decanoic acid Li-salt | 20336-95-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: decanoic acid Li-salt
• 英文别名: Lithium decanoate；lithium;decanoate
• CAS: 20336-95-2
• 化学式: C₁₀H₁₉O₂*Li
• 分子量: 178.201
• InChiKey: POYDCAKGHSRECA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.12
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  decanoic acid Li-salt 在 9-borabicyclo[3.3.1]nonane dimer 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 以98%的产率得到癸醛
  参考文献：
  名称：

  Cha, Jin Soon; Oh, Se Yeon; Lee, Kwang Woo, Heterocycles, 1988, vol. 27, # 7, p. 1595 - 1598

  摘要：

  DOI：
• 作为产物：
  描述：

  正癸酸 、 正丁基锂 生成 decanoic acid Li-salt
  参考文献：
  名称：

  KANO SHIZO; YOKOMATSU TSUTOMU; SIBUYA SIROSHI, J. ORG. CHEM., 1978, 43, NO 22, 4366-4367

  摘要：

  DOI：

文献信息

• Solvent-containing coating material and the use thereof
  申请人：——

  公开号：US20040019142A1

  公开（公告）日：2004-01-29

  Method for making a solvent-containing coating material comprising 5 to 70% by weight of at least one mixture of substances (A). The mixture of substances is obtained by copolymerizing in at least one hydroxy-group containing reactive diluent a mixture (A1) of olefinically unsaturated monomers that contain a1) 1 to 90% by weight, based on mixture (A1), of at least one cycloaliphatic monomer and a2) 0 to 90% by weight, based on mixture (A1), of at least one hydroxy-group containing monomer. The coating material further contains 5 to 70% by weight of at least one hydroxy-group containing polyaddition resin (polyadduct) (B) with a M n of 800 to 3,500 and 5 to 70% by weight of at least one cross-linking agent (C) for thermally cross-linking the material. The weight of A, B, and C are based on the solid content of the coating material.

  制备含溶剂的涂料材料的方法，其中包括5至70重量％的至少一种物质（A）的混合物。该物质的混合物是通过在至少一个含有羟基的反应性稀释剂中共聚合含有a1）1至90重量％（基于混合物（A1））的至少一种环脂烃单体和a2）0至90重量％（基于混合物（A1））的至少一种含羟基单体的烯烃不饱和单体的混合物（A1）中获得的。涂料材料还包含5至70重量％的至少一种含羟基的聚加成树脂（聚加物）（B），其Mn为800至3,500，并且5至70重量％的至少一种交联剂（C），用于热交联材料。 A，B和C的重量基于涂料材料的固体含量。
• THERMAL AMPLIFICATION OF FREE RADICAL POLYMERIZATION INDUCED BY RED TO NEAR-INFRARED IRRADIATION
  申请人：Universite de Haute-Alsace

  公开号：US20200362061A1

  公开（公告）日：2020-11-19

  The present invention relates to compositions thermally curable on demand by red to near infrared irradiation, method of using same for thermal amplification of free radical polymerizations, and articles obtained by such method. The invention also relates to the use of a heat-generating dye in association with a thermal initiator for controlling the onset of thermal free radical polymerization.

  本发明涉及一种通过红外线至近红外线辐射在需求时热固化的组合物，以及使用该组合物进行自由基聚合的热放大方法和由此方法获得的制品。本发明还涉及在热起始剂中与产热染料结合使用以控制热自由基聚合的开始的使用。
• Olefin oxidation process
  申请人：PHILLIPS PETROLEUM COMPANY

  公开号：EP0000143A1

  公开（公告）日：1979-01-10

  Olefins are oxidized to carbonyl compounds, for example, 1-hexene to 2-hexanone, with a Pd/Cu/alkali metal or alkaline earth metal chloride catalyst and a suitable surfactant in a diluent system comprising at least two liquid phases, wherein at least one liquid phase is an aqueous phase, in the presence of free oxygen. The addition of the surfactant to the system provides an improvement in olefin conversion and selectivity to the corresponding carbonyl compound. Suitable surfactants include, for example, quaternary ammonium halide compounds.

  在由至少两个液相（其中至少一个液相是水相）组成的稀释剂体系中，在存在自由氧的情况下，使用钯/铜/碱金属或碱土金属氯化物催化剂和合适的表面活性剂将烯烃氧化成羰基化合物，例如将 1-己烯氧化成 2-己酮。 在该体系中添加表面活性剂可提高烯烃转化率和对相应羰基化合物的选择性。 合适的表面活性剂包括季铵卤化物等。
• Crystalline polyolefin composition
  申请人：Chisso Corporation

