tert-pentylacrylamide | 3729-16-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: tert-pentylacrylamide
• 英文别名: N-tert-Pentylacrylamide；N-tert-Pentyl-acrylamid；N-t-Amylacrylamid；<2-Methyl-butyl-2>-acrylamid；N-(1,1-dimethylpropyl)-2-propenamide；Acrylsaeure-tert-pentylamid；t-Pentyl-acrylamid；t-Amylacrylamid；N-(2-Methylbutan-2-yl)prop-2-enamide
• CAS: 3729-16-6
• 化学式: C₈H₁₅NO
• 分子量: 141.213
• InChiKey: UGHVZLXVTYMJBC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

安全信息

• 海关编码：
  2924199090

反应信息

• 作为反应物：
  描述：

  tert-pentylacrylamide 在 四氯化碳 、 溴 作用下， 生成 2,3-dibromo-propionic acid tert-pentylamide
  参考文献：
  名称：

  A New Reaction of Nitriles. VI. Unsaturated Amides¹

  摘要：

  DOI：

  10.1021/ja01153a005
• 作为产物：
  描述：

  2-甲基-丁烯 、 丙烯腈 在 硫酸 作用下， 以 溶剂黄146 为溶剂， 反应 20.0h， 生成 tert-pentylacrylamide
  参考文献：
  名称：

  Glikmans,G. et al., Bulletin de la Societe Chimique de France, 1966, p. 1376 - 1383

  摘要：

  DOI：

文献信息

• [EN] CERTAIN CHEMICAL ENTITIES, COMPOSITIONS, AND METHODS<br/>[FR] ENTITÉS CHIMIQUES, COMPOSITIONS ET MÉTHODES PARTICULIÈRES
  申请人：NEUPHARMA INC

  公开号：WO2018035061A1

  公开（公告）日：2018-02-22

  Chemical entities that are kinase inhibitors, pharmaceutical compositions and methods of treatment of cancer are described.

  化学实体、药物组合物及其用于治疗癌症的方法，所述化学实体为激酶抑制剂。
• Design, Synthesis, and Insecticidal Evaluation of <i>N</i>-Pyridylpyrazole Amide Derivatives Containing 4,5-Dihydroisoxazole Amide as Potential Ryanodine Receptor Activators
  作者：Xiwen Pang、Li Han、Cong Zhou、Yuxin Li、Xiaoyong Xu、Xusheng Shao、Zhong Li

  DOI：10.1021/acs.jafc.3c03199

  日期：2023.9.20

  Using the 4,5-dihydroisoxazol amide structure to expand the aliphatic amide moiety of chlorantraniliprole, a series of 28 novel N-pyridylpyrazolecarboxamide derivatives containing 4,5-dihydroisoxazol amide fragment were designed and synthesized. All target compounds had been properly characterized and confirmed by 1H NMR, 13C NMR, and HRMS, and the effects were evaluated against Mythimna separata (M

  利用4,5-二氢异恶唑酰胺结构扩展氯虫苯甲酰胺的脂肪族酰胺部分，设计合成了一系列28种含有4,5-二氢异恶唑酰胺片段的新型N-吡啶基吡唑甲酰胺衍生物。所有目标化合物均经过1 H NMR、13 C NMR 和 HRMS 正确表征和证实，并针对粘虫( M. separata ) 和小菜蛾( P. xylostella )评估了效果。生物测定结果表明，大部分目标化合物在50 mg/L浓度下对斑小菜蛾和小菜蛾表现出良好的杀虫活性；尤其是，化合物A4针对M. separata表现出3.27mg/L的LC 50值。钙成像实验表明，目标化合物A4与氯虫苯甲酰胺具有相似的作用机制，导致细胞质Ca 2+浓度增加。分子对接揭示了化合物A4与兰尼碱受体可能的结合模式。
• Skin care composition
  申请人：S.C. JOHNSON & SON, INC.

  公开号：EP0134483A2

  公开（公告）日：1985-03-20

  An aqueous, stable, non-occlusive composition for personal use includes an emollient base, a carboxyl vinyl polymer thickener and an amphoteric emulsifier.

