要：

  Four new asymmetric Polyhedral Oligomeric SilSesquioxanes (POSS) with the formula (Aryl)Phenyl(7)-Si(8)O(12), where Aryl = 1-naphthyl, 2-naphthyl, 9-phenanthrenyl, and 1-pyrenyl, have been synthesized in reasonable yield and high purity. These compounds were characterized with (1)H, (13)C, (29)Si NMR and elemental combustion analysis. These compounds possess polycyclic aromatic functionality, which disrupts symmetry to improve solubility in organic solvents and aromatic polymers, without significant impact on thermal stability. Published by Elsevier B. V.

  DOI：

  10.1016/j.jorganchem.2011.03.035