  公开号：EP0416321A1

  公开（公告）日：1991-03-13

  A crystalline polyolefin composition which provides molded articles having improved stiffness characteristics is disclosed, comprising 100 parts by weight of a crystalline polyolefin, (A) from 0.001 to 1 part by weight of a fluorophosphite compound represented by formula (I): wherein R represents an alkylidene group having from 1 to 4 carbon atoms or a sulfur atom; Ar1 and Ar2, which may be the same or different, each represents an alkylarylene group or a cycloalkylarylene group; and n represents 0 or 1, and (B) from 0.001 to 1 part by weight of at least one compound selected from the group consisting of (1) an aliphatic monocarboxylic acid salt with lithium or sodium, (2) a dithiocarbamic acid salt with lithium, sodium or potassium, (3) a 2-mercaptobenzothiazole salt with lithium, sodium or potassium, (4) a 2-mercaptobenzimidazole salt with lithium, sodium or potassium and (5) a benzotriazole salt with lithium, sodium or potassium. A crystalline polyolefin composition which provides molded articles having improved stiffness charateristics is also disclosed, comprising 100 parts by weight of a crystalline polyolefin, (A) from 0.001 to 1 part by weight of a fluorophosphite compound represented by formula (I) shown above, (B ) from 0.001 to 1 part by weight of at least one compound selected from the group consisting of (1) an aliphatic monocarboxylic acid salt with potassium, strontium or barium, (2) a hydroxy-higher fatty acid salt with potassium, strontium or barium, (3) an aliphatic polycarboxylic acid salt with lithium, sodium, potassium, strontium or barium, (4) a salt of an aliphatic hydroxy acid having form 2 to 6 carbon atoms with lithium, sodium, potassium, magnesium, strontium or barium, (5) an aromatic carboxylic acid salt with lithium, sodium, strontium, barium or aluminum, (6) a glutamic acid salt with lithium, sodium, potassium, strontium or barium, (7) an aliphatic phosphoric acid salt with sodium, potassium, calcium, strontium or barium, (8) a lithium, sodium, potassium or barium salt of a cyclic phosphorus compound represented by formula (II): wherein Ar3 and Ar4, which may be the same or different, each represents an arylene group, an alkylarylene group, a cycloalkylarylene group, an arylarylene group or an aralkylarylene group; M represents lithium, sodium, potassium or barium; and m represents an atomic valence of M, (9) magnesium or aluminum hydroxide, (10) magnesium oxide, (11) magnesium or calcium carbonate and (12) hydrotalcite, and (C) from 0.01 to 1 part by weight of an aliphatic amine.

  本发明公开了一种结晶聚烯烃组合物，该组合物可提供具有改进的刚度特性的模塑制品，该组合物包括按重量计100份的结晶聚烯烃、(A)按重量计0.001至1份的由式(I)代表的亚磷酸氟化合物： 其中 R 代表具有 1 至 4 个碳原子的亚烷基或硫原子；Ar1 和 Ar2 可以相同或不同，各自代表烷基芳基或环烷基芳基；n 代表 0 或 1，以及 (B) 0.(1) 锂或钠的脂肪族一羧酸盐，(2) 锂、钠或钾的二硫代氨基甲酸盐、(3) 锂、钠或钾的 2-巯基苯并噻唑盐， (4) 锂、钠或钾的 2-巯基苯并咪唑盐， (5) 锂、钠或钾的苯并三唑盐。 本发明还公开了一种结晶聚烯烃组合物，该组合物可提供具有改进的刚度特性的模塑制品，其成分包括 100 份（重量）结晶聚烯烃、(A) 0.001 至 1 份（重量）由上文式(I)代表的亚磷酸氟化合物、(B ) 0.(1)钾、锶或钡的脂肪族一羧酸盐；(2)钾、锶或钡的羟基高级脂肪酸盐；(3)锂、钠、钾、锶或钡的脂肪族多羧酸盐；(4)锂、钠、钾、镁、锶或钡的具有 2 至 6 个碳原子的脂肪族羟基酸盐、(5) 锂、钠、锶、钡或铝的芳香族羧酸盐； (6) 锂、钠、钾、锶或钡的谷氨酸盐、(7) 含有钠、钾、钙、锶或钡的脂肪族磷酸盐， (8) 由式（II）代表的环磷化合物的锂、钠、钾或钡盐： 其中 Ar3 和 Ar4 可以相同或不同，各自代表芳基、烷芳基、环烷芳基、芳基芳基或芳基芳基；M 代表锂、钠、钾或钡；m 代表 M 的原子价，(9) 氢氧化镁或铝，(10) 氧化镁，(11) 碳酸镁或碳酸钙和 (12) 水滑石，以及 (C) 0.01至1份重量的脂肪族胺。
• Dual cure compositions, methods of curing thereof and articles therefrom
  申请人：General Electric Company

  公开号：EP1764382A1

  公开（公告）日：2007-03-21

  Disclosed herein are dual cure compositions, methods to cure dual cure compositions, the dual cure compositions comprising at least one filler, at least one curable monomer comprising at least one of an ethylenic unit or cyclic ether unit or mixture thereof; at least one photoinitiator; and at least one thermal initiator. The method comprises the step of photocuring by exposing the compositions to radiation to at least partially photocure the composition, which in turn generates an exotherm which initiates thermal curing. The methods may be used to make cured thick compositions and sandwich structures. Articles made by the methods are also described.

  本文公开了双固化组合物、固化双固化组合物的方法，双固化组合物包括至少一种填料、至少一种可固化单体（包括乙烯单元或环醚单元中的至少一种或其混合物）、至少一种光引发剂和至少一种热引发剂。该方法包括光固化步骤，将组合物暴露于辐射中，使组合物至少部分光固化，进而产生放热，引发热固化。这些方法可用于制造固化厚组合物和夹层结构。此外，还介绍了用这些方法制成的物品。