  一种水性、稳定、非封闭性的个人使用组合物包括一种润肤剂基质、一种羧基乙烯基聚合物增稠剂和一种两性乳化剂。
• Pressure-sensitive adhesive having broad useful temperature range
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0220885A2

  公开（公告）日：1987-05-06

  This invention relates to pressure-sensitive adhesives and sheet material, including tapes and the like, coated therewith. There is a need for pressure-sensitive adhesives which have balanced adhesive properties over a wide temperature range, good adhesion to plastic films which for the most part have low energy surfaces, and which adhesives can be prepared easily and economically on conventional equipment. The adhesive composition of this invention consists essentially of a first component consisting essentially of a tackified, emulsifiable adhesive and a second component consisting essentially of at least one terminally unsaturated vinyl monomer, at least one vinyl-unsaturated, homopolymerizable, emulsifier monomer, and, optionally a small amount of an external emulsifier. The adhesive provides high tack and excellent adhesion at both low temperatures and in areas that encounter extremes of weather.

  本发明涉及压敏胶和涂有压敏胶的片状材料，包括胶带等。 我们需要在宽温度范围内具有均衡粘合性能的压敏粘合剂，这种粘合剂对塑料薄膜具有良好的粘合力，而塑料薄膜大部分具有低能表面，而且这种粘合剂可以在常规设备上方便而经济地制备。 本发明的粘合剂组合物主要由第一组分和第二组分组成，第一组分主要是一种粘性可乳化的粘合剂，第二组分主要是至少一种端基不饱和乙烯基单体、至少一种乙烯基不饱和、可均聚的乳化剂单体，以及少量的外部乳化剂。这种粘合剂在低温和极端气候条件下都能提供高粘性和出色的粘附性。
• A coated abrasive containing a pressure-sensitive adhesive coatable from water
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0418093A2

  公开（公告）日：1991-03-20

  This invention relates to coated abrasive products having a pressure-sensitive adhesive layer coatable from water. Many coated abrasive products, especially coated abrasive sheets and discs, are mounted on a support pad, sometimes called a back-up pad, during use. One means for securing the coated abrasive article to the support pad calls for a pressure-sensitive adhesive. Typically, the surface of the coated abrasive article not containing the abrasive grains will bear a layer of pressure-sensitive adhesive. For many years, pressure-sensitive adhesives have been coated from organic solvent solutions onto the non-abrasive side of the coated abrasive article with excellent results. However, because recent governmental regulations require reductions in solvent emissions, the coated abrasive industry desires to eliminate all organic solvents from their coating operations. This invention provides a coated abrasive product having a backing bearing abrasive grains on one major surface thereof and a pressure-sensitive adhesive, coatable from water, on the other major surface thereof. The pressure-sensitive adhesive can be used to secure the coated abrasive to a support pad or back-up pad. The support pad provides the coated abrasive with the necessary foundation during abrading operations. The pressure-sensitive adhesives of this invention can adequately secure the coated abrasive to the support pad even at high rotation speeds and at high grinding pressures. Previously known pressure-sensitive adhesives for coated abrasives that are coatable from water were unable to provide this property.

  本发明涉及具有可从水中涂布的压敏胶层的涂布研磨产品。许多涂附磨具产品，特别是涂附磨片和磨盘，在使用过程中被安装在支撑垫上，有时也称为支撑垫。将涂附磨具固定在支撑垫上的一种方法需要使用压敏胶。通常情况下，不含磨粒的涂布磨具表面会有一层压敏胶。多年来，压敏胶都是用有机溶剂溶液涂在涂布磨具的非磨料面上，效果非常好。然而，由于最近的政府法规要求减少溶剂排放，涂布磨料行业希望在涂布操作中消除所有有机溶剂。本发明提供了一种涂布磨料产品，它的一个主要表面是带有磨料颗粒的衬底，另一个主要表面是可用水涂布的压敏胶。压敏胶可用于将涂布磨料固定在支撑垫或支撑垫上。支撑垫可在研磨操作过程中为涂层磨料提供必要的基础。即使在高转速和高研磨压力下，本发明的压敏胶也能充分地将涂布磨料固定在支撑垫上。以前已知的可从水中涂敷的涂布磨料压敏粘合剂无法提供这种特性。